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US 2017/0321055 A1Published application
Polycarbonate resin composition including polycarbonate-polyorganosiloxane copolymer, and molded article of same
AssigneeIdemitsu Kosan Co., Ltd.
InventorYusuke AOKI
Life of this patent
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Abstract
Provided is a polycarbonate-based resin composition (A), including: 90 mass % to 10 mass % of a polycarbonate-polyorganosiloxane copolymer (A-1) having a polyorganosiloxane block; and 10 mass % to 90 mass % of a polycarbonate-based resin (A-2) except the (A-1), in which a ratio of terminal hydroxyl groups in the composition (A) is from 5 mol % to 70 mol %, and a content of a polyorganosiloxane block moiety in the composition (A) is from 0.7 mass % to 40 mass %.
Claims12
A polycarbonate-based resin composition (A), comprising:
- 90 mass % to 10 mass % of a polycarbonate-polyorganosiloxane copolymer (A-1) having a polycarbonate block containing a repeating unit represented by the following general formula (I) and a polyorganosiloxane block containing a siloxane repeating unit represented by the following general formula (II);
- and
- 10 mass % to 90 mass % of a polycarbonate-based resin (A-2) except the (A-1),
- wherein a ratio of terminal hydroxyl groups in the composition (A) is from 5 mol % to 70 mol %, and a content of a polyorganosiloxane block moiety in the composition (A) is from 0.7 mass % to 40 mass %:
- wherein:
- R1 and R2 each independently represent a halogen atom, an alkyl group having 1 to 6 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms, X represents a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, a fluorenediyl group, an arylalkylene group having 7 to 15 carbon atoms, an arylalkylidene group having 7 to 15 carbon atoms, —S—, —SO—, —SO2—, —O—, or —CO—, and a and b each independently represent an integer of from 0 to 4;
- and
- R3 and R4 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms, and an average number n of repetitions represents a total number of siloxane repeating units in the polyorganosiloxane block.
5 more elements
A polycarbonate-based resin composition (A′), comprising:
- 90 mass % to 10 mass % of a polycarbonate-polyorganosiloxane copolymer (A-1′) having a polycarbonate block containing a repeating unit represented by the following general formula (I) and a polyorganosiloxane block containing a siloxane repeating unit represented by the following general formula (II), and having a ratio of terminal hydroxyl groups of 5 mol % or less;
- and
- 10 mass % to 90 mass % of a polycarbonate-polyorganosiloxane copolymer (A-3) having a polycarbonate block containing a repeating unit represented by the general formula (I) and a polyorganosiloxane block containing a siloxane repeating unit represented by the following general formula (II), and having a ratio of terminal hydroxyl groups of from 7 mol % to 70 mol %,
- wherein a content of a polyorganosiloxane block moiety in the composition (A′) is from 0.7 mass % to 40 mass %:
- wherein:
- R1 and R2 each independently represent a halogen atom, an alkyl group having 1 to 6 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms, X represents a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, a fluorenediyl group, an arylalkylene group having 7 to 15 carbon atoms, an arylalkylidene group having 7 to 15 carbon atoms, —S—, —SO—, —SO2—, —O—, or —CO—, and a and b each independently represent an integer of from 0 to 4;
- and
- R3 and R4 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms, and an average number n of repetitions represents a total number of siloxane repeating units in the polyorganosiloxane block.
5 more elements
Dependencies are inferred from the claim text.