Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

A molecule having the following formula

• wherein:
• (A) R1, R2, R3, R4, R5, R6, R7, R9, and R10 are each independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, OH, (C1-C4)alkyl, (C2-C4)alkenyl, (C1-C4)haloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, and (C3-C6)cycloalkyl,
• wherein each alkyl, alkenyl, haloalkyl, alkoxy, haloalkoxy, and cycloalkyl, are optionally substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, I, CN, NO2, OH, (C1-C4)alkyl, (C2-C4)alkenyl, (C1-C4)haloalkyl, (C1-4)alkoxy, (C1-C4)haloalkoxy, and (C3-C6)cycloalkyl
• preferably, R1, R2, R3, R4, R6, R7, R8, R9, R10, R11, and R12 are H, and R5 is (C1-C4)haloalkoxy, even more preferably R5 is OCF3 or OCF2CF3;
• (B) R8 is H;
• (C) L is selected from the group consisting of
• (1) a bond connecting nitrogen to carbon in the ring, and
• (2) a (C1-C4)alkyl wherein said alkyl is optionally substituted with one or more substituents independently selected from the group consisting of F, Cl, CN, OH, and oxo
• preferably L is a bond or L is —CH2CH2—;
• (D) R11 and R12 are each independently selected from the group consisting of H, (C1-C4)alkyl, (C2-C4)alkenyl, (C2-C4)alkenyloxy, (C2-C4)alkynyl, (C2-C4)alkynyloxy, (C1-C4)haloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C3-C6)cycloalkyl, (C3-C6)cycloalkoxy, (C3-C6)cycloalkenyl, (C3-C6)cycloalkenyloxy, ((C1-C4)alkyl)((C3-C6)cycloalkyl), C(O)((C1-C4)alkyl), ((C1-C4)alkyl)C(O)((C1-C4)alkyl), and ((C1-C4)alkyl)C(O)O((C1-C4)alkyl),
• wherein each alkyl, alkenyl, alkenyloxy, alkynyl, alkynyloxy, haloalkyl, alkoxy, haloalkoxy, cycloalkyl, cycloalkoxy, cycloalkenyl, and cycloalkenyloxy, are optionally substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, I, CN, NO2, OH, and oxo;
• (E) R13 is heterocyclyl, wherein said heterocyclyl is selected from the group consisting of dihydrofuranyl, furanyl, indazolyl, indolyl, imidazolyl, isoindolyl, isothiazolyl, isoxazolyl, oxadiazolyl, oxazolyl, pyrazolinyl, pyrazolyl, pyrrolyl, tetrazolyl, thiazolyl, thienyl, triazinyl, and triazolyl,
• wherein each heterocyclyl is optionally substituted with one or more substituents independently selected from the group consisting of oxo, (C1-C8)alkyl, C(O)O(C1-C4)alkyl, phenyl, and pyridyl,
• wherein each phenyl is optionally substituted with one or more substituents R, independently selected from the group consisting of F, Cl, Br, I, (C1-C4)alkyl, (C1-C4)alkoxy, and (C1-C4)haloalkoxy
• preferably, R13 is dihydrofuranyl, imidazolyl, isoxazolyl, oxadiazolyl, oxazolyl, pyrazolyl, thienyl, or thiazolyl that is substituted with one or more substituents selected from the group consisting of oxo, CH3, CH(CH3)CH2CH(CH3)2, C(O)OCH2CH3, phenyl, and pyridyl that is further substituted with one or more substituents R, selected from F, Cl, CH3, CH2CH3, CH(CH3)2, OCH3, and OCF3;
• (F) Q is selected from the group consisting of O and S;
• and
• agriculturally acceptable acid addition salts, salt derivatives, solvates, ester derivatives, crystal polymorphs, isotopes, resolved stereoisomers, and tautomers, of the molecules of Formula One.