Process for the preparation of fluorinated compounds
AssigneeArkema France
InventorsAnne PIGAMO, Michel DEVIC, Laurent WENDLINGER
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AssigneeArkema France
InventorsAnne PIGAMO, Michel DEVIC, Laurent WENDLINGER
Estimating the term…
A subject-matter of the invention is a process for the preparation of 2,3,3,3-tetrafluoro-1-propene which comprises the following stages: (i) hydrogenation of hexafluoropropylene to give 1,1,1,2,3,3-hexafluoropropane; (ii) dehydrofluorination of the 1,1,1,2,3,3-hexafluoropropane obtained in the preceding stage to give 1,2,3,3,3-pentafluoro-1-propene; (iii) hydrogenation of the 1,2,3,3,3-pentafluoro-1-propene obtained in the preceding stage to give 1,1,1,2,3-pentafluoropropane; and (iv) dehydrofluorination of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage to give 2,3,3,3-tetrafluoro-1-propene. Stages (ii) and (iv) are carried out using a water and potassium hydroxide mixture with the potassium hydroxide representing between 58 and 86% by weight of the mixture and at a temperature of between 110 and 180° C.
Process for the preparation of 2,3,3,3-tetrafluoro-1-propene which comprises the following stages:
Process according to any one of the preceding claims, characterized in that the stream resulting from stage (i) and/or stage (iii) is or are conveyed directly to the following stage.
Process according to any one of the preceding claims, characterized in that the stream resulting from stage (ii) is subjected to a purification stage before being conveyed to stage (iii).
Process according to any one of the preceding claims, characterized in that it is carried out continuously.
Process according to any one of the preceding claims, characterized in that stage (ii) and/or stage (iv) is or are carried out in at least two reactors in series.
Process according to any one of the preceding claims, characterized in that stage (i) and/or stage (iii) is or are carried out in a multistage reactor or in at least two reactors in series.
Dependencies are inferred from the claim text.