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AssigneeShenzhen Institutes of Advanced Technology
InventorsHuaiyu WANG, Yuetao ZHAO, Xuefeng YU
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The present invention provides a titanium ligand-modified black phosphorus and the preparation method and use thereof. The titanium ligand-modified black phosphorus is a complex of black phosphorus and a titanium ligand having a structure represented by formula (I): wherein in the formula (I), R1 comprises C1-C6 alkyl, or phenyl optionally further substituted with 0 to 5 groups each independently selected from halogen atom, C1-C6 alkyl, nitro, hydroxy, amino or C1-C3 alkoxy; the C1-C6 alkyl or C1-C3 alkoxy is optionally further substituted with 0 to 3 groups each independently selected from halogen atom, nitro, hydroxy, amino, methyl, ethyl or n-propyl. The titanium ligand-modified black phosphorus of the present invention is not likely oxidized without changing inherent properties of the black phosphorus, and the antioxidant capacity is greatly enhanced.
A titanium ligand-modified black phosphorus, which is a complex of black phosphorus and a titanium ligand having a structure represented by formula (I):
The composition according 9, wherein, the halogen atom is fluorine atom.
The composition according 9, wherein, the titanium ligand comprises:
A composition according 9, wherein the black phosphorus comprises one or more of black phosphorous bulk material, multilayered black phosphorous nanosheet, monolayer black phosphorous nanosheet and black phosphorus quantum dot;
The use according to 13, wherein, the halogen atom is fluorine atom.
The use according to 13, wherein, the titanium ligand comprises:
The use according to 13, wherein the black phosphorus comprises one or more of black phosphorous bulk material, multilayered black phosphorous nanosheet, monolayer black phosphorous nanosheet and black phosphorus quantum dot;
The use according to 17, wherein, the halogen atom is fluorine atom.
The use according to 17, wherein, the titanium ligand comprises:
The use according to 17, wherein the black phosphorus comprises one or more of black phosphorous bulk material, multilayered black phosphorous nanosheet, monolayer black phosphorous nanosheet and black phosphorus quantum dot;
Dependencies are inferred from the claim text.