Resin composition and molded article thereof
AssigneeAsahi Kasei Kabushiki Kaisha
InventorsShunichiro I, Mihoko YAMAMOTO
Life of this patent
Estimating the term…
Abstract
The resin composition of the present invention comprises (a) a polypropylene-based resin, (b) a polyphenylene ether-based resin, and (c) a first hydrogenated block copolymer-based resin and further comprises (d) an ethylene-α-olefin copolymer rubber and/or (e) a second hydrogenated block copolymer-based resin.
Claims19
A resin composition comprising (a) a polypropylene-based resin, (b) a polyphenylene ether-based resin, and (c) a first hydrogenated block copolymer-based resin, and further comprising (d) an ethylene-α-olefin copolymer rubber and/or (e) a second hydrogenated block copolymer-based resin, wherein
- each of the components (c) and (e) is a hydrogenated block copolymer prepared by hydrogenating a block copolymer comprising at least one polymer block A composed mainly of a vinyl aromatic compound and at least one polymer block B composed mainly of a conjugated diene compound, and/or a modified product of the hydrogenated block copolymer,
- a total ratio of a 1,2-vinyl bond and a 3,4-vinyl bond to all bonds in the conjugated diene compound units in the component (c) is 45 to 90%,
- the component (c) comprises 30 to 50% by mass of the vinyl aromatic compound units,
- a total ratio of a 1,2-vinyl bond and a 3,4-vinyl bond to all bonds in the conjugated diene compound units in the component (e) is 25% or more and less than 60%,
- a rate of hydrogenation of ethylenic double bonds (double bonds in the conjugated diene compound units) in the block copolymer in the component (c) is 80 to 100%, and
- a rate of hydrogenation of ethylenic double bonds (double bonds in the conjugated diene compound units) in the block copolymer in the component (e) is 10% or higher and lower than 80%.
A resin composition comprising (a) a polypropylene-based resin, (b) a polyphenylene ether-based resin, and (c) a hydrogenated block copolymer-based resin, wherein
- the component (c) is a hydrogenated block copolymer prepared by hydrogenating a block copolymer comprising at least one polymer block A composed mainly of a vinyl aromatic compound and at least one polymer block B composed mainly of a conjugated diene compound, and/or a modified product of the hydrogenated block copolymer, and
- a ratio of a loss tangent at −50° C. (−50° C. tan δ) to a loss tangent at 0° C. (0° C. tan δ) (−50° C. tan δ/0° C. tan δ) obtained by the following measurement method is 0.39 or more;
- <Measurement of loss tangent (tan δ)>
- the loss tangent (tan δ) of an ISO test piece obtained from the resin composition is measured at −50° C. and 0° C. using a viscoelasticity measuring machine at a tensile mode under temperature sweep conditions involving an oscillation frequency of 10 Hz, a strain of 0.2% under static stress, a strain of 0.1% under dynamic stress, a contact load of 0.5 N, a rate of temperature rise of 3° C./min, and a temperature range of −100° C. to 160° C.
Dependencies are inferred from the claim text.