Process to produce magnesium compounds, and various by-products using sulfuric acid in a hcl recovery loop
AssigneeAlliance MagnéSium
InventorsJoël FOURNIER, Laury GAUTHIER
Life of this patent
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Abstract
The present description relates to a process for extracting magnesium compounds from magnesium-bearing ores comprising leaching serpentine tailing with dilute HCl to dissolve the magnesium and other elements like iron and nickel. The resudial silica is removed and the rich solution is further neutralized to eliminate impurities and recover nickel. Magnesium chloride is transformed in magnesium sulfate and hydrochloric acid by reaction with sulfuric acid. The magnesium sulfate can be further decomposed in magnesium oxyde and sulphur dioxyde by calcination. The sulphur gas can further be converted into sulfuric acid.
Claims25
1:
- A process for extracting magnesium sulfate from magnesium-bearing ores, comprising the steps of:
- (a) leaching the magnesium-bearing ores with HCl obtaining a slurry containing chloride compounds;
- (b) filtrating the slurry to obtain a liquor containing the chloride compounds and silica, the silica being extracted from the liquor;
- (c) purifying the liquor by increasing the pH by adding a neutralizing agent producing a brine chloride solution enriched in magnesium containing precipitated iron and impurities;
- (d) filtrating the brine to extract the precipitated iron and impurities contained in said brine;
- (e) neutralizing the brine to extract the precipited nickel content by adding a base;
- and
- (f) adding the enriched magnesium chloride brine to sulfuric acid forming magnesium sulfate and hydrochloric acid which is recycled.
2:
- The process of claim 1, further comprising the step (g) of thermally decomposing the magnesium sulfate in sulphur dioxide gaz and magnesium oxide.
3:
- The process of claim 1, wherein the magnesium-bearing ores are magnesium silicate ores or tailings.
4:
- The process of claim 3, wherein the magnesium silicate ores are serpentine mineral, lizardite, antigorite, olivine, talc, sepiolite or a mixture thereof.
5-7. (canceled)
8:
- The process of claim 1, wherein the neutralizing agent is serpentine tailing.
9:
- The process of claim 1, further comprising adding an oxidizing agent to convert the iron in solution in a bivalent form to a trivalent form.
10:
- The process of claim 9, wherein the oxidizing agent is chlorine gas, hydrogen peroxide, potassium permanganate, dioxygen, air, or a mixture thereof.
11:
- The process of claim 1, wherein the neutralization step (e) is conducted at a temperature between 60-110° C.
12:
- The process of claim 1, wherein the base is magnesium oxide, sodium hydroxide, potassium hydroxide or a mixture thereof.
13-14. (canceled)
15:
- The process of claim 1, further comprising the step (e′) of precipitating the contained manganese from the neutralized brine.
16:
- The process of claim 15, further comprising adding an oxidative agent to convert the manganese in solution from a bivalent form to a quatrivalent form.
17:
- The process of claim 16, wherein said oxidative agent is chlorine gas, hydrogen peroxide, potassium permanganate, dioxygen, air, or a mixture thereof.
18-19. (canceled)
20:
- The process of claim 1, further comprises the step (e″) of precipitating by crystallization the magnesium chloride contained in the enriched magnesium chloride brine using dry gaseous hydrogen chloride obtaining a crystal of magnesium chloride and a solution of magnesium chloride and filtrating to separate said crystal of magnesium chloride from said solution of magnesium chloride, the filtrated magnesium chloride crystal being added to sulfuric acid to form magnesium sulfate and hydrocloric acid which is recycled.
21:
- The process of claim 20, wherein the dry gaseous hydrogen chloride is sparged or bubbled through the enriched magnesium chloride brine.
(canceled)
23:
- The process of claim 1, wherein hydrochloric acid mixed with the magnesium sulfate is stripped of by the use of a gas producing gaseous and wet hydrochloric acid, the gaseous hydrochloric acid being recycled.
(canceled)
25:
- The process of 20, wherein the wet hydrochloric acid and the filtrated magnesium chloride solution are further dehydrated in a dehydration unit in contact with a concentrated hydrochloric acid solution producing dry gaseous hydrochloric acid which is recycled and a diluted hydrochloric solution which is reused in the leaching step (a).
26:
- The process of claim 20, further comprising the step (f′) of converting the magnesium chloride contained in the enriched magnesium chloride brine into magnesium metal by electrolysis.
27:
- A process for extracting magnesium sulfate from magnesium-bearing ores, comprising the steps of:
- (a) leaching the magnesium-bearing ores with HCl obtaining a slurry containing chloride compounds;
- (b) filtrating the slurry to obtain a liquor containing the chloride compounds and silica, the silica being extracted from the liquor;
- (c) purifying the liquor by increasing the pH by adding a neutralizing agent producing a brine chloride solution enriched in magnesium containing precipitated iron and impurities;
- (d) filtrating the brine to extract the precipitated iron and impurities contained in said brine;
- (e) neutralizing the brine to extract the precipited nickel content by adding a base;
- (e″) precipitating by crystallization the magnesium chloride contained in the magnesium chloride brine using dry gaseous hydrogen chloride obtaining a crystal of magnesium chloride and a solution of magnesium chloride;
- (e′″) filtrating to separate said crystal of magnesium chloride from said solution of magnesium chloride;
- and
- (e″″) adding the magnesium chloride crystal to sulfuric acid to form magnesium sulfate and hydrocloric acid which is recycled.
28:
- The process of claim 27, further comprising the step (e′) of precipitating the contained manganese from the neutralized brine.
29:
- The process of claim 27, further comprising the step (g) of thermally decomposing the magnesium sulfate in sulphur dioxide gaz and magnesium oxide.
Dependencies are inferred from the claim text.