# US 2016/0244377 A1 · Fluid ionized compositions, methods of preparation and uses thereof

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- Number: US 2016/0244377 A1
- Document ID: US20160244377A1
- Status: Published application
- Kind: A1
- Application number: 15/145,698
- Filed: 2016-05-03
- Published: 2016-08-25
- Earliest claimed: 2011-11-30
- Assignees: Bi-En Corp.
- Applicants: Bi-En Corp.
- Inventors: Richard O. Hartmann
- Web page: https://patentgrep.com/patent/US20160244377A1

## CPC

- C05C 1/00: Ammonium nitrate fertilisers
- C05B 7/00: Fertilisers based essentially on alkali or ammonium orthophosphates (C05B11/00 takes precedence)
- C05B 17/00: Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
- C05C 3/00: Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
- C05C 5/04: containing calcium nitrate
- C05C 7/00: Fertilisers containing calcium or other cyanamides
- C05C 9/00: Fertilisers containing urea or urea compounds
- C05D 3/02: from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
- C05D 9/02: containing trace elements
- C05F 3/00: Fertilisers from human or animal excrements, e.g. manure
- C05G 5/23: Solutions
- C05G 5/27: Dispersions, e.g. suspensions or emulsions
- C05C 5/00: Fertilisers containing other nitrates
- Y02A 40/20: Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
- Y02P 20/145: the feedstock being materials of biological origin
- Y02W 10/37: using solar energy
- C05C: NITROGENOUS FERTILISERS
- C05B: PHOSPHATIC FERTILISERS
- C05D: INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05F: ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05G: MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS (organic fertilisers containing added bacterial cultures, mycelia, or the like C05F11/08; organic fertilisers containing plant vitamins or hormones C05F11/10); FERTILISERS CHARACTERISED BY THEIR FORM
- Y02A: TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02W: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT

## Abstract

Disclosed herein are fluid ionized compositions, such as fluid calcium cyanamide fertilizer compositions, methods of preparation and uses thereof. In some examples, a fluid composition includes a mixture of about 40 to 20 parts of dissolved acid or acid-formed approximately neutral pH nitrogen plant nutrient compounds (such as urea ammonium nitrate and H2O) and about 1 to about 5 parts of a mixture of insoluble or weakly soluble high pH calcium-formed plant nutrient compounds (such as calcium cyanamide and H2O). The disclosed compositions and methods stabilize the compositions' contained active nutrient ions and digested carbon. The disclosed compositions and methods facilitate controllable site-directed delivery of the contents of the compositions. The compositions and methods are effective for microbes nourishment plant fertilizing, soil amending, heavy metals leaching inhibition, and digesting organic proteinaceous excreta. The compositions are stable, easily calibrated, and non-clogging for soil injection, spray and irrigation water delivery to target sites.

## Claims

### Claim 1

A method of enhancing plant growth, comprising:
applying quantum harmonic resonance to a sprayable fluid composition, wherein the sprayable fluid composition comprises:
mixture of about 40 to 20 parts of dissolved acid or acid-formed approximately neutral pH nitrogen plant nutrient compounds and about 1 to about 5 parts of a mixture of insoluble or weakly soluble high pH calcium-formed plant nutrient compounds,
wherein the dissolved acid comprises nitric acid, phosphoric acid, a weak carbonic acid or a combination thereof and the acid-formed nitrogen plant nutrient compounds are in solution and comprise fluid ammonium nitrate (UAN), ammonium nitrate, or calcium ammonium nitrate, ammonium phosphate, high pH aqueous ammonia or combinations thereof; and
the insoluble or weakly soluble high pH calcium-formed plant nutrient compounds are in solution and comprise H2O and lime nitrogen; and
applying an effective amount of the sprayable fluid composition to soil prior to, during and/or after planting, thereby enhancing plant growth.

### Claim 2 (depends on 1)

The method of claim 1, wherein the H2O present in the sprayable fluid composition comprises at least 14× the mass of the insoluble or weakly soluble high pH calcium formed plant nutrient compounds to soil prior to, during and/or after planting, thereby enhancing plant growth.

### Claim 3 (depends on 2)

The method of claim 2, wherein applying an effective amount comprises applying the composition by spraying, soil shank injecting or sprinkler or drip irrigation.

### Claim 4 (depends on 2)

The method of claim 2, wherein the insoluble or weakly soluble high pH calcium formed plant nutrient comprises lime nitrogen.

### Claim 5 (depends on 2)

The method of claim 2, wherein the fluid composition comprises particles of with an about 60 to about 100 mesh pass through screen size.

### Claim 6

A method of enhancing plant growth, comprising:
exposing a plant to sound prior to, during and/or following treatment with a sprayable fluid composition, wherein the sprayable fluid composition comprises:
mixture of about 40 to 20 parts of dissolved acid or acid-formed approximately neutral pH nitrogen plant nutrient compounds and about 1 to about 5 parts of a mixture of insoluble or weakly soluble high pH calcium-formed plant nutrient compounds,
wherein the dissolved acid comprises nitric acid, phosphoric acid, a weak carbonic acid or a combination thereof and the acid-formed nitrogen plant nutrient compounds are in solution and comprise fluid ammonium nitrate (UAN), ammonium nitrate, or calcium ammonium nitrate, ammonium phosphate, high pH aqueous ammonia or combinations thereof; and
the insoluble or weakly soluble high pH calcium-formed plant nutrient compounds are in solution and comprise H2O and lime nitrogen, thereby enhancing plant growth.

### Claim 7 (depends on 6)

The method of claim 6, wherein sound comprises low frequency sound of less than 4,000 Hertz.

### Claim 8 (depends on 6)

The method of claim 6, wherein the H2O present in the sprayable fluid composition comprises at least 14× the mass of the insoluble or weakly soluble high pH calcium formed plant nutrient compounds to soil prior to, during and/or after planting, thereby enhancing plant growth.

### Claim 9 (depends on 6)

The method of claim 6, wherein treatment with a sprayable composition comprises applying the composition by spraying, soil shank injecting or sprinkler or drip irrigation.

### Claim 10 (depends on 6)

The method of claim 6, wherein the insoluble or weakly soluble high pH calcium formed plant nutrient comprises lime nitrogen.

### Claim 11 (depends on 2)

The method of claim 2, wherein the fluid composition comprises particles of with an about 60 to about 100 mesh pass through screen size.

### Claim 12

A method of making a sprayable fluid composition, comprising:
combining in the presence of a circulation process a mixture of about 40 to 20 parts of dissolved acid or acid-formed approximately neutral pH, H2O containing nitrogen plant nutrient compounds to about 1 to about 5 parts of a mixture of insoluble or weakly soluble high pH calcium-formed plant nutrient compounds,
wherein the dissolved acid comprises nitric acid, phosphoric acid, a weak carbonic acid or a combination thereof and the acid-formed nitrogen plant nutrient compounds are in solution and comprise fluid urea ammonium nitrate (UAN), ammonium nitrate, or calcium ammonium nitrate; and
the insoluble or weakly soluble high pH calcium-formed plant nutrients are in solution and comprise H2O and lime nitrogen, thereby forming a fluid composition.

### Claim 13 (depends on 12)

The method of claim 12, wherein the circulation process comprises a venturi by-pass system.

### Claim 14 (depends on 13)

The method of claim 13, where the dissolved acid or acid-formed approximately neutral pH nitrogen plant nutrient compounds comprises a urea ammonium nitrate (UAN), where the UAN solution comprises about 30% to about 35% urea, about 40% to about 45% ammonium nitrate with the residual as H2O.

### Claim 15 (depends on 13)

The method of claim 13, where the H2O present in the fluid mixture comprises less than 14× the mass of the insoluble or weakly soluble high pH calcium formed plant nutrient compounds in the mixture.

### Claim 16 (depends on 13)

The method of claim 13, where the H2O present in the fluid mixture comprises at least 14× the mass of the insoluble or weakly soluble high pH calcium formed plant nutrient compounds in the mixture.

### Claim 17 (depends on 13)

The method of claim 13, further comprising adding at least one non-nitrogen material to the composition.

### Claim 18 (depends on 17)

The method of claim 17, wherein the non-nitrogen material is a plant nutrient, phosphorous, potassium, iron, copper, zinc, manganese, boron, magnesium, molybdenum, sulfur, magnesium, nickel, and mixtures thereof.

### Claim 19 (depends on 13)

The method of claim 13, further comprising adding excreta, such as liquidized manure, dairy excreta, to the composition.

### Claim 20 (depends on 13)

The method of claim 13, wherein the method is performed in an opened or unsealed container.

### Claim 21 (depends on 13)

The method of claim 13, where the method is performed in the presence of atmospheric CO2.

### Claim 22 (depends on 12)

The method of claim 12, further comprising dehydrating the fertilizer composition to form a solid.

### Claim 23

A method of composting, comprising:
exposing organic matter to an effective amount of a sprayable fluid composition, wherein the sprayable fluid composition comprises:
mixture of about 40 to 20 parts of dissolved acid or acid-formed approximately neutral pH nitrogen plant nutrient compounds and about 1 to about 5 parts of a mixture of insoluble or weakly soluble high pH calcium-formed plant nutrient compounds,
wherein the dissolved acid comprises nitric acid, phosphoric acid, a weak carbonic acid or a combination thereof and the acid-formed nitrogen plant nutrient compounds are in solution and comprise fluid ammonium nitrate (UAN), ammonium nitrate, or calcium ammonium nitrate, ammonium phosphate, high pH aqueous ammonia or combinations thereof; and
the insoluble or weakly soluble high pH calcium-formed plant nutrient compounds are in solution and comprise H2O and lime nitrogen, thereby decomposing the organic matter.

### Claim 24 (depends on 23)

The method of claim 23, wherein the organic matter is soil or excreta containing proteinaceous matter.

### Claim 25 (depends on 24)

The method of claim 24, wherein the method is used to convert soil or excreta containing proteinaceous matter into a nitrogen source.