# US 2014/0360429 A1 · Gas barrier element for pecvd reactors

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- Number: US 2014/0360429 A1
- Document ID: US20140360429A1
- Status: Published application
- Kind: A1
- Application number: 14/298,518
- Filed: 2014-06-06
- Published: 2014-12-11
- Earliest claimed: 2013-06-06
- Assignees: Tel Solar AG
- Applicants: TEL Solar AG
- Inventors: Devendra Chaudhary; Daniele Zorzi; Werner Wieland; Markus Klindworth; Aurel Salabas
- Web page: https://patentgrep.com/patent/US20140360429A1

## CPC

- C23C 16/505: using radio frequency discharges
- C23C 16/4401: {Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber}
- H01J 37/32082: {Radio frequency generated discharge (H01J37/32357, H01J37/32366, H01J37/32394 and H01J37/32403 take precedence)}
- H01J 37/3244: {Gas supply means}
- H01J 37/32568: {Relative arrangement or disposition of electrodes; moving means}
- C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04)
- H01J: ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS (spark-gaps H01T; electric arc lamps H05B31/00; particle accelerators H05H)

## Abstract

This disclosure relates to plasma processing for photovoltaic device manufacturing. Particularly to a plasma processing system that includes an electrode that allows gas to pass through into the process chamber that includes a substrate. A gas barrier component may be used to minimize parasitic plasma occurring at the edges of the electrode by preventing process gas reaching the edge of the chamber or from entering the process chamber by going around the electrode. The gas barrier component may be made of a non-conductive flexible material that forms a fluidic seal between the electrode and the chamber. In other embodiments, the gas barrier may also support isolation grids that are disposed opposite of the electrode and prevent the isolation grids from moving.

## Claims

### Claim 1

A system, comprising:
RF electrode comprising:
a power connector that is configured to be coupled to a radio frequency power generator; and
a plurality of holes that each have an opening on at least two sides of the electrode such that a gas can flow through one or more of the holes;
a ground component that surrounds a portion of the electrode;
a gas plenum that is formed between the electrode and ground component that can store the gas that can flow through the one or more holes of the electrode;
a non-conductive gas barrier disposed between a portion of the electrode and a portion of the ground component and that forms a fluid seal between the gas plenum the RF electrode;
a voltage dampening grid in the gas plenum that is coupled to the non-conductive gas barrier, and that increases the electrical isolation between the electrode and the ground component.

### Claim 2 (depends on 1)

The system of claim 1, further comprising:
an electrode suspension component that is mechanically coupled to the electrode and comprises:
a portion of the electrode suspension component that traverses the gas plenum; and
an adjustment component that can control a distance between the electrode and the ground component; and
a non-conductive component that surrounds the portion of the electrode suspension component that traverses the gas plenum.

### Claim 3 (depends on 2)

The system of claim 2, wherein the voltage dampening grid being, at least partially, supported by the non-conductive component,

### Claim 4 (depends on 1)

The system of claim 1, wherein the insulating material comprises Polytetrafluoroethylene.

### Claim 5 (depends on 4)

The system of claim 4, wherein the insulating material comprises:
at least one receptacle to support the voltage dampening grid; and
at least one heat expansion feature configured to compensate for thermal expansion of the insulating material.

### Claim 6 (depends on 5)

The system of claim 5, wherein the electrode and the ground component being substantially square or substantially rectangular.

### Claim 7 (depends on 6)

The system of claim 6, wherein the insulating material further comprises at least one corner component that conforms to at least one corner of the substantially square electrode or the substantially rectangular electrode.

### Claim 8 (depends on 1)

The system of claim 1, further comprising a plasma processing region that is substantially separated from the gas plenum by the electrode and is configured to process substrates of at least 1 m2, and the gas plenum and the plurality of holes being configured to maintain a pressure differential between the plasma processing region and the gas plenum of at least 2 Pa.

### Claim 9

A plasma processing system, comprising:
a ground component comprising at least one ground pass-through for gas that is used to generate plasma;
a electrode that is mechanically suspended from the ground component and electrically insulated from the ground component, and comprises:
a perimeter that is no more than 6 mm. away from a surface of the ground component; and
at least one electrode pass-through for the gas to a plasma processing region configured for substrates comprising a surface area of at least 1 m2;
an insulating material disposed between the perimeter of the electrode and the surface of the ground component, the insulating material forming a gas flow resistant seal between the electrode and the ground component; and
one or more voltage dampening components suspended between the ground component and the electrode by, at least, the insulating material.

### Claim 10 (depends on 9)

The plasma processing system of claim 9, wherein the insulating material comprises:
a compressible characteristic that enables the insulating material to be compressed between the ground component and he electrode to enable preventing the gas from flowing between the perimeter of the electrode and the surface of the ground component;
an insulating characteristic that at least minimizes electrical arcing between the electrode and the ground component near the perimeter of the electrode;
a chemical compatibility with fluorine under a temperature of at least 150 degrees Celsius;
at least one receptacle for each of the one or more voltage dampening components; and
a heat expansion feature that accommodates thermal expansion of the insulating feature.

### Claim 11 (depends on 9)

The plasma processing system of claim 9, further comprising:
at least one mechanical suspension component coupled to the ground component and the electrode; and
at least one substantially cylindrical suspension insulating element that surrounds at least a portion of the at least one suspension component, the suspension insulating element configured to prevent plasma from forming proximate to the at least one suspension element.

### Claim 12 (depends on 11)

The plasma processing system of claim 11, wherein the at least one suspension element is configured to support the one or more voltage dampening components.

### Claim 13 (depends on 11)

The plasma processing system of claim 11, wherein the electrode comprises a substantially square geometry or a substantially rectangular geometry.

### Claim 14 (depends on 9)

The plasma processing system of claim 9, wherein the insulating component comprises two or more interlocking components that are configured to accommodate thermal expansion of the two or more interlocking components

### Claim 15

A plasma processing system, comprising:
a first electrical component comprising:
a connection to electrical ground;
a substantially square pocket comprising a surface area of at leas pocket being proximate to a center of the first electrical component; and
a coupling to a gas source;
a second electrical component that is disposed within the pocket and offset from the surface area of the pocket by at least 4 mm and no more than 20 mm;
at least one metal sheet component disposed between the first electrical component and the second electrical component; and
a sealing component disposed between the first electrical component and the second electrical component to prevent a gas from leaking between the first electrical component and the second electrical component, and to support, at least partially, the at least one metal component.

### Claim 16 (depends on 15)

The plasma processing system of claim 15, herein the sealing component comprises:
two or more interlocking components that are configured to accommodate thermal expansion of the two or more interlocking components; and
at least one thermal expansion feature to compensate for thermal expansion of the sealing component to at least 150 degrees Celsius.

### Claim 17 (depends on 15)

The plasma processing system of claim 15, wherein the sealing component comprises Polytetrafluoroethylene.

### Claim 18 (depends on 15)

The plasma processing system of claim 15, further comprising suspension couplings that offset the second electrical component from the first electrical component.

### Claim 19 (depends on 15)

The plasma processing system of claim 15, wherein the second electrical component comprises an electrode that is configured to generate plasma in the plasma processing system.

### Claim 20 (depends on 15)

The plasma processing system of claim 15, wherein the second electrical component comprises a plurality of gas pass-through holes that enable a gas to diffuse through the second electrical component.
