Resist composition and patterning process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorJun Hatakeyama
Life of this patent
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Abstract
To a resist composition comprising a polymer comprising recurring units having an acid labile group and an acid generator is added a metal-acid complex. The metal is Ce, Cu, Zn, Fe, In, Y, Yb, Sn, Tm, Sc, Ni, Nd, Hf, Zr, Ti, La, Ag, Ba, Ho, Tb, Lu, Eu, Dy, Gd, Rb, Sr or Cs. The acid is a fluoroalkylsulfonic acid, fluorinated arylsulfonic acid, fluorinated tetraphenylboric acid, fluoroalkylsulfonimidic acid or fluoroalkylsulfonemethide acid. Due to a high contrast of alkaline dissolution rate before and after exposure, high resolution, high sensitivity, and controlled acid diffusion rate, the composition forms a pattern with satisfactory profile and minimal line edge roughness.
Claims12
A resist composition comprising a polymer comprising recurring units of acid labile group-substituted (meth)acrylic acid, styrenecarboxylic acid or vinylnaphthalenecarboxylic acid and/or recurring units having an acid labile group-substituted phenolic hydroxyl group, and an acid generator, or a copolymer comprising recurring units of acid labile group-substituted (meth)acrylic acid, styrenecarboxylic acid or vinylnaphthalenecarboxylic acid and/or recurring units having an acid labile group-substituted phenolic hydroxyl group and recurring units having an acid generator,
- said resist composition further comprising a complex of a metal with an acid, the metal being selected from the group consisting of cerium, copper, zinc, iron, indium, yttrium, ytterbium, tin, thulium, scandium, nickel, neodymium, hafnium, zirconium, titanium, lanthanum, silver, barium, holmium, terbium, lutetium, europium, dysprosium, gadolinium, rubidium, strontium, and cesium, and the acid being selected from the group consisting of an alkylsulfonic acid, arylsulfonic acid, alkylsulfonimidic acid, alkylsulfonemethide acid, and tetraphenylboric acid each of which has at least one fluorine atom.
A resist composition comprising a polymer comprising recurring units of acid labile group-substituted (meth)acrylic acid, styrenecarboxylic acid or vinylnaphthalenecarboxylic acid and/or recurring units having an acid labile group-substituted phenolic hydroxyl group, and an acid generator, or a copolymer comprising recurring units of acid labile group-substituted (meth)acrylic acid, styrenecarboxylic acid or vinylnaphthalenecarboxylic acid and/or recurring units having an acid labile group-substituted phenolic hydroxyl group and recurring units having an acid generator,
- said resist composition further comprising a complex of a metal with an acid, the metal being selected from the group consisting of cerium, copper, zinc, iron, indium, yttrium, ytterbium, tin, thulium, scandium, nickel, neodymium, hafnium, zirconium, titanium, lanthanum, silver, barium, holmium, terbium, lutetium, europium, dysprosium, gadolinium, rubidium, strontium, and cesium, and the acid being selected from the group consisting of a C1-C4 fluoroalkylsulfonic acid, C6-C12 arylsulfonic acid having at least one fluorine atom which may be substituted with hydroxy group. C1-C12 alkoxy group or acyloxy group, or sulfonyl group, tetraphenylboric acid having at least one fluorine atom, C1-C4 fluoroalkylsulfonimidic acid, and C1-C4 fluoroalkylsulfonemethide acid.
Dependencies are inferred from the claim text.