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US 2016/0102225 A1Published application
Coating compositions and textile fabrics coated therewith
AssigneesBluestar Silicones France SAS, Bluestar Silicones USA Corp.
InventorsRemi Thiria, Pascale Jackson
Life of this patent
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Abstract
A curable coating composition that exhibits improved curs and adhesion to various substrates, especially synthetic textiles used in the manufacture of air bags, and good air pressure holding performance.
Claims11
A curable silicone composition (A) useful for coating textile fabrics and comprising:
- (1) components (a-1) or (a-2):
- (a-1) corresponding to at least one polyorganosiloxane that may be cured by the action of a catalyst based on at least one organic peroxide, and
- (a-2) corresponding to a polyorganosiloxane blend that may be cured by a polyaddition reaction, comprising:
- at least one organopolysiloxane (I) having an average of at least two silicon-bonded aliphatically unsaturated hydrocarbon substituents on the molecule, and
- at least one organopolyorganosiloxane (II) and/or at least one organosilicon crosslinker (II′) having an average of at least 2 silicon-bonded hydrogen on the molecule,
- (2) an effective amount of a curing catalyst (III) comprising:
- when component (a-1) is used, at least one organic peroxide, and when component (a-2) is used, at least one catalyst able to promote reaction of aliphatically unsaturated hydrocarbon substituents with SiH groups,
- (3) at least 10 weight parts, per 100 weight parts of the curable silicone composition, of an organopolysiloxane resin (IV) of formula MMViQ and consisting essentially of:
- (a) monovalent siloxane units MVi of the formula R′R2SiO1/2;
- (b) monovalent siloxane units M of the formula R3SiO1/2, and
- (c) tetravalent siloxane units Q of the formula SiO4/2
- wherein R denotes a monovalent hydrocarbon group and R*′ denotes a vinyl group:
- (4) an organopolysiloxane resin (V) different from said organopolysiloxane resin (IV) and comprising at least two different siloxane units chosen from those of M siloxane unit of formula R3SiO1/2, D siloxane unit of formula R2SiO2/2. T siloxane unit of formula RSiO3/2 and Q siloxane unit of formula SiO4/2,
- wherein R denotes a monovalent .hydrocarbon group, on condition that, at least one siloxane unit being a T or Q siloxane unit and that at least one of the M, D and T siloxane units comprises an alkenyl group
- (5) at least one adhesion promoter (VI),
- (6) at least one reinforcing filler (VII), p1 (7) optionally at least-one polydiorganosiloxane gum (XI) which is a linear or partially-branched homopolymer or copolymer having at least 2 alkenyl groups per molecule and said gum having a viscosity of greater than 500,000 mPa·s at 25° C.,
- (8) optionally, at least one curing inhibitor (VIII),
- (9) optionally, at least one coloration additive (IX), and
- (10) optionally, at least one additive (X) for improving the fire resistance.
16 more elements
Dependencies are inferred from the claim text.