Method for purifying biogas through membranes at negative temperatures
AssigneeL'Air Liquide, Societe Anonyme pour I'Etude et I'Exploitation des Procedes Georges Claude
InventorsSarah BIGEARD, Delphine GARNAUD, David J. HASSE, Sudhir S. KULKARNI, Edgar S. SANDERS, Golo ZICK
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Abstract
The invention relates to a method for membrane permeation of a gas flow including methane and carbon dioxide, wherein said gas flow is cooled to a temperature of 0° C. to −60° C. before being fed into a membrane separation unit.
Claims15
1-13. (canceled)
Process for purifying a gas stream comprising methane and carbon dioxide by membrane permeation, said process comprising the following successive steps:
- a) compressing the gas stream to a pressure between 5 and 20 bar;
- b) a first step of cooling the compressed gas stream to a temperature between 0° C. and 15° C.;
- c) drying the cooled and compressed gas stream to obtain a water content ≦0.1 ppm;
- d) a second step of cooling the gas stream resulting from step c) using a heat exchanger to a temperature between 0° C. and −60° C.;
- e) separating the gas stream resulting from step d) through at least one membrane stage so as to obtain a CO2-enriched permeate and a CO2-depleted retentate;
- and
- f) recovering a methane-enriched gas stream.
A plant for purifying a gas stream comprising methane and carbon dioxide by membrane permeation, said plant comprising, in the flow direction of the gas stream:
- a) a compressor configured to compress the gas stream to between 5 and 20 bar,
- b) a cooling means configured to cool the gas stream to a temperature between 0° C. and 15° C.,
- c) a dryer configured to dry the cooled and compressed gas stream so as to obtain a gas stream having a water content of less than 0.1 ppm,
- d) an exchanger configured to cool the gas stream to a temperature between 0° C. and −60° C.,
- e) a separation unit comprising at least one membrane stage more permeable to carbon dioxide configured to separate the gas stream leaving the exchanger.
Dependencies are inferred from the claim text.