# US 2016/0252811 A1 · Optical waveguide photosensitive resin composition, photocurable film for forming optical waveguide core layer, optical waveguide using same, and mixed flexible printed circuit board for optical/electrical transmission

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 2016/0252811 A1
- Document ID: US20160252811A1
- Status: Published application
- Kind: A1
- Application number: 15/030,782
- Filed: 2014-10-24
- Published: 2016-09-01
- Earliest claimed: 2013-11-08
- Assignees: Nitto Denko Corporation
- Applicants: Nitto Denko Corporation
- Inventors: Tomoyuki Hirayama
- Web page: https://patentgrep.com/patent/US20160252811A1

## CPC

- G03F 7/038: Macromolecular compounds which are rendered insoluble or differentially wettable (G03F7/075 takes precedence; macromolecular azides G03F7/012; macromolecular diazonium compounds G03F7/021)
- C08G 59/68: characterised by the catalysts used
- C08L 101/00: Compositions of unspecified macromolecular compounds
- G02B 6/13: Integrated optical circuits characterised by the manufacturing method
- G02B 6/138: by using polymerisation
- G02B 6/4281: {the printed circuit boards being flexible (in general H05K1/147)}
- G03F 7/0005: {Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor}
- G03F 7/0045: {with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors}
- G02B 2006/12069: {Organic material}
- H05K 1/0274: {Optical details, e.g. printed circuits comprising integral optical means (H05K1/0269 takes precedence; coupling light guides with opto-electronic components G02B6/42)}
- H05K 3/287: {Photosensitive compositions}
- G03F: PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR; (phototypographic composing devices B41B; photosensitive materials or processes for photographic purposes G03C; electrophotography, sensitive layers or processes therefor G03G)
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- H05K: PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS

## Abstract

Provided is an optical waveguide photosensitive resin composition containing a photocurable resin and a photopolymerization initiator, in which the photopolymerization initiator is a specific photoacid generator represented by the general formula (1). Accordingly, when a core layer is formed by using the optical waveguide photosensitive resin composition as a material for forming an optical waveguide, especially a core layer-forming material, excellent high transparency (low loss effect) is obtained. In the formula (1), R1 and R2 each represent hydrogen or an alkyl group having 1 to 15 carbon atoms, and may be identical to or different from each other.

## Claims

### Claim 1

An optical waveguide photosensitive resin composition, comprising:
a photocurable resin; and
a photopolymerization initiator,
wherein the photopolymerization initiator comprises a photoacid generator represented by the following general formula (1):
in the formula (1), R1 and R2 each represent hydrogen or an alkyl group having 1 to 15 carbon atoms, and may be identical to or different from each other.

### Claim 2 (depends on 1)

The optical waveguide photosensitive resin composition according to claim 1, wherein a content of the photopolymerization initiator is from 0.1 part by weight to 3 parts by weight with respect to 100 parts by weight of the photocurable resin.

### Claim 3 (depends on 1)

The optical waveguide photosensitive resin composition according to claim 1, wherein the photocurable resin is in a solid state at 25° C.

### Claim 4 (depends on 1)

The optical waveguide photosensitive resin composition according to claim 1, wherein the optical waveguide photosensitive resin composition is a core layer-forming material in an optical waveguide including a base material, a cladding layer formed on the base material, and a core layer configured to propagate an optical signal, the core layer being formed in the cladding layer in a predetermined pattern.

### Claim 5 (depends on 1)

A photocurable film for forming an optical waveguide core layer, which is obtained by forming the optical waveguide photosensitive resin composition of claim 1 into a film shape.

### Claim 6 (depends on 1)

An optical waveguide, comprising:
a base material:
a cladding layer formed on the base material; and
a core layer configured to propagate an optical signal, the core layer being formed in the cladding layer in a predetermined pattern,
wherein the core layer is formed by curing the optical waveguide photosensitive resin composition of claim 1.

### Claim 7 (depends on 6)

A mixed flexible printed circuit board for optical/electrical transmission, comprising the optical waveguide of claim 6.

### Claim 8 (depends on 5)

An optical waveguide, comprising:
a base material;
a cladding layer formed on the base material; and
a core layer configured to propagate an optical signal, the core layer being formed in the cladding layer in a predetermined pattern,
wherein the core layer is formed by curing the photocurable film for forming the optical waveguide core layer of claim 5.

### Claim 9 (depends on 8)

A mixed flexible printed circuit board for optical/electrical transmission, comprising the optical waveguide of claim 8.
