Eo/po block copolymers useful as stabilizers for pur foams
AssigneeCovestro Deutschland AG
InventorJan Schoenberger
Life of this patent
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Abstract
The invention relates to compositions for producing hydrophilicized polyurethane foams, in particular for wound management, wherein the composition, containing a polyurethane dispersion and specific additives, is frothed and dried.
Claims18
1-13 (canceled)
A polyurethane foam comprising an EO/PO block copolymer as stabilizer.
The polyurethane foam of claim 1, wherein said polyurethane foam is hydrophilicized as well as stabilized.
A composition comprising an aqueous, anionically hydrophilicized polyurethane dispersion (I) and foam additives (II), wherein said foam additives (II) comprise an EO/PO block copolymer.
A polyurethane foam comprising an EO/PO block copolymer as stabilizer, wherein said polyurethane foam is obtained from an aqueous, anionically hydrophilicized polyurethane dispersion (I) by mechanical frothing and physical drying,
- wherein said EO/PO block copolymer comprises 40% to 85% by weight of ethylene oxide units based on the sum total of all ethylene oxide and propylene oxide units and has a number-average molecular weight of 1,000 to 10,000 g/mol,
- and wherein said aqueous, anionically hydrophilicized polyurethane dispersion (I) is obtained by
- A) producing isocyanate-functional prepolymers from at least
- A1) organic polyisocyanates;
- A2) polymeric polyols having number-average molecular weights in the range of from 400 to 8,000 g/mol and OH functionalities in the range of from 1.5 to 6;
- A3) optionally hydroxyl-functional compounds having molecular weights in the range of from 62 to 399 g/mol;
- and
- A4) optionally isocyanate-reactive, anionic, or potentially anionic and/or optionally nonionic hydrophilicizing agents;
- and
- B) wholly or partially reacting the free NCO groups of said isocyanate-functional prepolymers via chain extension with
- B1) amino-functional compounds having molecular weights in the range from 32 to 400 g/mol;
- and/or
- B2) with isocyanate-reactive, preferably amino-functional, anionic or potentially anionic hydrophilicizing agents,
- wherein said prepolymers are dispersed in water after B) and any potential ionic groups present are converted into their ionic form by partial or complete reaction with a neutralizing agent.
Dependencies are inferred from the claim text.