# US 2016/0355404 A1 · Process for converting oxygenated gas into carbon monoxide

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- Number: US 2016/0355404 A1
- Document ID: US20160355404A1
- Status: Published application
- Kind: A1
- Application number: 15/175,016
- Filed: 2016-06-06
- Published: 2016-12-08
- Earliest claimed: 2015-06-04
- Inventors: Schams A. Ahad
- Web page: https://patentgrep.com/patent/US20160355404A1

## CPC

- C01B 32/50: Carbon dioxide
- C01B 32/40: Carbon monoxide
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}

## Abstract

A process for a gas phase thermochemical reduction of oxygenated gas, such as carbon dioxide (CO2), by a solid activated charcoal to obtain premium grade, very high purity, carbon monoxide (CO) product. Whereby granular activated carbon (GAC) or powdered activated carbon (PAC) via a high temperature Reverse Boudouard Reduction Reaction (RBRR) using an oxygen exchange mechanism (OEM), is used to yield the carbon monoxide (CO) product in both a non-catalytic and a catalytic reactor.

## Claims

### Claim 1

A process comprising:
directing carbon dioxide into a mixer;
releasing an activated carbon from a storage bin for combining with said carbon dioxide, wherein said activated carbon comprises a biomass charcoal;
combining, with said mixer, said carbon dioxide with said activated carbon;
feed stocking said mixed activated carbon and carbon dioxide to a Reverse Boudouard Reduction reactor unit;
heating said Reverse Boudouard Reduction reactor unit containing said mixed activated carbon and carbon dioxide with a high temperature furnace to produce a carbon monoxide product, wherein a steel forge grade renewable charcoal fuel is configured to provide a first source of fuel for said high temperature furnace;
filtering said carbon monoxide product in a high temperature bag house, wherein said filtering is configured to remove at least a portion of entrained activated carbon particles, and wherein said carbon monoxide product is substantially a result of a Reverse Boudouard Reaction from said reactor unit;
splitting said filtered carbon monoxide product into a first carbon monoxide product stream and second carbon monoxide product stream;
conveying at least a portion of said first carbon monoxide product stream back to said high temperature furnace, wherein said first carbon monoxide product stream is configured to provide at least a portion of a second source of fuel for said high temperature furnace;
directing a substantial portion of said second carbon monoxide product stream to a heat exchanger, said heat exchanger being configured to be operable for cooling said second carbon monoxide product stream.

### Claim 2 (depends on 1)

The process of claim 1, further comprising compressing said cooled first carbon monoxide product stream in a compressor unit.

### Claim 3 (depends on 2)

The process of claim 2, further comprising piping said cooled and compressed first carbon monoxide product stream to a product storage tank.

### Claim 4 (depends on 3)

The process of claim 3, further comprising purging an off-specification carbon monoxide product to an emergency product vent, wherein said off-specification carbon monoxide product is caused by at least one of, a process upset, a discontinuity and a failure to meet design operating condition.

### Claim 5 (depends on 1)

The process of claim 1, further comprising disposing said entrained activated carbon particles into a sanitary landfill.

### Claim 6 (depends on 3)

The process of claim 3, wherein said carbon monoxide product is configured to provide renewable fuel.

### Claim 7 (depends on 1)

The process of claim 1, in which said activated carbon comprising, at least one of, a granular activated carbon (GAC), a powdered activated carbon (PAC), and a mixture of both GAC and PAC.

### Claim 8 (depends on 1)

The process of claim 1, further comprising adding a catalyst in said Reverse Boudouard Reaction reactor unit, wherein said catalyst is configured to maintain a high reactivity of reactants such that said carbon monoxide product dominates a product stream, and wherein said catalyst is further configure to lower a temperature of said reaction thereby decreasing the amount of energy used to complete said reaction and consequently lower an operating cost of said process.

### Claim 9 (depends on 1)

The process of claim 1, further comprising providing heat to said high temperature furnace with steel forge grade renewable charcoal fuel.

### Claim 10

A system comprising:
means for mixing an amount of carbon dioxide with an amount of activated carbon;
means for heating a Reverse Boudouard Reduction reactor unit containing said mixed activated carbon and carbon dioxide to produce a carbon dioxide product, wherein said heating means is configured to operate with renewable fuel;
means for filtering said carbon monoxide, wherein said filtering means is configured to remove entrained activated carbon particles, and wherein said carbon monoxide product is a result of a Reverse Boudouard Reaction from said reactor unit;
means for splitting said filtered carbon monoxide product into a first carbon monoxide product stream and second carbon monoxide product stream;
means for conveying said first carbon monoxide product stream back to said high temperature furnace;
means for cooling said second carbon monoxide product stream;
means for directing said second carbon monoxide product stream to said cooling means.

### Claim 11 (depends on 10)

The process of claim 10, further comprising means for compressing said cooled second carbon monoxide product stream.

### Claim 12 (depends on 11)

The process of claim 11, further comprising means for piping said compressed carbon monoxide product to a product storage tank.

### Claim 13

A process comprising:
directing an oxygenated gas into a mixer;
releasing an activated carbon from a storage bin;
mixing said oxygenated gas with said released activated carbon in said mixer;
feed stocking said mixed activated carbon and said oxygenated gas to a Reverse Boudouard Reduction reactor unit;
heating said Reverse Boudouard Reduction reactor unit containing said mixed activated carbon and said oxygenated gas with a high temperature furnace, in which said heating is configured to produce a reduced Oxide product, wherein a renewable charcoal fuel is configured to provide a first source of fuel for said high temperature furnace;
filtering said reduced Oxide product in a high temperature bag house, wherein said filtering is configured to remove entrained activated carbon particles, and
wherein said reduced Oxide product is a result of a Reverse Boudouard Reaction from said reactor unit;
splitting said filtered reduced Oxide product into a first reduced Oxide product stream and second reduced Oxide product stream;
conveying said first reduced Oxide product stream back to said high temperature furnace, wherein said first reduced Oxide product stream is configured as a second source of fuel for said high temperature furnace;
directing said at least a portion of second reduced Oxide product stream to a heat exchanger, wherein said heat exchanger is configure to cool said second reduced Oxide product.

### Claim 14 (depends on 13)

The process of claim 13, wherein said oxygenated gas is carbon dioxide and said reduced Oxide is carbon monoxide.

### Claim 15 (depends on 14)

The process of claim 14, further comprising compressing said second cooled second carbon monoxide product stream in a compressor unit.

### Claim 16 (depends on 15)

The process of claim 15, further comprising piping said compressed second carbon monoxide product stream to a product storage tank.

### Claim 17 (depends on 16)

The process of claim 16, further comprising purging an off-specification carbon monoxide product to an emergency product vent, wherein said off-specification carbon monoxide product is caused by, at least one of, a process upset, a discontinuity and a failure to meet design operating conditions.

### Claim 18 (depends on 14)

The process of claim 14, further comprising disposing said entrained activated carbon particles.

### Claim 19 (depends on 14)

The process of claim 14, in which said activated carbon comprising, at least one of, a granular activated carbon (GAC), a powdered activated carbon (PAC), and a mixture of both GAC and PAC.

### Claim 20 (depends on 14)

The process of claim 14, further comprising adding a catalyst in said Reverse Boudouard Reaction reactor unit, wherein said catalyst is configured to maintain a high reactivity of reactants such that said carbon monoxide product dominates a product stream, and wherein said catalyst is further configured to lower a temperature of said reaction thereby decreasing the amount of energy used to complete said reaction and consequently lower an operating cost of said process.
