# US 2017/0283672 A1 · Thermosetting resin composition

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- Number: US 2017/0283672 A1
- Document ID: US20170283672A1
- Status: Published application
- Kind: A1
- Application number: 15/473,170
- Filed: 2017-03-29
- Published: 2017-10-05
- Earliest claimed: 2016-03-30
- Assignees: Asahi Kasel Kabushiki Kaisha
- Applicants: ASAHI KASEl KABUSHIKI KAISHA
- Inventors: Akinori Inoue; Shozo Takada
- Web page: https://patentgrep.com/patent/US20170283672A1

## CPC

- C09K 3/10: {Materials in mouldable or extrudable form} for sealing or packing joints or covers (filling pastes C09D5/34)
- C08G 59/20: characterised by the epoxy compounds used
- C08G 59/50: Amines
- C08L 63/00: Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C09J 163/00: Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
- H10W 74/016: {using moulds}
- H10W 74/47: comprising organic materials, e.g. plastics or resins
- H10W 74/473: {containing a filler}
- C08K 3/013: Fillers, pigments or reinforcing additives
- C08K 3/36: Silica
- C08K 2201/005: Additives being defined by their particle size in general
- C08K 2201/006: Additives being defined by their surface area
- C09K 2003/1078: {Fire-resistant, heat-resistant materials}
- H10W 72/884: {Die-attach connectors and bond wires}
- H10W 74/00: Encapsulations, e.g. protective coatings
- H10W 90/756: {between a chip and a stacked lead frame, conducting package substrate or heat sink}
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- C09J: ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES (preparation of glue or gelatine C09H)
- H10W: GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)

## Abstract

A resin composition including at least (A) an epoxy resin, (B) a curing agent and (C) an inorganic filler, satisfies the following conditions: (I-I) the minimum modulus is no greater than 104 MPa when evaluated at a set temperature of 200° C. after temperature increase from room temperature to 200° C. at 50° C./min by evaluation with a rheometer, and the final modulus is 105 MPa or greater from 10 minutes after the initial temperature increase; (I-II) the softening point of the epoxy resin (A) is 35° C. or higher; (I-III) the residual solvent in the resin composition is no greater than 0.1%; and (I-IV) the equivalent value of the curing agent (B) is no greater than 90 g/eq and the softening point is 105° C. or higher.

## Claims

### Claim at position 1

-6. (canceled)

### Claim 7

A resin composition including (A) an epoxy resin, (B) a curing agent and (C) an inorganic filler, and satisfying the following conditions:
(I-I) the minimum modulus is no greater than 104 MPa by evaluation with a rheometer, when evaluated at a set temperature of 200° C. after temperature increase from 23° C. to 200° C. at 50° C./min;
(I-II) the softening point of the epoxy resin (A) is 35° C. or higher;
(I-III) the residual solvent in the resin composition is less than 0.1 wt %; and
(I-IV) the softening point of the curing agent (B) is 105° C. or higher.

### Claim 8 (depends on 7)

The resin composition according to claim 7, wherein, under the condition (I-I), the final modulus is 105 MPa or greater from 10 minutes after the temperature increase.

### Claim 9 (depends on 7)

The resin composition according to claim 7, wherein, under the condition (I-IV), the equivalent value of the curing agent (B) is no greater than 90 g/eq.

### Claim 10 (depends on 7)

A resin composition according to claim 7, wherein the curing agent (B) is a compound with amino groups.

### Claim 11 (depends on 7)

A sealing material comprising the cured product of a resin composition according to claim 7.

### Claim 12 (depends on 11)

A semiconductor device wherein a semiconductor element is sealed with a sealing material according to claim 11.

### Claim 13 (depends on 11)

A method for producing a semiconductor device, including a step of sealing a semiconductor element by compression molding using a sealing material according to claim 11.

### Claim 14

A resin composition including (A) an epoxy resin, (B) a curing agent and (C) an inorganic filler, and satisfying the following conditions:
(II-I) X atoms other than C, O, H and N atoms in the main component of the inorganic filler (C) (the component present in a range of 1 to 95 mol %), based on EDX measurement, are on the surface of the inorganic filler (C) in the resin composition;
(II-II) the weight percentage of the inorganic filler (C) in the resin composition is no greater than 95 wt %;
(II-III) the mean particle size of the inorganic filler (C) is 0.5 μm or greater;
(II-IV) a ratio of the specific surface area of the inorganic filler (C) for the total resin composition is no greater than 3 m2/g;
(II-V) the softening point of the epoxy resin (A) is 35° C. or higher;
(II-VI) the residual solvent in the resin composition is less than 0.1 wt %; and
(II-VII) the softening point of the curing agent (B) is 105° C. or higher.

### Claim 15 (depends on 14)

The resin composition according to claim 14, wherein, under the condition (II-I), the abundance ratio of C atoms of the epoxy resin (A) or curing agent (B) and the X atoms of the inorganic filler (C), based on EDX measurement, on the surface of the inorganic filler (C) in the resin composition satisfies the following formula:
C/X=≧1
wherein C is defined as a molar concentration of the C atoms and X is defined as a molar concentration of the X atoms.

### Claim 16 (depends on 14)

The resin composition according to claim 14, wherein, under the condition (II-VII), the equivalent value of the curing agent (B) is no greater than 90 g/eq and the softening point is 105° C. or higher.

### Claim 17 (depends on 14)

A resin composition according to claim 14, wherein the curing agent (B) is a compound with amino groups.

### Claim 18 (depends on 14)

A sealing material comprising the cured product of a resin composition according to claim 14.

### Claim 19 (depends on 18)

A semiconductor device wherein a semiconductor element is sealed with a sealing material according to claim 18.

### Claim 20 (depends on 18)

A method for producing a semiconductor device, including a step of sealing a semiconductor element by compression molding using a sealing material according to claim 18.
