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US 2015/0031806 A1Published application
Moisture curable compositions with enhanced elongation and tear strentgh properties
AssigneeMomentive Performance Materials Inc.
InventorsThomas Fay-Oy Lim, Vikram Kumar, Martin Wusik
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Abstract
Moisture-curable compositions are provided which comprises a moisture-curable silylated resin, a flexibilizer and at least one curing catalyst. The cured compositions possess enhanced elongation and tear properties, and are highly suitable for applications such as adhesives, sealants, coatings, gaskets, industrial rubber goods, and the like.
Claims24
A moisture-curable composition comprising:
- (a) a moisture-curable silylated resin having the general Formula (I):
- P[-L-SiR1a(OR1)3-a]m Formula (I)
- wherein:
- P is a polymer residue derived from at least one addition or condensation monomer, wherein the polymer residue P has a polymer backbone selected from the group consisting of polyether, polyester, polyether-co-polyester, polyester-co-polyether, polythioether, polyamine, polyamide, polyester-co-polyamide, polyacrylate, polyacetal, polycarbonate, polycarbonate, polybutadiene, polyurethane and polyurea;
- L is a divalent linking group;
- each occurrence of R1 is independently an alkyl group having from 1 to 6 carbon atoms, a phenyl group or an arenyl group having 7 to 12 carbon atoms;
- each occurrence of subscript a is independently 0, 1 or 2;
- and
- m is an integer from 1 to 15;
- (b) a flexibilizer having the general Formula (II):
- wherein:
- each occurrence of R4 is independently an alkyl group having from 1 to 6 carbon atoms, a phenyl group or an arenyl group having 7 to 12 carbon atoms:
- each occurrence of R5 is independently an alkyl group having from 1 to 6 carbon atoms;
- each occurrence of R6 is independently a phenyl group or an arenyl group having 7 to 12 carbon atoms;
- each occurrence of X1 is independently a hydroxyl group, an alkoxy group having from 1 to 6 carbon atoms;
- each occurrence of X2 is independently a hydroxyl group, an alkoxy group having from 1 to 6 carbon atoms, or a group with the Formula (IIa):
- R4, R5 and R6 are the same as defined above;
- each occurrence of subscripts e, n, p, q, x and y is independently an integer wherein c is 1 to 3;
- n is 0 to 500, p is 1 to 500, q is 0 to 10, x is 0 to 50, and y is 0 to 50 with the provisos that
- (1) the molar ratio of n to p is from 0 to 15, and
- (2) the molar ratio of q to p is from 0 to 1;
- and,
- (c) at least one curing catalyst.
20 more elements
Dependencies are inferred from the claim text.