Catalyst for the production of synthesis gas and process for obtaining it
AssigneePetroleo Brasileiro S.A. - Petrobras
InventorsAntonio Marcos FONSECA BIDART, Roberto Carlos PONTES BITTENCOURT, Fabio MENEZES PASSARELLI
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Abstract
This invention is aimed at making viable a catalyst and the process for obtaining it that besides having a higher resistance to the deposition of coke on the catalyst surface, does not introduce limitations to the process variables, maintains acceptable levels of activity throughout the steam reforming process and has a lower cost of production. The aforementioned objective is achieved by means of a catalyst formed by an inorganic oxide support, a mixture of Nickel, Lanthanum and Cerium and a promoter element.
Claims17
A catalyst for the production of synthesis gas, nickel-based, to be used in a steam reforming process, with greater resistance to the deposition of coke on its surface and catalytic activity, comprising:
- an inorganic oxide support;
- a mixture of Nickel, Lanthanum and Cerium oxides, in the form of their oxides (NiO, La2O3 and Ce2O3), which are impregnated simultaneously on the inorganic oxide support;
- the ratio between the mixture of NiO and La2O3 is comprised in a range of values between 6:1 (w/w) and 15:1 (w/w);
- the ratio of mixture of Ce2O3 and La2O3 comprised in a range of values between 2:1 (w/w) and 4:1 (w/w) and the total content of NiO in a range comprised between values between 5% (w/w) and 50% (w/w), preferably between 7% (w/w) and 30% (w/w);
- and
- a promoter element comprised in a range of values between 0.3% (w/w) and 2.0% (w/w).
Dependencies are inferred from the claim text.