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US 2017/0260336 A1Published application
Cross-linkable masses based on organyl-oxysilane-terminated polymers
AssigneeWacker Chemie AG
InventorsVolker STANJEK, Lars ZANDER
Life of this patent
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Abstract
Moisture curable compositions having a low modulus and a high resilience are prepared by curing a composition containing a first polymer which predominately contains two moisture-curable silyl groups, and a second polymer which is terminated by an alkoxy group and contains but a single moisture-curable silyl group, or a hydroxyl group.
Claims20
A moisture-curable composition comprising:
- (A) 100 parts by weight of at least one silane-crosslinking polymer of the formula
- (HO)x—Y—[O—CO—NH—(CR12)b—SiRa(OR2)3-a]2-x (I)
- where
- Y is a divalent polymer radical,
- R each, independently, is the same or different and is a monovalent, optionally substituted hydrocarbyl radical,
- R1 each, independently, is the same or different and is a hydrogen atom or a monovalent, optionally substituted hydrocarbyl radical,
- R2 each, independently, is may be the same or different and is a hydrogen atom or a monovalent, optionally substituted hydrocarbyl radical,
- x is 0 or 1,
- a each, independently, is the same or different and is 0, 1 or 2
- and
- b each, independently, is the same or different and is an integer from 1 to 10,
- with the proviso that component (A) includes less than 15 mol % of polymers of the formula (I) with x=1,
- and
- (B) 5 to 500 parts by weight of at least one silane-crosslinking polymer of the formula
- R6—O—Z—[O—CO—NH—(CR42)d—SiR3c(OR5)3-c]1-y[OH]y (II)
- where
- Z is a divalent polymer radical having no hydroxyl group,
- R3 each, independently, is the same or different and is a monovalent, optionally substituted hydrocarbyl radical,
- R4 each, independently, is the same or different and is a hydrogen atom or a monovalent, optionally substituted hydrocarbyl radical,
- R5 each, independently, is the same or different and is a hydrogen atom or a monovalent, optionally substituted hydrocarbyl radical,
- R6 each, independently, is monovalent, optionally substituted hydrocarbyl radical,
- y is 0 or 1,
- c each, independently, is the same or different and is 0, 1 or 2
- and
- d may be the same or different and is an integer from 1 to 10,
- (C) 0.1 to 10 parts by weight of organosilicon compounds containing nitrogen atoms not bonded to a carbonyl group;
- (D) 50 to 500 parts by weight of filler(s), and
- (I) 0.01 to 100 parts by weight of unreactive plasticizers,
- with the provisos that component (A) contains less than 10 mol % of polymers of the formula (I) with x=1, and that component (B) includes less than 10 mol % of polymers of the formula (II) with y=1.
26 more elements
Dependencies are inferred from the claim text.