Composition comprising a dicarbonyl derivative and method for straightening the hair using this composition
AssigneeL'oreal
InventorNicolas Daubresse
Life of this patent
Estimating the term…
Loading patent…
AssigneeL'oreal
InventorNicolas Daubresse
Estimating the term…
The present invention relates to a cosmetic composition comprising: one or more dicarbonyl derivatives corresponding to formula (I) below, and/or derivatives thereof and/or hydrates thereof and/or salts thereof: in which formula (I) R═H, COOH, linear or branched C1-C6 alkyl which is optionally substituted with an OH or COOH or Br radical; phenyl or benzyl optionally substituted with an OH or COOH radical; or alternatively an indolyl radical or one or more silanes corresponding to formula (II) below and/or oligomers thereof: R1Si(OR2)z(R3)x(OH)y (II) in which formula (II): R1 is a linear or branched, saturated or unsaturated, cyclic or acyclic C1-C6 hydrocarbon-based chain substituted with a group chosen from the following groups: amine NH2 or NHR (R═C1-C20 and especially C1-C6 alkyl optionally substituted with a radical comprising a silicon atom, C3-C40 cycloalkyl or C6-C30 aromatic), or with a hydroxyl group, a thiol group, an aryl or aryloxy group which is unsubstituted or substituted, in particular with an amino group or with a C1-C4 aminoalkyl group; R1 possibly being interrupted with a heteroatom (O, S or NH) or a carbonyl group (CO), R2 and R3, which may be identical or different, represent a linear or branched alkyl group comprising from 1 to 6 carbon atoms, y denotes an integer ranging from 0 to 3, and z denotes an integer ranging from 0 to 3, and x denotes an integer ranging from 0 to 2, with z+x+y=3. The invention also relates to a process for straightening keratin fibers, especially the hair, using the compounds of formulae (I) and (II) with a straightening step using a straightening iron at a temperature of at least 150° C., preferably ranging from 150 to 250° C.
A cosmetic composition comprising:
The composition as claimed in either of the preceding claims, in which the dicarbonyl compound(s) corresponding to formula (I) and/or derivatives thereof and/or hydrates thereof and/or salts thereof are chosen from glyoxylic acid and pyruvic acid, a derivative thereof, salts thereof and hydrates thereof, preferably from glyoxylic acid, a derivative thereof and the hydrate forms of these compounds.
The composition as claimed in any one of the preceding claims, in which the dicarbonyl derivative(s) corresponding to formula (I) and/or derivatives thereof are chosen from glyoxylic acid esters, glyoxylic acid amides, glyoxylic acid (thio)acetals and hemi(thio)acetals, and glyoxylic acid ester (thio)acetals and hemi(thio)acetals.
The composition as claimed in any one of the preceding claims, characterized in that R1 represents a C1-C6 aminoalkyl group.
The composition as claimed in any one of the preceding claims, characterized in that z ranges from 1 to 3 and preferably z is equal to 3.
The composition as claimed in any one of the preceding claims, characterized in that R1 is an acyclic chain and in that the compound of formula (II) comprises only one silicon atom in its structure.
The composition as claimed in any one of the preceding claims, characterized in that it comprises at least one compound of formula (II) chosen from 3-aminopropyltriethoxysilane (APTES), 3-aminoethyltriethoxysilane (AETES), 3-aminopropylmethyldiethoxysilane, N-(2-aminoethyl)-3-aminopropyltriethoxysilane, 3-(m-aminophenoxy)propyltrimethoxysilane, p-aminophenyltrimethoxysilane and N-(2-aminoethylaminomethyl)phenethyltrimethoxysilane, better still from 3-aminopropyltriethoxysilane (APTES), 3-aminoethyltriethoxysilane (AETES), 3-aminopropylmethyldiethoxysilane and N-(2-aminoethyl)-3-aminopropyltriethoxysilane or oligomers thereof.
The composition as claimed in any one of the preceding claims, characterized in that it comprises at least one compound chosen from 3-aminopropyltriethoxysilane and oligomers thereof.
The composition as claimed in one of the preceding claims, characterized in that the silane(s) of formula (II) and/or the oligomers thereof are present in an active material content ranging from 0.05% to 20% by weight, preferably from 0.1% to 10% by weight, preferably ranging from 0.2% to 20% by weight, relative to the total weight of the composition.
The composition as claimed in any one of the preceding claims, in which the weight ratio of dicarbonyl derivatives corresponding to formula (I) and/or a derivative thereof and/or hydrate forms thereof and/or salts/silanes thereof of formula (II) and/or oligomers thereof ranges from 0.1 to 10 and better still from 0.2 to 5.
The composition as claimed in any one of the preceding claims, characterized in that it is aqueous and comprises water in a concentration preferably ranging from 5% to 98%, better still from 5% to 90% and even better still from 10% to 90% by weight relative to the total weight of the composition.
The composition as claimed in any one of the preceding claims, characterized in that it has a pH of less than 4, the pH preferentially ranging from 1 to 3, better still from 1.5 to 3 and even better still from 1.7 to 3.
Dependencies are inferred from the claim text.