Back to results
US 2016/0108069 A1Published application
Dinuclear metallocene compound, and a method for preparing the same
AssigneeLG Chem, Ltd.
InventorsYoung Shil DO, Choong Hoon LEE, Seung Hwan JUNG, Ji Joong MOON, Yoon Hee CHO, Sang Eun PARK
Life of this patent
Estimating the term…
Abstract
The present invention relates to a dinuclear metallocene compound with a new structure which can manufacture polyolefin having high molecular weight and to a method for preparing the same. The dinuclear metallocene compound according to the present invention is a dinuclear metallocene compound with a new structure, and, unlike a single-site catalyst, has high accessibility to a substrate, and thus, can provide a multi-site catalyst with high activity.
Claims6
A dinuclear metallocene compound represented by the following Chemical Formula 1:
- in the Chemical Formula 1,
- R1 to R4 may be identical to or different from each other, and are independently hydrogen;
- a halogen radical;
- an alkyl radical having a carbon number of 1 to 20;
- an alkenyl radical having a carbon number of 2 to 20;
- a silyl radical;
- an aryl radical having a carbon number of 6 to 20;
- an alkylaryl radical having a carbon number of 7 to 20;
- or an arylalkyl radical having a carbon number of 7 to 20;
- and two or more adjacent radicals of R1 to R4 may be linked each other to form an aliphatic ring, or an aromatic ring;
- R5 to R7 may be identical to or different from each other, and are independently hydrogen;
- a halogen radical;
- an alkyl radical having a carbon number of 1 to 20;
- an alkenyl radical having a carbon number of 2 to 20;
- an aryl radical having a carbon number of 6 to 20;
- an alkylaryl radical having a carbon number of 7 to 20;
- an arylalkyl radical having a carbon number of 7 to 20;
- an alkoxy radical having a carbon number of 1 to 20;
- an aryloxy radical having a carbon number of 6 to 20;
- or an amido radical;
- and two or more adjacent radicals of R5 to R7 may be linked each other to form an aliphatic ring, or an aromatic ring;
- CY is an aliphatic or aromatic ring containing nitrogen, and may be unsubstituted or substituted with halogen, an alkyl or aryl radical having a carbon number of 1 to 20, and if it has multiple substituents, two or more substituents may be linked each other to form an aliphatic or aromatic ring;
- M is Group 4 transition metal;
- X1 is a halogen radical;
- an alkyl radical having a carbon number of 1 to 20;
- an alkenyl radical having a carbon number of 2 to 20;
- an aryl radical having a carbon number of 6 to 20;
- an alkylaryl radical having a carbon number of 7 to 20;
- an arylalkyl radical having a carbon number of 7 to 20;
- an alkylamido radical having a carbon number of 1 to 20;
- an arylamido radical having a carbon number of 6 to 20;
- or an alkylidene radical having a carbon number of 1 to 20;
- and
- n is an integer of 0 to 10.
31 more elements
A method for preparing a dinuclear metallocene compound represented by the following Chemical Formula 1, comprising the step of reacting a compound represented by the following Chemical Formula 2 with a compound represented by the following Chemical Formula 3:
- in the Chemical Formulae 1, 2 and 3,
- R1 to R4 may be identical to or different from each other, and are independently hydrogen;
- a halogen radical;
- an alkyl radical having a carbon number of 1 to 20;
- an alkenyl radical having a carbon number of 2 to 20;
- a silyl radical;
- an aryl radical having a carbon number of 6 to 20;
- an alkylaryl radical having a carbon number of 7 to 20;
- or an arylalkyl radical having a carbon number of 7 to 20;
- and two or more adjacent radicals of R1 to R4 may be linked each other to form an aliphatic ring, or an aromatic ring;
- R5 to R7 may be identical to or different from each other, and are independently hydrogen;
- a halogen radical;
- an alkyl radical having a carbon number of 1 to 20;
- an alkenyl radical having a carbon number of 2 to 20;
- an aryl radical having a carbon number of 6 to 20;
- an alkylaryl radical having a carbon number of 7 to 20;
- an arylalkyl radical having a carbon number of 7 to 20;
- an alkoxy radical having a carbon number of 1 to 20;
- an aryloxy radical having a carbon number of 6 to 20;
- or an amido radical;
- and two or more adjacent radicals of R5 to R7 may be linked each other to form an aliphatic ring, or an aromatic ring;
- CY is an aliphatic or aromatic ring containing nitrogen, and may be unsubstituted or substituted with halogen, an alkyl or aryl radical having a carbon number of 1 to 20, and if it has multiple substituents, two or more substituents may be linked each other to form an aliphatic or aromatic cring;
- M is Group 4 transition metal;
- X1 and X2 may be identical to or different from each other, and are independently a halogen radical;
- an alkyl radical having a carbon number of 1 to 20;
- an alkenyl radical having a carbon number of 2 to 20;
- an aryl radical having a carbon number of 6 to 20;
- an alkylaryl radical having a carbon number of 7 to 20;
- an arylalkyl radical having a carbon number of 7 to 20;
- an alkylamido radical having a carbon number of 1 to 20;
- an arylamido radical having a carbon number of 6 to 20;
- or an alkylidene radical having a carbon number of 1 to 20;
- and
- n is an integer of 0 to 10.
31 more elements
Dependencies are inferred from the claim text.