Latent additive and composition containing latent additive
AssigneeAdeka Corporation
InventorsMitsuhiro Okada, Tomoyuki Ariyoshi
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Abstract
A latent additive represented by general formula (1): wherein A is a 5- or 6-membered aromatic or heterocyclic ring; R1 and R2 are each hydrogen, halogen, cyano, hydroxyl, nitro, carboxyl, optionally substituted C1-C40 alkyl, C6-C20 aryl, C7-C20 arylalkyl, or C2-C20 heterocyclic ring-containing group; and R4 is C1-C20 alkyl, C2-C20 alkenyl, C6-C20 aryl, C7-C20 arylalkyl, C2-C20 heterocyclic ring-containing group, or trialkylsilyl.
Claims11
A latent additive represented by general formula (1):
- wherein A represents a 5- or 6-membered aromatic or heterocyclic ring;
- R1 and R2 each independently represent a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an optionally substituted C1-C40 alkyl group, a C6-C20 aryl group, a C7-C20 arylalkyl group, or a C2-C20 heterocyclic ring-containing group;
- R4 represents a C1-C20 alkyl group, a C2-C20 alkenyl group, a C6-C20 aryl group, a C7-C20 arylalkyl group, a C2-C20 heterocyclic ring-containing group, or a trialkylsilyl group;
- the methylene moiety of the alkyl or arylalkyl group represented by R1, R2, and R4 may be replaced by a combination of one or more groups selected from a carbon-carbon double bond, —O—, —S—, —CO—, —O—CO—, —CO—O—, —O—CO—O—, —O—CO—O—, —S—CO—, —CO—S—, —S—CO—O—, —O—CO—S—, —CO—NH—, —NH—CO—, —NH—CO—O—, —NR′—, >P═O, —S—S—, and —SO2—;
- R′ represents a hydrogen atom or a C1-C8 alkyl group;
- a plurality of R's may be taken together to form a benzene ring or a naphthalene ring;
- a plurality of R's may be the same or different;
- a plurality of R4's may be the same or different;
- n represents an integer of 1 to 10;
- d represents an integer of 1 to 3;
- k represents an integer of 1 to 3;
- and
- X represents a single bond, a nitrogen atom, an oxygen atom, a sulfur atom, a phosphorus atom, a group represented by [Chem 2] shown below, >P═O, >C═O, >NR10, >PR10, —OR10, —SR10, —NR10R11, —PR10R11, a C1-C120 aliphatic hydrocarbon group, a C6-C35 aromatic ring-containing hydrocarbon group, or a C2-C35 heterocyclic ring-containing group, the aliphatic hydrocarbon group, aromatic ring-containing hydrocarbon group, and heterocyclic ring-containing group having as many valences as n and optionally having a substituent;
- R10 and R11 each represent a hydrogen atom, an optionally substituted C1-C35 aliphatic hydrocarbon group, an optionally substituted C6-C35 aromatic ring-containing hydrocarbon group, or an optionally substituted C2-C35 heterocyclic ring-containing group, the aliphatic hydrocarbon group, aromatic ring-containing group, and heterocyclic ring-containing group being optionally substituted by a combination of one or more groups selected from a carbon-carbon double bond, —O—, —S—, —CO—, —O—CO—, —CO—O—, —O—CO—O—, —O—CO—O—, —S—CO—, —CO—S—, —S—CO—O—, —O—CO—S—, —CO—NH—, —NH—CO—, —NH—CO—O—, —NR′—, >P═O, —S—S—, —SO2—, and a nitrogen atom;
- the aromatic or heterocyclic ring may be fused to one or more additional rings;
- when X is a nitrogen atom, a phosphorous atom, or the group represented by [Chem. 2] shown below, n is 3;
- when X is an oxygen atom or a sulfur atom, n is 2;
- when X is >C═O, —NH—CO—, —CO—NH—, >NR10, or >PR10, n is 2;
- and when X is —OR10, —SR10, —NR10R11, or —PR10R11, n is 1;
- and X may be taken together with A to form a ring.
A compound represented by general formula (2):
- wherein A represents a 5- or 6-membered aromatic or heterocyclic ring;
- R201 and R202 each independently represent a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an optionally substituted C1-C40 alkyl group, a C6-C20 aryl group, a C7-C20 arylalkyl group, or a C2-C20 heterocyclic ring-containing group;
- d represents an integer of 1 to 3;
- k represents an integer of 1 to 3;
- R204 represents a C1-C20 alkyl group, a C2-C20 alkenyl group, a C6-C20 aryl group, a C7-C20 arylalkyl group, a C2-C20 heterocyclic ring-containing group, or a trialkylsilyl group;
- the methylene moiety of the alkyl or arylalkyl group represented by R201, R202, and R204 may be replaced by a combination of one or more groups selected from a carbon-carbon double bond, —O—, —S—, —CO—, —O—CO—, —CO—O—, —O—CO—O—, —O—CO—O—, —S—CO—, —CO—S—, —O—CO—S—, —S—CO—O—, —CO—NH—, —NH—CO—, —NH—CO—O—, —NR′—, >P═O, —S—S—, and —SO2—;
- R′ represents a hydrogen atom or a C1-C8 alkyl group;
- a plurality of R202's may be taken together to form a benzene ring or a naphthalene ring;
- a plurality of R202's may be the same or different;
- a plurality of R204's may be the same or different;
- X2 represents an oxygen atom, a sulfur atom, a group represented by [Chem. 4] shown below, >C═O, —NH—CO—, —CO—NH—, >NR12, >PR12, a substituent represented by group selected from general formula (3), general formula (4), or [Chem. 10] shown below;
- R12 represents a hydrogen atom, an optionally substituted C1-C35 aliphatic hydrocarbon group, an optionally substituted C6-C35 aromatic ring-containing hydrocarbon group, or an optionally substituted C2-C35 heterocyclic ring-containing group, the aliphatic hydrocarbon group, aromatic ring-containing hydrocarbon group, and heterocyclic ring-containing group being optionally substituted by a combination of one or more groups selected from a carbon-carbon double bond, —O—, —S—, —CO—, —O—CO—, —CO—O—, —O—CO—O—, —O—CO—O—, —S—CO—, —CO—S—, —O—CO—S—, —S—CO—O—, —CO—NH—, —NH—CO—, —NH—CO—O—, —NR′—, >P═O, —S—S—, and —SO2—;
- the aromatic or heterocyclic ring may be fused to one or more additional rings;
- and
- X2 may be taken together with A to form a ring.
- wherein Y1 and Y5 each independently represent a single bond, a C1-C4 alkylene group;
- Y2 and Y4 each independently represent an oxygen atom or —NR13—;
- R13 represents a hydrogen atom or a C1-C20 aliphatic hydrocarbon group;
- Y3 represents a single bond, —NR16—, a divalent C1-C35 aliphatic hydrocarbon group, a divalent C6-C35 aromatic ring-containing group, or a substituent represented by general formula (5) below, the aliphatic hydrocarbon group and C6-C35 aromatic ring-containing hydrocarbon group being optionally substituted by —COO—, —O—, —OCO—, —NHCO—, —NH—, or —CONH—;
- R14 and R15 each independently represent a hydrogen atom, a C1-C8 alkyl group, a C6-C20 aryl group, or a C7-C20 arylalkyl group;
- and R16 represents a hydrogen atom, an optionally substituted C1-C35 aliphatic hydrocarbon group, an optionally substituted C6-C35 aromatic ring-containing hydrocarbon group, or an optionally substituted C2-C35 heterocyclic ring-containing group, the aliphatic hydrocarbon group, aromatic ring-containing hydrocarbon group, and heterocyclic ring-containing group being optionally substituted by a combination of one or more groups selected from a carbon-carbon double bond, —O—, —S—, —CO—, —O—CO—, —CO—O—, and —SO2—.
- wherein Y6 and Y8 each independently represent —NR17— or an optionally oxygen-interrupted C1-C4 alkylene group;
- Y7 represents a single bond, —O—, —S—, —SO2—, —CR18R19—, or any one of the substituents represented by [Chem. 7] to [Chem. 9] shown below;
- R17 represents a hydrogen atom or a C1-C20 aliphatic hydrocarbon group;
- R16 and R19 each independently represent a hydrogen atom or an optionally substituted C1-C8 alkyl group;
- R100 and R101 each independently represent a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, a C1-C8 alkyl group, or a C1-C8 alkoxy group;
- e represents a number of 1 to 4;
- and f represents a number of 1 to 4.
- wherein R21 represents a hydrogen atom, an optionally substituted phenyl group, or a C3-C10 cycloalkyl group;
- R22 represents a C1-C10 alkyl group, a C1-C10 alkoxy group, a C2-C10 alkenyl group, or a halogen atom, the alkyl, alkoxy, or alkenyl group optionally having a substituent;
- and a represents an integer of 0 to 5.
- wherein R102 and R103 each independently represent a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, a C1-C8 alkyl group, or a C1-C8 alkoxy group;
- i represents a number of 1 to 4;
- and j represents a number of 1 to 4.
- wherein R23 and R24 each independently represent an optionally substituted C1-C10 alkyl group, an optionally substituted C6-C20 aryl group, an optionally substituted C6-C20 aryloxy group, an optionally substituted C6-C20 arylthio group, an optionally substituted C6-C20 arylalkenyl group, an optionally substituted C7-C20 arylalkyl group, an optionally substituted C2-C20 heterocyclic ring-containing group, or a halogen atom, the methylene moiety of the alkyl and arylalkyl group being optionally replaced by an unsaturated bond, —O—, or —S—;
- adjacent R23's may be taken together to form a ring;
- b represents a number of 0 to 4;
- c represents a number of 0 to 8;
- and the sum of g and h is 2 to 4.
- wherein R31 represents a hydrogen atom, an optionally substituted C1-C35 aliphatic hydrocarbon group, an optionally substituted C6-C35 aromatic ring-containing hydrocarbon group, or an optionally substituted C2-C35 heterocyclic ring-containing group, the aliphatic hydrocarbon group being optionally substituted by a carbon-carbon double bond, —O—, —S—, —CO—, —O—CO—, —CO—O—, or —SO2—.
- wherein Y9 and Y10 each independently represent a C1-C4 alkylene group.
A compound represented by general formula (6):
- wherein A represents a 5- or 6-membered aromatic or heterocyclic ring;
- R301 and R302 each independently represent a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an optionally substituted C1-C40 alkyl group, a C6-C20 aryl group, a C7-C20 arylalkyl group, or a C2-C20 heterocyclic ring-containing group;
- d represents an integer of 1 to 3;
- k represents an integer of 1 to 3;
- R304 represents a C1-C20 alkyl group, a C2-C20 alkenyl group, a C6-C20 aryl group, a C7-C20 arylalkyl group, a C2-C20 heterocyclic ring-containing group, or a trialkylsilyl group;
- the methylene moiety of the alkyl or arylalkyl group represented by R301, R302, and R304 may be replaced by a combination of one or more groups selected from a carbon-carbon double bond, —O—, —S—, —CO—, —O—CO—, —CO—O—, —O—CO—O—, —O—CO—O—, —S—CO—, —CO—S—, —O—CO—S—, —S—CO—O—, —CO—NH—, —NH—CO—, —NH—CO—O—, —NR′—, >P═O, —S—S—, —SO2—, and a nitrogen atom;
- R′ represents a hydrogen atom or a C1-C8 alkyl group;
- a plurality of R302's may be taken together to form a benzene ring or a naphthalene ring;
- a plurality of R302's may be the same or different;
- a plurality of R304's may be the same or different;
- and
- X3 represents a substituent represented by general formula (7);
- X3 may optionally be taken together with A to form a ring;
- and the aromatic or heterocyclic ring may be fused to one or more additional rings.
- wherein Y11 represents a trivalent C3-C35 aliphatic hydrocarbon group, a trivalent C3-C35 alicyclic hydrocarbon group, a trivalent C6-C35 aromatic ring-containing hydrocarbon group, or a trivalent C2-C35 heterocyclic ring-containing group;
- Z1, Z, and Z3 each independently represent a single bond, —O—, —S—, >CO, —CO—O—, —O—CO—, —SO2—, —SS—, —SO—, >NR32, >PR32, an optionally substituted C1-C35 aliphatic hydrocarbon group, an optionally substituted C6-C35 aromatic ring-containing hydrocarbon group, or an optionally substituted C2-C35 heterocyclic ring-containing group;
- and R3 represents a hydrogen atom, an optionally substituted C1-C35 aliphatic hydrocarbon group, an optionally substituted C6-C35 aromatic ring-containing hydrocarbon group, or an optionally substituted C2-C35 heterocyclic ring-containing group, the aliphatic hydrocarbon group being optionally substituted by a combination of one or more groups selected from a carbon-carbon double bond, —O—, —S—, —CO—, —O—CO—, —CO—O—, and —SO2—.
A compound represented by general formula (8):
- wherein A represents a 5- or 6-membered aromatic or heterocyclic ring;
- R401 and R402 each independently represent a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an optionally substituted C1-C40 alkyl group, a C6-C20 aryl group, a C7-C20 arylalkyl group, or a C2-C20 heterocyclic ring-containing group;
- d represents an integer of 1 to 3;
- k represents an integer of 1 to 3;
- R404 represents a C1-C20 alkyl group, a C2-C20 alkenyl group, a C6-C20 aryl group, a C7-C20 arylalkyl group, a C2-C20 heterocyclic ring-containing group, or a trialkylsilyl group;
- the methylene moiety of the alkyl or arylalkyl group represented by R401, R402, and R404 may be replaced by a combination of one or more groups selected from a carbon-carbon double bond, —O—, —S—, —CO—, —O—CO—, —CO—O—, —O—CO—O—, —O—CO—O—, —S—CO—, —CO—S—, —O—CO—S—, —S—CO—O—, —CO—NH—, —NH—CO—, —NH—CO—O—, —NR′—, >P═O, —S—S—, and —SO2—;
- R′ represents a hydrogen atom or a C1-C8 alkyl group;
- a plurality of R402's may be taken together to form a benzene ring or a naphthalene ring;
- a plurality of R402's may be the same or different;
- a plurality of R404's may be the same or different;
- n represents a number of 4 to 6;
- X4 represents a substituent represented by general formula (9) when n is 4, X4 represents a substituent represented by general formula (10) when n is 5, or X4 represents a substituent represented by general formula (11) when n is 6;
- X4 may optionally be taken together with A to form a ring;
- and the aromatic or heterocyclic ring may be fused to one or more additional rings.
- wherein Y12 represents a carbon atom, a tetravalent C1-C35 aliphatic hydrocarbon group, a tetravalent C6-C35 aromatic ring-containing hydrocarbon group, or a tetravalent C2-C35 heterocyclic ring-containing group, the aliphatic hydrocarbon group being optionally substituted by a combination of one or more groups selected from —COO—, —O—, —OCO—, —NHCO—, —NH—, and —CONH—;
- and Z1, Z2, Z3, and Z4 each independently have the same meaning as Z1 to Z3 in general formula (7).
- wherein Y13 represent a pentavalent C2-C35 aliphatic hydrocarbon group, a pentavalent C6-C30 aromatic ring-containing hydrocarbon group, or a pentavalent C2-C30 heterocyclic ring-containing group, the aliphatic hydrocarbon group being optionally substituted by a combination of one or more groups selected from —COO—, —O—, —OCO—, —NHCO—, —NH—, and —CONH—;
- and Z1, Z2, Z3, Z4, and Z5 each independently have the same meaning as Z1 to Z3 in general formula (7).
- wherein Y14 represents a hexavalent C2-C35 aliphatic hydrocarbon group, a hexavalent C6-C35 aromatic ring-containing hydrocarbon group, or a hexavalent C2-C35 heterocyclic ring-containing group, the aliphatic hydrocarbon group being optionally substituted by a combination of one or more groups selected from —COO—, —O—, —OCO—, —NHCO—, —NH—, and —CONH—;
- and Z1, Z2, Z3, Z4, Z5, and Z6 each independently have the same meaning as Z1 to Z3 in general formula (7).
Dependencies are inferred from the claim text.