Amphoteric polymer particles and compositions thereof
AssigneesRohm and Haas Company, Dow Global Technologies LLC
InventorsJames C. Bohling, Ward Thomas Brown, Arnold S. Brownell, Paul Clark, Thomas Glenn Madle
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Abstract
The present invention relates to a stable aqueous dispersion of multiphase amphoteric polymer particles comprising a crosslinked polymer phase comprising structural units of a phosphorus acid monomer, a carboxylic acid monomer, a multiethylenically unsaturated monomer, and an ethylenically unsaturated nonionic monomer; and a second polymer phase comprising a carboxylic acid monomer and an ethylenically unsaturated nonionic monomer. The present invention also relates to composites of the particles and pigment particles such as TiO2. The composition is useful for preparing dried coatings with improved hiding.
Claims9
A stable aqueous dispersion of multiphase amphoteric polymer particles comprising:
- a) a crosslinked polymer phase comprising, based on the weight of the crosslinked polymer phase:
- i) from 1 to 10 weight percent structural units of a phosphorus acid monomer or a salt thereof;
- ii) from 0.5 to 5 weight percent structural units of a carboxylic acid monomer or a sulfur acid monomer or a salt thereof or a combination thereof;
- iii) from 1 to 10 weight percent amine groups or salts thereof or quaternary ammonium salts;
- iv) 0.1 to 20 weight percent structural units of a multiethylenically unsaturated monomer;
- and
- v) from 80 to 97 weight percent structural units of an ethylenically unsaturated nonionic monomer;
- and
- b) a second polymeric phase comprising:
- i) from 0.1 to 4 weight percent structural units of a carboxylic acid monomer or a sulfur acid monomer or a salt thereof or combination thereof;
- and
- ii) from 80 to 99.9 weight percent structural units of an ethylenically unsaturated nonionic monomer;
- wherein the crosslinked polymer phase protuberates from the second polymer phase;
- wherein the weight:weight ratio of the crosslinked polymer phase to the second polymer phase is in the range of from 1:4 to 1:99;
- with the proviso that the multiphase amphoteric polymer particles comprise from 0.01 to 4 weight percent structural units of the phosphorus acid monomer or a salt thereof and from 0.01 to 4 weight percent of the amine groups or salts thereof or the quaternary ammonium salt groups.
Dependencies are inferred from the claim text.