# US 2014/0360245 A1 · Functional test for gas sensors

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- Number: US 2014/0360245 A1
- Document ID: US20140360245A1
- Status: Published application
- Kind: A1
- Application number: 14/468,671
- Filed: 2014-08-26
- Published: 2014-12-11
- Earliest claimed: 2012-03-12
- Assignees: Mettler-Toledo AG
- Applicants: Mettler-Toledo AG
- Inventors: René Oberlin; André Möbius
- Web page: https://patentgrep.com/patent/US20140360245A1

## CPC

- G01N 33/0006: {Calibrating gas analysers}
- G01N 25/18: by investigating thermal conductivity (by calorimetry G01N25/20; by measuring change of resistance of an electrically-heated body G01N27/18)
- G01N 27/18: caused by changes in the thermal conductivity of a surrounding material to be tested (G01N27/20 takes precedence)
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

A gas sensor which works according to the principle of thermal conductivity is functionally tested. In the method, a calibration cycle is conducted in which a membrane of the gas sensor is immersed in a fluid calibration medium having a known concentration of a target gas. After the calibration cycle, a measurement chamber of the gas sensor is purged with a purging gas. Then, a measuring cycle is conducted, using a thermal conductivity sensor to measure the target gas in the measurement chamber. Using a calibration baseline established from the calibration cycle and a measurement baseline in the measurement cycle, a baseline comparison value is obtained and compared to a predetermined baseline threshold value. An error message, indicating a malfunction in the purging gas supply, is generated when the baseline comparison value exceeds the predetermined baseline threshold value.

## Claims

### Claim 1

A method for functionally testing a gas sensor operating according to the principle of thermal conductivity, the gas sensor designed to sense the presence of a target gas in a fluid medium, the gas sensor comprising a measurement chamber with a connection to a supply of a purging gas, a thermal conductivity sensor, disposed in the measurement chamber, for determining one or more measurement values, a temperature sensor, and a membrane that separates the measurement chamber from the fluid medium during operation, the membrane being permeable to the target gas; the method comprising the steps of:
performing a calibration cycle, comprising the steps of:
immersing the membrane of the gas sensor in a calibration medium that is a fluid medium with a known concentration of the target gas;
conducting a purging procedure, comprising purging the measurement chamber with the purging gas;
conducting a measuring procedure after the purging procedure, the measuring step comprising the step of using the thermal conductivity sensor to take a plurality of measurements of the gas in the measurement chamber, obtaining a plurality of time-related measurement values; and
determining a calibration baseline from the plurality of time-related measurement values;
performing a measurement cycle, comprising the steps of:
immersing the membrane of the gas sensor in a measurement medium that is a fluid medium with an unknown concentration of the target gas;
conducting a purging procedure, comprising purging the measurement chamber with the purging gas;
conducting a measuring procedure after the purging procedure, the measuring step comprising the step of using the thermal conductivity sensor to make a plurality of measurements of the gas in the measurement chamber,
obtaining a plurality of time-related measurement values; and
determining a measurement baseline from the plurality of time-related measurement values;
calculating a baseline comparison value taking account of the calibration baseline and the measurement baseline; and
comparing the baseline comparison value to a predetermined baseline threshold value, and, if the baseline comparison value is greater than the baseline threshold value, generating a first error message, indicating a malfunction in the purging gas supply.

### Claim 2 (depends on 1)

The method of claim 1, further comprising the steps of:
during the measuring procedure of the measuring cycle, using an electronic measurement circuit of the gas sensor to determine a measurement voltage; and
comparing the determined measurement voltage to a predetermined voltage range; and
based upon the result of the comparing step, taking at least one of the following steps:
generating a further error message if the measurement voltage lies outside the voltage range;
determining a measurement current value if the measurement voltage lies within the voltage range, and comparing the determined measurement current value to a predetermined measurement current value to obtain a first control value;
determining a control current value by means of a control circuit which is a part of the measurement circuit, and comparing the determined measurement current value to the determined control current value to obtain a second control value;
comparing each of the first and the second control values to a respective predetermined first and second control threshold value, and
generating a second error message, which displays a malfunction of the gas sensor if at least one of the first and the second control values is greater than the respective predetermined first and second control threshold value.

### Claim 3 (depends on 2)

The method of claim 2, further comprising the steps of:
comparing the second control value to a predetermined third control threshold value if the second control value is greater than the predetermined second threshold value; and
generating a third error message, indicating a failure of the gas sensor, if the second control value is greater than the third control threshold value.

### Claim 4 (depends on 1)

The method of claim 1, further comprising the steps of:
during the measurement procedure of the measurement cycle, using an electronic measurement circuit of the gas sensor to determine a measurement voltage;
determining a measurement current value;
adjusting the measurement current value to correspond to a predetermined measurement current value, thereby determining a value of a manipulated variable, by adjusting at least one of: an adjustable first resistor or the supply voltage of the electronic measurement circuit; and
comparing the value of the manipulated variable to a predetermined first value of a control manipulated variable and generating a second error message, indicating a malfunction of the gas sensor, if the value of the manipulated variable is greater than the predetermined first value of the control manipulated variable.

### Claim 5 (depends on 4)

The method of claim 4, further comprising the steps of:
comparing the value of the manipulated variable to a predetermined second value of the control manipulated variable if the value of the manipulated variable is greater than the first value of the control manipulated variable; and
generating a third error message, indicating a failure of the gas sensor, if the value of the manipulated variable is greater than both the first and the second values of the control manipulated variable.

### Claim 6 (depends on 1)

The method of claim 1, further comprising the steps of:
during a measurement procedure of the measurement cycle, using an electronic measurement circuit of the gas sensor to determine, as a function of time, a plurality of measurement voltages;
comparing the time-related behavior of the measurement voltage to a predetermined first membrane threshold value range;
performing a purging procedure to determine, as a function of time, a plurality of purging measurement voltages during the purging procedure;
comparing the time-related behavior of the purging measurement voltage to a preselected second membrane threshold value range; and
generating a fourth error message, indicating a malfunction of the membrane in the gas sensor, if the measurement voltage lies outside the first membrane threshold value range and the purging measurement voltage lies outside the second membrane threshold value range.

### Claim 7 (depends on 1)

The method of claim 1, wherein:
any error message generated is recorded in a control unit of the gas sensor.

### Claim 8 (depends on 7)

The method of claim 7, wherein:
any error message generated is displayed in at least one of the following means:
optically, acoustically and electronically.

### Claim 9 (depends on 1)

A device for sensing the presence of a target gas in a fluid medium, the device comprising:
a measurement chamber having a connection for a purging gas;
a temperature sensor, disposed in the measurement chamber;
a thermal conductivity sensor, disposed in the measurement chamber to determine one or more measurement values; and
a membrane, permeable to the target gas, arranged to separate the measurement chamber from the fluid medium during operation, and
a control unit, in communication with the thermal conductivity sensor, programmed with an algorithm perform the method of claim 1 to generate at least one error message to indicate at least one malfunction of the device.

### Claim 10 (depends on 9)

The device of claim 9, further comprising:
a sensor body, with the control unit, at least partially disposed therein.

### Claim 11 (depends on 10)

The device of claim 10, wherein:
the control unit comprises a control circuit that detects leakage currents arising from moisture that has penetrated into the sensor body.