# US 2017/0288218 A1 · Conductive composition for electrode, electrode using same, and lithium ion secondary battery

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 2017/0288218 A1
- Document ID: US20170288218A1
- Status: Published application
- Kind: A1
- Application number: 15/503,362
- Filed: 2015-08-06
- Published: 2017-10-05
- Earliest claimed: 2014-08-11
- Assignees: Denka Company Limited
- Applicants: Denka Company Limited
- Inventors: Yoko Horikoshi; Toru Arai; Hitoshi Kaneko; Tatsuya Nagai; Ayumu Tsukamoto
- Web page: https://patentgrep.com/patent/US20170288218A1

## CPC

- H01M 4/405: {Alloys based on lithium}
- C01B 32/05: Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
- C09D 127/16: Homopolymers or copolymers of vinylidene fluoride
- C09D 127/18: Homopolymers or copolymers of tetrafluoroethene
- C09D 129/04: Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
- H01B 1/24: the conductive material comprising carbon-silicon compounds, carbon or silicon
- H01M 4/386: {Silicon or alloys based on silicon}
- H01M 4/525: of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
- H01M 4/623: {fluorinated polymers}
- H01M 4/625: {Carbon or graphite}
- H01M 10/052: Li-accumulators
- B82Y 30/00: Nanotechnology for materials or surface science, e.g. nanocomposites
- B82Y 40/00: Manufacture or treatment of nanostructures
- C08F 14/26: Tetrafluoroethene
- C08F 20/06: Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
- C08L 9/06: Copolymers with styrene
- H01M 4/131: Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- H01B: CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES (selection for magnetic properties H01F1/00; waveguides H01P {; printed circuits H05K})
- B82Y: SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A conductive composition for electrode is provided that is excellent in conductivity and dispersibility. Further, an electrode for lithium ion secondary battery with lower plate resistance and a lithium ion secondary battery excellent in rate characteristics are provided that use this conductive composition. A conductive composition for electrode, including: carbon nanofiber with a median diameter D50 value by volume from 0.1 to 8 μm; an active material; and a binder enables production of an electrode for lithium ion secondary battery with lower plate resistance and a lithium ion secondary battery excellent in rate characteristics.

## Claims

### Claim 1

A conductive composition for electrode, comprising: carbon nanofiber with a median diameter D50 value by volume from 0.1 to 8μm; an active material; and a binder.

### Claim 2 (depends on 1)

The composition of claim 1, wherein the carbon nanofiber further has powder resistivity of, measured under a load of 9.8 MPa, 0.03 Ωcm or less and D/G from 0.5 to 1.3.

### Claim 3 (depends on 1)

The composition of claim 1, wherein a content of the carbon nanofiber is from 0.1 to 2 mass % based on a sum total of the composition.

### Claim 4 (depends on 1)

The composition of claim 1, wherein the active material is selected from any one or more of LiCoO2, LiMn2O4, LiNiO2, LiMPO4, Li2MSiO4, LiNiXMn(2-X)O4, Li(MnXNiYCoZ)O2, Li(AlXNiYCoZ)O2, and xLi2MnO3-(1-x)LiMO2, where X in LiNiXMn(2-X)O4 satisfies relationship of 0<X<2, X, Y, and Z in Li(MnXNiYCoZ)O2 or Li(AlXNiYCoZ)O2 satisfy relationship of X+Y+Z=1 and also satisfy relationship of 0<X<1, 0<Y<1, and 0<Z<1, x in xLi2MnO3-(1-x)LiMO2 satisfies relationship of 0<x<1, and M in LiMPO4, Li2MSiO4, or xLi2MnO3-(1-x)LiMO2 is one or more elements selected from Fe, Co, Ni, and Mn.

### Claim 5 (depends on 1)

The composition of claim 1, wherein the binder is selected from any one or more of polyvinylidene fluoride, polytetrafluoroethylene, a styrene-butadiene copolymer, a (meth)acrylate copolymer, polyvinyl alcohol, and a copolymer of polyvinyl alcohol and polyacrylonitrile.

### Claim 6 (depends on 1)

The composition of claim 1, wherein
the carbon nanofiber is carbon nanofiber produced using a catalyst having an active species containing cobalt as a main component, and using carbon monoxide as a carbon source;
the catalyst has the active species from 3 to 150 mass % supported on a carrier of a magnesium-containing oxide with a specific surface area from 0.01 to 5 m2/g; and
the carbon nanofiber is produced in conditions of a reaction temperature from 670° C. to 780° C., a carbon monoxide partial pressure from 0.04 to 0.98 MPa, a hydrogen partial pressure from 1% to 100% based on the carbon monoxide partial pressure, and a carbon monoxide gas flow rate of 1 NL/g-active species min. or more.

### Claim 7 (depends on 1)

An electrode for lithium ion secondary battery, comprising the composition of claim 1.

### Claim 8 (depends on 7)

A lithium ion secondary battery, comprising the electrode for lithium ion secondary battery of claim 7.
