Back to results
US 2014/0318628 A1Published application
Conjugated Polymers Containing Fused Electron Rich and Electron Poor Units, Preparation, Method and Uses
AssigneeAdvent Technologies
InventorsChristos L. Chochos, Vasilis G. Gregoriou
Life of this patent
Estimating the term…
Abstract
New conjugated polymers based on 2,3-diphenylquinoxaline, dibenzo[a,c]phenazine, 2,3-diphenylpyrido[3,4-b]pyrazine, dibenzo[f,h]pyrido[3,4-b]quinoxaline, 2,3-diphenylpyrazino[2,3-d]pyridazine and dibenzo[f,h]pyridazino[4,5-b]quinoxaline along with their derivatives and thiophene, thieno[3,2-b]thiophene and thieno[2,3-b]thiophene along with their derivatives and a preparation method and uses thereof are disclosed.
Claims12
A conjugated polymer selected from the group consisting of:
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —Cw/H2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
186 more elements
A conjugated polymer selected from the group consisting of:
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein X, Y, Z can be the same or different and is selected from the group consisting of:
- X=hydrogen or fluorine atoms;
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000 and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
185 more elements
A conjugated polymer selected from the group consisting of:
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
- wherein Y, Z can be the same or different and is selected from the group consisting of:
- Y=alkyl, alkoxy;
- in ortho, meta or para positions and can be linear or branch;
- Z=oxygen, sulfur, selenium;
- m, k and n can be the same or different and are numbers between 1 to 1000
- and R1:
- —CpH2p+1, p≧0;
- linear or branch
- and R2:
- —CwH2w+1, w≧0;
- linear or branch.
177 more elements
Dependencies are inferred from the claim text.