Water repellent composition, its production method, hydrophobic substrate treating agent composition and article
AssigneeAsahi Glass Company, Limited
InventorsShin YAMANE, Shuichiro Sugimoto
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Abstract
A water repellent composition comprising a fluorinated copolymer having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group, structural units based on a monomer (b) having a C1-6 alkyl group and structural units based on a monomer (c) (halogenated olefin), and a medium, wherein the proportion of the structural units based on the monomer (a) is from 50 to 90 mass % of the structural units (100 mass %) based on all the monomers.
Claims3
A hydrophobic substrate treating agent composition, which comprises the water repellent composition, a penetrant, and an antistatic agent, wherein said water repellent composition to be used for treatment of a hydrophobic substrate, which comprises a fluorinated copolymer having structural units based on the following monomer (a), structural units based on the following monomer (b) and structural units based on the following monomer (c), and a medium,
- wherein the proportion of the structural units based on the monomer (a) is from 50 to 90 mass % of the structural units (100 mass %) based on all the monomers:
- monomer (a):
- a compound represented by the following formula (1):
- (Z—Y)nX (1)
- wherein Z is a C1-6 polyfluoroalkyl group or a group represented by the following formula (2), Y is a bivalent organic group or a single bond, n is 1 or 2, and X is, when n is 1, any one of the groups represented by the following formulae (3-1) to (3-5) and, when n is 2, any one of the groups represented by the following formulae (4-1) to (4-4):
- CiF2i+1O(CFX1CF2O)jCFX2— (2)
- wherein i is an integer of from 1 to 6, j is an integer of from 0 to 10, and each of X1 and X2 is a fluorine atom or a trifluoromethyl group;
- —CR═CH2 (3-1)
- —C(O)OCR═CH2 (3-2)
- —OC(O)CR═CH2 (3-3)
- —OCH2-φ-CR═CH2 (3-4)
- —OCH═CH2 (3-5)
- wherein R is a hydrogen atom, a methyl group or a halogen atom, and φ is a phenylene group;
- —CH[—(CH2)mCR═CH2]— (4-1)
- —CH[—(CH2)mC(O)OCR═CH2]— (4-2)
- —CH[—(CH2)mOC(O)CR═CH2]— (4-3)
- —OC(O)CH═CHC(O)O— (4-4)
- where R is a hydrogen atom, a methyl group or a halogen atom, and m is an integer of from 0 to 4;
- monomer (b):
- a (meth)acrylate having no polyfluoroalkyl group and having a C1-6 alkyl group;
- monomer (c):
- a halogenated olefin.
Dependencies are inferred from the claim text.