# US 2016/0252784 A1 · Liquid crystal display device

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- Number: US 2016/0252784 A1
- Document ID: US20160252784A1
- Status: Published application
- Kind: A1
- Application number: 15/150,740
- Filed: 2016-05-10
- Published: 2016-09-01
- Earliest claimed: 2013-05-22
- Assignees: DIC Corporation
- Applicants: Dic Corporation
- Inventors: Shinji Ogawa; Yoshinori Iwashita; Makoto Negishi
- Web page: https://patentgrep.com/patent/US20160252784A1

## CPC

- G02F 1/134309: {characterised by their geometrical arrangement}
- C09K 19/12: at least two benzene rings directly linked, e.g. biphenyls
- C09K 19/3003: {Compounds containing at least two rings in which the different rings are directly linked (covalent bond)}
- C09K 19/42: Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40
- C09K 19/44: containing compounds with benzene rings directly linked
- G02F 1/1337: Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
- G02F 1/134336: {Matrix}
- G02F 1/13439: {characterised by their electrical, optical, physical properties; materials therefor; method of making}
- G02F 1/136286: {Wiring, e.g. gate line, drain line}
- G02F 1/1368: in which the switching element is a three-electrode device {(G02F1/136277 takes precedence)}
- C09K 2019/122: {Ph-Ph}
- C09K 2019/123: {Ph-Ph-Ph}
- C09K 2019/3004: {Cy-Cy}
- C09K 2019/3009: {Cy-Ph}
- C09K 2019/301: {Cy-Cy-Ph}
- C09K 2019/3016: {Cy-Ph-Ph}
- C09K 2019/3027: {Compounds comprising 1,4-cyclohexylene and 2,3-difluoro-1,4-phenylene}
- G02F 1/133738: {for homogeneous alignment}
- G02F 1/134372: {for fringe field switching [FFS] where the common electrode is not patterned}
- G02F 1/13712: {the liquid crystal having negative dielectric anisotropy}
- G02F 2201/40: Arrangements for improving the aperture ratio
- G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

## Abstract

The present invention provides an FFS mode liquid crystal display device that uses a liquid crystal composition which has a negative dielectric anisotropy and can achieve good display properties by being used for FFS mode liquid crystal display devices without degrading the image sticking property of display devices and various properties of liquid crystal display devices, such as dielectric anisotropy, viscosity, nematic phase upper limit temperature, low-temperature nematic phase stability, and γ1. The liquid crystal composition contains at least one compound selected from the group of compounds represented by general formula (I) below and at least one compound selected from the group of compounds represented by general formula (II) below.

## Claims

### Claim 1

An FFS mode liquid crystal display device comprising a first transparent insulating substrate and a second transparent insulating substrate disposed so as to face each other; a liquid crystal layer containing a liquid crystal composition and sandwiched between the first transparent insulating substrate and the second transparent insulating substrate;
a common electrode composed of a transparent conductive material and disposed on the first transparent insulating substrate; a plurality of gate bus lines and a plurality of data bus lines disposed on the first transparent insulating substrate so as to form a matrix;
a thin film transistor disposed at each of intersections of the gate bus lines and the data bus lines; a pixel electrode composed of a transparent conductive material and driven by the transistor, the thin film transistor and the pixel electrode being included in each pixel; and
alignment films that induce homogeneous alignment and are disposed between the liquid crystal layer and the first transparent insulating substrate and between the liquid crystal layer and the second transparent insulating substrate, alignment directions of the alignment films being parallel to each other,
wherein an interelectrode distance R between the pixel electrode and the common electrode is smaller than a distance G between the first transparent insulating substrate and the second transparent insulating substrate so that a fringing field is formed between the pixel electrode and the common electrode,
the common electrode is disposed on substantially an entire surface of the first transparent insulating substrate so as to be closer to the first transparent insulating substrate than the pixel electrode, and
the liquid crystal composition has a negative dielectric anisotropy, a nematic phase-isotropic liquid phase transition temperature of 60° C. or higher, and an absolute value of dielectric anisotropy of 2 or more, the liquid crystal composition having a refractive index anisotropy Δn of 0.10 or more, and
the liquid crystal composition comprises: at least one compound selected from the group of compounds represented by general formula (I), at least one compound selected from the group of compounds represented by general formula (II); and one or more of compounds represented by general formula (IV),
wherein in the general formula (I), R1 and R2 each independently represent an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms; A represents a trans-1,4-cyclohexylene group; k represents 1; and when k represents 2, two A may be the same or different),
wherein in the general formula (II), R3 represents an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms; R4 represents an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 4 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, or an alkenyloxy group having 3 to 8 carbon atoms; B represents a 1,4-phenylene group or a trans-1,4-cyclohexylene group; m represents 0, 1, or 2; and when m represents 2, two B may be the same or different,
wherein the general formula (IV), R7 and R8 each independently represent an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms; one or more hydrogen atoms in the alkyl group, the alkenyl group, the alkoxy group, or the alkenyloxy group may be substituted with fluorine atoms; a methylene group in the alkyl group, the alkenyl group, the alkoxy group, or the alkenyloxy group may be substituted with an oxygen atom as long as oxygen atoms do not directly bond to each other and may be substituted with a carbonyl group as long as carbonyl groups do not directly bond to each other;
A1 and A2 each independently represent a 1,4-cyclohexylene group, a 1,4-phenylene group, or a tetrahydropyran-2,5-diyl group; when A1 and/or A2 represents a 1,4-phenylene group, one or more hydrogen atoms in the 1,4-phenylene group may be substituted with fluorine atoms;
Z1 and Z2 each independently represent a single bond, —OCH2—, —OCF2—, —CH2O—, or CF2O—;
n1 and n2 each independently represent 0, 1, 2, or 3 and n1+n2 is 1 to 3; when a plurality of A1, A2, Z1, and/or Z2 are present, A1, A2, Z1, and/or Z2 may be the same or different, wherein the general formula (IV) excludes a compound in which n1 represents 1 or 2, n2 represents 0, A1 represents a 1,4-cyclohexylene group, and all Z1 represent single bonds.

### Claim 2 (depends on 1)

The liquid crystal display device according to claim 1, wherein the compounds represented by the general formula (I) include at least one compound selected from the group of compounds represented by general formula (III) below,
(in the formula, R5 represents a hydrogen atom or a methyl group and R6 represents an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms).

### Claim 3 (depends on 1)

The liquid crystal composition according to claim 1, wherein the compounds represented by the general formula (IV) include at least one compound selected from the group of compounds represented by general formula (IVa1) and general formula (IVa2) below,
(in the formula, R7a1, R7a2, R8a1, and R8a2 each independently represent an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms; one or more hydrogen atoms in the alkyl group, the alkenyl group, the alkoxy group, or the alkenyloxy group may be substituted with fluorine atoms; a methylene group in the alkyl group, the alkenyl group, the alkoxy group, or the alkenyloxy group may be substituted with an oxygen atom as long as oxygen atoms do not directly bond to each other and may be substituted with a carbonyl group as long as carbonyl groups do not directly bond to each other;
na2 represents 0 or 1; A1a2 represents a 1,4-cyclohexylene group, a 1,4-phenylene group, or a tetrahydropyran-2,5-diyl group; and one or more hydrogen atoms in the 1,4-phenylene group in the general formula (IVa1) and the general formula (IVa2) may be substituted with fluorine atoms).

### Claim 4 (depends on 1)

The liquid crystal display device according to claim 1, wherein the pixel electrode is a comb-shaped pixel electrode or a pixel electrode having a slit.

### Claim 5 (depends on 1)

The liquid crystal display device according to claim 1, wherein the total content of the compounds represented by the general formula (I), the general formula (II), and the general formula (IV) in the liquid crystal composition is 90 to 100 mass %.

### Claim 6 (depends on 1)

The liquid crystal display device according to claim 1, wherein the liquid crystal composition has a refractive index anisotropy Δn of 0.10 to 0.12.

### Claim 7 (depends on 1)

The liquid crystal display device according to claim 1 wherein the interelectrode distance (R) is 0.

### Claim 8 (depends on 1)

The liquid crystal display device according to claim 1 wherein the total content of the compounds represented by the general formula (I), the general formula (II), and the general formula (IV) in the liquid crystal composition is 80 to 100 mass %.