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US 2016/0108199 A1Published application
Process for preparing aminomethylated bead polymers
AssigneeLANXESS Deutschland GmbH
InventorsReinhold KLIPPER, PIerre VANHOORNE
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Abstract
Aminomethylated bead polymers for use as ion exchangers, especially as anion exchangers, or for the preparation of chelate resins, are prepared in the presence of 1,3-dichloropropane as solvent and swelling agent
Claims19
A process for preparing aminomethylated bead polymers, the process comprising:
- a) converting monomer droplets composed of a mixture comprising at least one monoethylenically unsaturated aromatic compound, at least one multiethylenically unsaturated compound, and at least one initiator to bead polymer;
- b) contacting the bead polymer with:
- compounds of the formula (I) or salts thereof
- where R1=C1-C3-alkyl or H, and
- compounds of the formula (II)
- where n=1 to 100,
- in the presence of a swelling agent and solvent comprising 1,3-dichloropropane, and
- in the presence of protic acids, to give a phthalimidomethylated bead polymer;
- and
- c) hydrolysing the phthalimidomethylated bead polymer to produce aminomethylated bead polymer.
7 more elements
Dependencies are inferred from the claim text.