Superoleophobic and/or superhydrophobic material, process for preparing same and applications thereof

A fluorine-free monomer having following general formula (I):

• wherein:
• Z1 is chosen from the atoms and groups S, O, NH and N—W;
• Z3 is chosen from the atoms and groups H, X1—W, X1—R1—X2, C(R2)(R3);
• Z4 is chosen from the atoms and groups X1—W, X1—R1—X2, C(R2)(R3);
• Z5 and Z6 represent an H atom or a hydrocarbon chain including 3 carbon atoms;
• wherein:
• W represents B1—H, Q1-Z2 or B1-Q1-Z2;
• with B1, B2, B3, identical or different, chosen from the groups:
• C1-C20 alkyls, C1-C20 alkenyls, C1-C20 alkynyls, C6-C18 aryls, C6-C18 heteroaryls;
• with Z2 corresponding to A1, CH(A1)(A2), CH2(A1), NH(A1), N(A1)(A2), O(A1) or S(A1);
• for which A1 and A2, identical or different, represent:
• —B2—H,
• —B3-ph-Q2-B2—H;
• “ph” designating the functional phenyl group;
• with Q1 and Q2, identical or different, which represent OC(O), C(O), SC(O), NHC(O);
• X1 and X2;
• identical or different, are chosen from the atoms or groups O, S, NH;
• R1 is chosen from the groups —CH(W)—, —(CH2)n1—CH(W)—, —CH(W)—(CH2)n1, —(CH2)n2—CH(W)—(CH2)n3— and —(CH2)n1, when Z1 equals N—W;
• W being as defined above and n1, n2, n3, identical or different, are between 1 and 12, the sum of n2+n3 being less than or equal to 12;
• R2 is a hydrocarbon chain including 3 carbon atoms;
• R3 is chosen from the groups W, X1—W or X1—R1—X2;
• and wherein:
• when Z3 and Z4 correspond to X1—R1—X2, they are linked to one another to form a ring;
• when Z3 and/or Z4 correspond to C(R2)(R3), they are linked to Z6 and Z5, (Z6 and Z3) and (Z5 and Z4), in order to form a 6-carbon aromatic ring, and when R3 corresponds to X1—R1—X2 then Z3 and Z4 are linked to one another and also form a ring;
• and wherein, when Z1 is an S atom:
• if Z3 is an H atom, then Z4 is chosen from the groups X1—W or C(R2)(R3);
• Z3 and Z4 cannot simultaneously be equal to OW;
• and wherein, when Z1 is an S or NW atom:
• if Z3 and Z4 correspond to X1—R1—X2, n1 is equal to 1 and Z2 corresponds to CH2(A1) then B2, B3, identical or different, are chosen from the groups:
• C1-C20 alkenyls, C1-C20 alkynyls, C6-C18 aryls, C6-C18 heteroaryls;
• and wherein, when Z1 is N—W and W corresponds to B1—H, then B1 is chosen from the groups:
• C1-C20 alkenyls, C1-C20 alkynyls, C6-C18 aryls, C6-C18 heteroaryls.