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US 2017/0317386 A1Published application
Non-aqueous electrolytic solution and lithium battery
AssigneeUbe Industries, Ltd.
InventorsKoji ABE, Takashi HATTORI, Yasuo MATSUMORI
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Abstract
A non-aqueous electrolytic solution comprising a non-aqueous solvent and an electrolyte, which further contains a combination of a nitrile compound and an S═O group-containing compound (or a dinitrile compound) in an amount of 0.001 to 10 wt. % imparts improved cycle performance and storage property to a lithium battery, particularly a lithium secondary battery.
Claims20
1:
- A non-aqueous electrolytic solution, comprising:
- a non-aqueous solvent;
- an electrolyte;
- and
- from 0.01 to 3% by weight of succinonitrile or glutaronitrile, based on a total weight of the non-aqueous electrolytic solution.
2 more elements
2:
- The non-aqueous electrolytic solution of claim 1, further comprising:
- from 0.2 to 3% by weight of at least one S═O group-comprising compound.
3:
- The non-aqueous electrolytic solution of claim 2, wherein the S═O group-comprising compound is at least one selected from the group consisting of dimethylsulfite, diethylsulfite, ethylenesulfite, propylenesulfite, vinylenesulfite, dimethylsulfone, diethylsulfone, methylethylsulfone, divinylsulfone, sulforane, sulforene, methyl methanesulfonate, ethyl methanesulfonate, propargyl methanesulfonate, methyl benzenesulfonate, 1,3-propanesultone, 1,4-butanesultone, dimethyl sulfate, diethylsulfate, ethyleneglycol sulfate, and 1,2-propanediol sulfate.
4:
- The non-aqueous electrolytic solution of claim 1, wherein the non-aqueous solvent comprises a cyclic carbonate.
5:
- The non-aqueous electrolytic solution of claim 4, wherein the cyclic carbonate is at least one selected from the group consisting of ethylene carbonate, propylene carbonate, butylene carbonate, and vinylene carbonate.
6:
- The non-aqueous electrolytic solution of claim 5, wherein the cyclic carbonate comprises vinylene carbonate.
7:
- The non-aqueous electrolytic solution of claim 1, wherein the non-aqueous solvent comprises at least one of a linear carbonate selected from the group consisting of dimethyl carbonate, methyl ethyl carbonate, diethyl carbonate, dipropyl carbonate, and dibutyl carbonate.
8:
- The non-aqueous electrolytic solution of claim 7, in which the linear carbonate comprises methyl ethyl carbonate.
9:
- The non-aqueous electrolytic solution of claim 1, wherein the non-aqueous electrolytic solution comprises from 0.5 to 1.5 M of the electrolyte.
10:
- The non-aqueous electrolytic solution of claim 9, wherein the electrolyte is at least one selected from the group consisting of LiPF6, LiBF4, LiAsF6, LiClO4, LiOSO2CF3, LiN(SO2CF3)2, LiN(SO2C2F5)2, LiC(SO2CF3)3, LiPF4(CF3)2, LiPF3(CF3)3, LiPF3(C2F5)3, LiPF5(iso-C3F7), LiPF4(iso-C3F7)2, and LiBF3(C2F5).
11:
- The non-aqueous electrolytic solution of claim 10, wherein the electrolyte comprises LiPF6.
12:
- A lithium secondary battery, comprising:
- a positive electrode;
- a negative electrode comprising a carbonaceous material of graphite crystal structure having a lattice distance of lattice surface (002) of 0.34 nanometer or less;
- and
- the non-aqueous electrolytic solution of claim 1.
2 more elements
13:
- The lithium secondary battery of claim 12, wherein the positive electrode comprises a lithium element and a complex metal oxide containing one metal element selected from the group consisting of cobalt, manganese, nickel, chromium, iron, and vanadium.
14:
- The lithium secondary battery of claim 13, wherein the complex metal oxide comprises at least one selected from the group consisting of LiCoO2, LiMn2O4, LiNiO2 and LiCO1-xNixO2(0.01<x<1).
15:
- A lithium secondary battery, comprising:
- a positive electrode;
- a negative electrode comprising a carbonaceous material of graphite crystal structure having a lattice distance of lattice surface (002) of 0.34 nanometer or less;
- and
- the non-aqueous electrolytic solution of claim 2.
2 more elements
16:
- The lithium secondary battery of claim 15, wherein the positive electrode comprises a lithium element and a complex metal oxide containing one metal element selected from the group consisting of cobalt, manganese, nickel, chromium, iron, and vanadium.
17:
- The lithium secondary battery of claim 16, wherein the complex metal oxide comprises at least one selected from the group consisting of LiCoO2, LiMn2O4, LiNiO2 and LiCO1-xNixO2(0.01<x<1).
18:
- A lithium secondary battery, comprising:
- a positive electrode;
- a negative electrode comprising a carbonaceous material of graphite crystal structure having a lattice distance of lattice surface (002) of 0.34 nanometer or less;
- and
- the non-aqueous electrolytic solution of claim 3.
2 more elements
19:
- The lithium secondary battery of claim 18, wherein the positive electrode comprises a lithium element and a complex metal oxide containing one metal element selected from the group consisting of cobalt, manganese, nickel, chromium, iron, and vanadium.
20:
- The lithium secondary battery of claim 19, wherein the complex metal oxide comprises at least one selected from the group consisting of LiCoO2, LiMn2O4, LiNiO2 and LiCO1-xNixO2(0.01<x<1).