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US 2016/0237265 A1Published application
Polyethylene composition having high swell ratio
AssigneeBasell Polyolefine GmbH
InventorsIakovos Vittorias, Jens Wiesecke, Bernd Lothar Marczinke, Gerhardus Meier, Ulf Schüller, Volker Dolle, Johannes-Friedrich Enderle, Dieter Lilge, Barbara Gall
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Abstract
The present disclosure relates to a polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-moulded articles, said composition having the following features: 1) a density from 0.952 to 0.960 g/cm3; 2) an MIF/MIP ratio from 17 to 30; and 3) a Shear-Induced Crystallization Index SIC from 2.5 to 5.0.
Claims11
A polyethylene composition comprising:
- 1) a density from 0.952 to 0.960 g/cm3 as determined according to ISO 1183 at 23° C.;
- 2) aMIF/MIP ratio from 17 to 30, wherein MIF is the melt flow index at 190° C. with a load of 21.60 kg, and MIP is the melt flow index at 190° C. with a load of 5 kg, both determined according to ISO 1133;
- and
- 3) a SIC Index from 2.5 to 5.0;
- wherein the SIC Index is the Shear-Induced Crystallization Index, determined according to the following relation:
- SIC Index=((tonset,SIC@1000×tonset, quiescent)/((HLMI)*100)
- where tonset,SIC@1000 is measured in seconds and is the time required for crystallization onset under shear rate of 1000 s−1, the t onset, quiescent is measured in seconds and is the crystallization onset time at temperature of 125° C. under no shear, determined in isothermal mode by differential scanning calorimetry;
- HLMI is the melt flow index determined at 190° C. with a load of 21.6 kg, according to ISO 1133.
5 more elements
Dependencies are inferred from the claim text.