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US 2016/0108220 A1Published application
One-step production of a polypropylene composition
AssigneeBorealis AG
InventorsHermann Prokschi, Katja Klimke, Hermann Braun
Life of this patent
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Abstract
The present invention relates to a process for providing a polypropylene composition comprising a branched polypropylene (b-PP), a polypropylene composition as well as a film comprising the polypropylene composition.
Claims22
Process for providing a polypropylene composition comprising a branched polypropylene (b-PP), the process comprising the steps of:
- a) providing a polypropylene (PP) having a melt flow rate MFR2 (230° C.) of more than 1.0 g/10 min;
- b) providing a thermally decomposing free radical-forming agent,
- c) providing bifunctionally unsaturated monomer(s) and/or multifunctionally unsaturated low molecular weight polymer(s),
- d) providing a linear polypropylene (l-PP) having a melt flow rate MFR2 (230° C.) of 10.0 to 50.0 g/10 min,
- e) reacting the polypropylene (PP) of step a) with the thermally decomposing free radical-forming agent of step b) and the bifunctionally unsaturated monomer(s) and/or multifunctionally unsaturated low molecular weight polymer(s) of step c) obtaining thereby the branched polypropylene (b-PP), and
- f) reacting the branched polypropylene (b-PP) obtained in step e) with the linear polypropylene (l-PP) of step d),
- wherein the polypropylene composition and/or branched polypropylene (b-PP) has/have
- i) a melt flow rate MFR2 (230° C.) measured according to ISO 1133 of 18.0 to 35.0 g/10 min,
- ii) a F30 melt strength of more than 3.4 cN and a v30 melt extensibility of more than 200 mm/s, wherein the F30 melt strength and the v30 melt extensibility are measured according to ISO 16790:2005.
6 more elements
Polypropylene composition comprising:
- (a) 95.0 to 99.0 parts by weight of a branched polypropylene (b-PP);
- and
- (b) 1.0 to 5.0 parts by weight of a linear polypropylene (l-PP) having a melt flow rate MFR2 (230° C.) measured according to ISO 1133 of 10.0 to 50.0 g/10 min;
- wherein the polypropylene composition has
- a melt flow rate MFR2 (230° C.) measured according to ISO 1133 from 18.0 to 35.0 g/10 min, and
- an OCS gel index of less than 2,500;
- and
- wherein the polypropylene composition and/or the branched polypropylene (b-PP) has/have a F30 melt strength of more than 3.4 cN and a v30 melt extensibility of more than 200 mm/s, wherein the F30 melt strength and the v30 melt extensibility are measured according to ISO 16790:2005.
5 more elements
Dependencies are inferred from the claim text.