Process for the in situ activation of zinc metal
AssigneesCambridge Display Technology Limited, Sumitomo Chemical Company, Limited
InventorsJonathan Pillow, James Morey
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Abstract
A non-carcinogenic process for the activation of zinc metal in a medium polarity solvent, wherein said zinc metal is activated by the reaction thereof with a halogen and a lithium compound selected from lithium halides and lithium pseudohalides, the use of said activated zinc metal for the preparation of an organozinc halide of formula R—ZnX, and a process for the preparation of compounds obtainable by the reaction of said organozinc halide of formula R—ZnX with compounds having functionality enabling them to react with said organozinc halide.
Claims28
A process for the activation of zinc metal in a medium polarity solvent having a low nucleophilicity, wherein said zinc metal is activated by the reaction thereof with a halogen and a lithium compound selected from lithium halides and lithium pseudohalides.
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