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US 2015/0307707 A1Published application
Flame-retardant polycarbonate molding materials vi
AssigneeBayer MaterialScience AG
InventorsMathieu JUNG, Thomas ECKEL, Vera TASCHNER
Life of this patent
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Abstract
The present invention relates to flame-retardant, impact-modified polycarbonate (PC) compositions and moulding compositions having a property combination of excellent mechanical properties, very good flame resistance, high hydrolytic stability and high resistance to chemicals (ESC behaviour). The present application additionally relates to the use of the compositions in the production of moulded articles, and to moulded articles produced from the compositions.
Claims15
Composition comprising
- A) from 60 to 95 parts by weight of aromatic polycarbonate and/or aromatic polyester carbonate,
- B) from 1.0 to 15.0 parts by weight of rubber-modified graft polymer with a graft base selected from the group consisting of silicone rubber, silicone-acrylate rubber and acrylate rubber,
- C) from 1.0 to 20.0 parts by weight of at least one cyclic phosphazene according to formula (X)
- wherein
- k represents 1 or an integer from 1 to 10, optionally a number from 1 to 8, optionally from 1 to 5,
- wherein the trimer content (k=1) is from 60 to 98 mol %, based on component C,
- and wherein
- R
- is in each case identical or different and represents an amine radical;
- C1- to C8-alkyl, optionally methyl, ethyl, propyl or butyl, each optionally halogenated, optionally halogenated with fluorine;
- C1- to C8-alkoxy, optionally methoxy, ethoxy, propoxy or butoxy;
- C5- to C6-cycloalkyl each optionally substituted by alkyl, optionally C 1-C4-alkyl, and/or by halogen, optionally chlorine and/or bromine;
- C6- to C20-aryloxy, optionally phenoxy, naphthyloxy, each optionally substituted by alkyl, optionally C1-C4-alkyl, and/or by halogen, optionally chlorine, bromine, and/or by hydroxy;
- C7- to C12-aralkyl, optionally phenyl-C1-C4-alkyl, each optionally substituted by alkyl, optionally C1-C4-alkyl, and/or by halogen, optionally chlorine and/or bromine;
- or a halogen radical, optionally chlorine;
- or an OH radical,
- D) from 0 to 15.0 parts by weight of rubber-free vinyl (co)polymer or polyalkylene terephthalate,
- E) from 0 to 15.0 parts by weight of one or more additives,
- F) from 0.05 to 5.0 parts by weight, optionally from 0.1 to 2.0 parts by weight, optionally from 0.1 to 1.0 part by weight, of one or more antidripping agents,
- wherein all the parts by weight are optionally normalised that the sum of the parts by weight of all the components A+B+C+D+E+F in the composition is 100.
17 more elements
A cyclic phosphazene according to formula (X)
- Capable of being used in production of a flame-retardant polymer composition having a property combination of excellent mechanical properties, very good flame resistance, high hydrolytic stability and high resistance to chemicals (ESC behaviour), wherein
- k represents 1 or an integer from 1 to 10, optionally a number from 1 to 8, optionally from 1 to 5,
- wherein the trimer content (k=1) is from 60 to 98 mol %, based on component C, and wherein
- R
- is in each case identical or different and represents an amine radical;
- C1- to C8-alkyl, optionally methyl, ethyl, propyl or butyl, each optionally halogenated, optionally halogenated with fluorine;
- C1- to C8-alkoxy, optionally methoxy, ethoxy, propoxy or butoxy;
- C5- to C6-cycloalkyl each optionally substituted by alkyl, optionally C 1-C4-alkyl, and/or by halogen, optionally chlorine and/or bromine;
- C6- to C20-aryloxy, optionally phenoxy, naphthyloxy, each optionally substituted by alkyl, optionally C1-C4-alkyl, and/or by halogen, optionally chlorine, bromine, and/or by hydroxy;
- C7- to C12-aralkyl, optionally phenyl-C1-C4-alkyl, each optionally substituted by alkyl, optionally C1-C4-alkyl, and/or by halogen, optionally chlorine and/or bromine;
- or a halogen radical, optionally chlorine;
- or an OH radical.
9 more elements
Dependencies are inferred from the claim text.