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US 2016/0208386 A1Published application
Precursors for the production of thin oxide layers and the use thereof
AssigneeMerck Patent GmbH
InventorsKlaus BONRAD, Joerg SCHNEIDER, Rudolf HOFFMAN, Mareiki KALOUMENOS
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Abstract
The present invention relates to novel precursors in the form of metal complexes with 2-substituted 1,3-diketones and to a process for the preparation thereof. The invention furthermore relates to the use thereof for the production of thin metal-oxide layers. The latter are constituents in a very wide variety of electronic components and devices having various functions.
Claims15
Metal complex with 2-functionalised 1,3-diketones of the general formula (I)
- Ml[R1—CO—C(H)mX—CO—R2]n, (I)
- in which
- M denotes a metal atom selected from the group zinc, indium, gallium, tin, aluminium, zirconium, titanium and hafnium,
- l denotes 1 or 2,
- m denotes 0 or 1,
- n denotes 1, 2, 3 or 4,
- R1 and R2, independently of one another, denote alkyl having 1 to 8 C atoms, cycloalkyl having 3 to 7 C atoms, alkoxy having 1 to 8 C atoms and/or amino, NHR3 or NR3R4, where R3 and R4, independently of one another, denote alkyl having 1 to 8 C atoms or cycloalkyl having 3 to 7 C atoms,
- and
- X denotes hydroxyimino, nitro, sulfo, including —SO2-alkyl having 1 to 8 C atoms, phosphato, including —PO(O—R)2, where R=alkyl having 1 to 8 C atoms or alkoxy having 1 to 8 C atoms;
- stannyl —SnR3, where R=alkyl having 1 to 8 C atoms;
- mercapto —SR, where R═H, alkyl having 1 to 8 C atoms or cycloalkyl having 3 to 7 C atoms, halide, such as F, Cl, Br or I, or pseudohalide, such as —CN, —N3, —OCN, —NCO, —CNO, —SCN or —SeCN.
8 more elements
Dependencies are inferred from the claim text.