Production of graphene nanoribbons by oxidative anhydrous acidic media

Abstract

In some embodiments, the present disclosure pertains to methods of producing graphene nanoribbons by exposing carbon nanotubes to a medium to result in formation of the graphene nanoribbons from the carbon nanotubes. In some embodiments, the carbon nanotubes include multi-walled carbon nanotubes. In some embodiments, the medium comprises: (a) an acid, (b) a dehydrating agent, and (c) an oxidizing agent. In some embodiments, the acid comprises sulfuric acid, the dehydrating agent comprises oleum (e.g., with a free sulfur trioxide (SO3) content of about 20% by weight of the oleum), and the oxidizing agent comprises ammonium persulfate. In some embodiments, the exposing opens the carbon nanotubes parallel to their longitudinal axis to form graphene nanoribbons. Additional embodiments of the present disclosure pertain to the graphene nanoribbons that are formed by the methods of the present disclosure. In some embodiments, the graphene nanoribbons are non-oxidized, un-functionalized and substantially free of defects.

Dependencies are inferred from the claim text.