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US 2016/0078977 A1Published application
Conductive polymer material and substrate
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsJun HATAKEYAMA, Takayuki NAGASAWA
Life of this patent
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Abstract
The present invention provides a conductive polymer material including (A) a π-conjugated polymer, (B) a dopant polymer which contains a repeating unit having a sulfo group and has a weight-average molecular weight in the range of 1,000 to 500,000, and (C) either or both of sulfonium salt compounds represented by the following general formulae (1-1) and (1-2). There can be provided a conductive polymer material that has low acidity, can suppress the gradual agglomeration of particles, and has excellent solution-stability.
Claims20
A conductive polymer material comprising:
- (A) a π-conjugated polymer;
- (B) a dopant polymer which contains a repeating unit having a sulfo group and has a weight-average molecular weight in the range of 1,000 to 500,000;
- and
- (C) either or both of sulfonium salt compounds represented by the following general formulae (1-1) and (1-2),
- wherein R1, R2, and R3 independently represent a halogen atom, an amino group that contains an alkyl group having 1 to 4 carbon atoms, a linear, branched, or cyclic alkyl group, alkenyl group, oxoalkyl group, or oxoalkenyl group having 1 to 12 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group or aryloxoalkyl group having 7 to 12 carbon atoms, in which these groups may contain an alkoxy group, a hydroxyl group, a carboxyl group, a nitro group, a cyano group, an amino group, a halogen atom, an ester group, an ether group, or a thioether group;
- R1 and R2 may form a ring together with each other, and when the ring is formed, R1 and R2 represent an alkylene group having 1 to 6 carbon atoms;
- R4, R5, and R6 independently represent an alkyl group having 1 to 4 carbon atoms;
- K− represents a hydroxide ion, a chloride ion, a bromide ion, a carbonate ion, a hydrogen carbonate ion, a nitrate ion, a carboxylate ion, a sulfonate ion, or a sulfinate ion;
- and when K− is a carboxylate ion, K− may be substituted for any of R1, R2, and R3 to form an inner salt.
6 more elements
Dependencies are inferred from the claim text.