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US 2016/0115333 A1Published application
Resin composition, optical compensation film using same, and production method for same
AssigneeTosoh Corporation
InventorsMasayasu ITO, Shinsuke TOYOMASU, Takahiro KITAGAWA
Life of this patent
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Abstract
A resin composition including from 30 to 99 wt % of a cellulose-based resin represented by the following formula (1) and from 70 to 1 wt % of a fumaric acid ester polymer containing 30 mol % or more of a fumaric acid diester residue unit represented by the following formula (2); an optical compensation film using the same; and a production method of the optical compensation film. (wherein R1 to R3 represent a substituent having a carbon number of 1 to 12, and R4 and R5 represent an alkyl group having a carbon number of 1 to 12).
Claims19
1:
- A resin composition, comprising:
- from 30 to 99 wt % of a cellulose-based resin as a cellulose ether, represented by the following formula (1);
- and
- from 70 to 1 wt % of a fumaric acid ester polymer containing 30 mol % or more of a fumaric acid diester residue unit represented by the following formula (2):
- (wherein each of R1, R2 and R3 independently represents a substituent having a carbon number of 1 to 12):
- (wherein R4 and R5 represent an alkyl group having a carbon number of 1 to 12).
3 more elements
2:
- The resin composition according to claim 1,
- wherein the fumaric acid ester polymer is a fumaric acid ester polymer containing from 30 to 95 mol % of the fumaric acid diester residue unit and from 70 to 5 mol % of a fumaric acid monoester residue unit represented by the following formula (3):
- (wherein R6 represents an alkyl group having a carbon number of 1 to 12).
3:
- The resin composition according to claim 1,
- wherein the fumaric acid ester polymer is a fumaric acid ester polymer selected from the group consisting of:
- a fumaric acid ester polymer containing from 30 to 100 mol % of a diethyl fumarate residue unit and from 70 to 0 mol % of a fumaric acid monoester residue unit represented by the following formula (3);
- a fumaric acid ester polymer containing from 30 to 95 mol % of a diisopropyl fumarate residue unit and from 70 to 5 mol % of a fumaric acid monoester residue unit represented by the following formula (3);
- and a fumaric acid ester polymer containing from 30 to 95 mol % of a di-tert-butyl fumarate residue unit and from 70 to 5 mol % of a fumaric acid monoester residue unit represented by the following formula (3):
- (wherein R6 represents an alkyl group having a carbon number of 1 to 12).
3 more elements
4:
- The resin composition according to claim 2,
- wherein the fumaric acid monoester residue unit in claim 2 is a fumaric acid monoester residue unit selected from the group consisting of a monomethyl fumarate residue unit, a monoethyl fumarate residue unit, a monoisopropyl fumarate residue unit, a mono-n-propyl fumarate residue unit, a mono-n-butyl fumarate residue unit and a mono-2-ethylhexyl fumarate residue unit.
5:
- The resin composition according to claim 1,
- wherein the fumaric acid ester polymer is a fumaric acid ester polymer containing from 70 to 99.5 mol % of a fumaric acid diester residue unit represented by the following formula (2) and from 30 to 0.5 mol % of a residue unit selected from the group consisting of an acrylic acid ester residue unit represented by the following formula (4), a methacrylic acid ester residue unit represented by the following formula (5), an acrylic acid amide residue unit represented by the following formula (6) and a methacrylic acid amide residue unit represented by the following formula (7):
- (wherein R4 and R5 represents an alkyl group having a carbon number of 1 to 12):
- (wherein each of R7, R8, R9 and R10 independently represents an alkyl group having a carbon number of 1 to 12, an alkylene group or an ether group).
1 more element
6:
- The resin composition according to claim 1,
- wherein an etherification degree (substitution degree) of the cellulose-based resin as a cellulose ether represented by formula (1) is from 1.5 to 3.0.
7:
- An optical compensation film, which is formed using the resin composition according to claim 1 and has a thickness of from 5 to 200 μm.
8:
- An optical compensation film, which is formed using the resin composition according to claim 1 and has a thickness of from 20 to 60 μm.
9:
- The optical compensation film according to claim 7,
- wherein an in-plane retardation (Re) represented by the following expression (1) is from 80 to 300 nm and an Nz coefficient represented by the following expression (2) is from 0.35 to 0.65:
- Re=(ny−nx)×d (1)
- Nz=(ny−nz)/(ny−nx) (2)
- (wherein nx represents a refractive index in a fast axis direction in a film plane;
- ny represents a refractive index in a slow axis direction in a film plane;
- nz represents a refractive index outside a film plane;
- and d represents a film thickness).
5 more elements
10:
- The optical compensation film according to claim 7,
- wherein the in-plane retardation (Re) represented by expression (1) is from 50 to 200 nm and the Nz coefficient represented by expression (2) is from −0.2 to 0.2.
11:
- The optical compensation film according to claim 7,
- wherein the in-plane retardation (Re) represented by expression (1) is from 0 to 20 nm and an out-of-plane retardation (Rth) represented by the following expression (3) is from −150 to 20 nm:
- Rth=[(nx+ny)/2−nz]×d (3)
- (wherein nx represents a refractive index in a fast axis direction in a film plane;
- ny represents a refractive index in a slow axis direction in a film plane;
- nz represents a refractive index outside a film plane;
- and d represents a film thickness).
4 more elements
12:
- The optical compensation film according to claim 7,
- wherein a light transmittance is 85% or more.
13:
- The optical compensation film according to claim 7,
- wherein a haze is 1% or less.
14:
- The optical compensation film according to claim 7,
- wherein a ratio Re(450)/Re(550) between a retardation at 450 nm and a retardation at 550 nm is 0.60<Re(450)/Re(550)<1.05.
15:
- A method for producing an optical compensation film according to claim 9, comprising:
- dissolving, in a solvent, a resin composition containing from 30 to 99 wt % of a cellulose-based resin as a cellulose ether, represented by the following formula (1), and from 70 to 1 wt % of a fumaric acid ester polymer containing 30 mol % or more of a fumaric acid diester residue unit represented by the following formula (2);
- casting an obtained resin solution on a base material;
- and
- after drying, separating a resulting film from the base material:
- (wherein each of R1, R2 and R3 independently represents a substituent having a carbon number of 1 to 12):
- (wherein R4 and R5 represent an alkyl group having a carbon number of 1 to 12).
4 more elements
16:
- The production method of an optical compensation film according to claim 15,
- wherein an etherification degree of the cellulose-based resin as a cellulose ether represented by formula (1) is from 1.5 to 3.0.
17:
- A method for producing an optical compensation film by using the resin composition according to claim 4.
18:
- A method for producing an optical compensation film according to claim 9, comprising:
- subjecting a film having a thickness of 10 to 200 μm obtained by casting to uniaxial stretching or unbalanced biaxial stretching.
19:
- A method for producing an optical compensation film according to claim 9, comprising:
- subjecting a film having a thickness of 30 to 100 μm obtained by casting to uniaxial stretching or unbalanced biaxial stretching.