Low-Viscosity Solutions of Alkaline-Earth Metal Alkoxides In Aprotic Solvents, Method for the Production of Same and Use for the Production of Ziegler-Natta Catalysts
AssigneeAlbemarle Germany GmbH
InventorsUlrich WIETELMANN, Ute EMMEL, Armin STOLL, Florian KIEFER
Life of this patent
Estimating the term…
Abstract
One or more concentrated low-viscosity solutions of alkaline earth alkoxide compounds M(OCH2R6)2-a-b(OR7)a[O(CHR8)OR9]b in mixture with a metal alkyl compound M(R10R11) in an aprotic solvent and related methods are disclosed herein.
Claims24
1-15. (canceled)
A solution of alkaline earth alkoxide compounds M(OCH2R6)2-a-b(OR7)a[O(CHR8)nOR9]b in mixture with a metal alkyl compound M(R10R11) with an alkaline earth metal concentration in the range of 0.2 to 1.8 mmol/g in an aprotic solvent, wherein
- M is an alkaline earth metal selected from the group consisting of Mg, Ca, Ba, and Sr;
- OCH2R6 is an alkoxide radical consisting of at least 3 and at most 40 carbon atoms with a branch in position 2 relative to the O function;
- R7 is an alkyl radical with 2-15 carbon atoms, which is either linear or has a branch in ≧position 3 relative to the O function;
- R8 is an alkyl radical with 1 to 6 carbon atoms, which is either linear or has a branch at ≧position 3 (relative to the O function;
- R9 is an alkyl radical with 2 to 15 carbon atoms, which is either linear or has a branch;
- R10 and R11 are any alkyl radicals with 1 to 15 carbon atoms;
- n is an integer from 1 to 4;
- a+b≦2 wherein a and b each have a value of 0 to 2;
- and
- the solution has a molar ratio of M(OCH2R6)2-a-b(OR7)a[O(CHR8)nOR9]b to M(R10R11) that is from 99.5:0.5 to 60:40.
A method for synthesis of alkaline earth alkoxide compounds M(OCH2R6)2-a-b(OR7)a[O(CHR8)nOR9]b in mixture with a metal alkyl compound M(R10R11) the method comprising:
- mixing an alkaline earth metal or an alkaline earth metal mixture in an aprotic solvent with an alcohol HO(CHR8)nOR9 under reaction conditions sufficient to produce a first reaction mixture, and
- adding a solution of a metal alkyl compound M(R10R11) to the first reaction mixture, wherein the molar ratio of M(OCH2R6)2-a-b(OR7)a[O(CHR8)nOR9]b to M(R10R11), is from 99.5:0.5 to 60:40.
A method for synthesis of alkaline earth alkoxide compounds M(OCH2R6)2-a-b(OR7)a[O(CHR8)nOR9]b in mixture with a metal alkyl compound M(R10R11), the method comprising:
- mixing a solution of the metal alkyl compound M(R10R11) in an aprotic solvent with one or more alcohols selected from the group of HOCH2R6, HOR7, HO(CHR8)nOR9, and any mixture thereof, wherein half of the molar ratio of the total number of moles of all alcohols to the metal alkyl compound is from 99.5:0.5 to 60:40.
Dependencies are inferred from the claim text.