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US 2014/0296561 A1Published application
Sulfonium salt-containing polymer, resist composition, patterning process, and sulfonium salt monomer and making method
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsYouichi OHSAWA, Masaki OHASHI, Seiichiro TACHIBANA, Jun HATAKEYAMA
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Abstract
A sulfonium salt having a 4-fluorophenyl group is introduced as recurring units into a polymer comprising hydroxyphenyl(meth)acrylate units and acid labile group-containing (meth)acrylate units to form a polymer which is useful as a base resin in a resist composition. The resist composition has a high sensitivity, high resolution and minimized LER.
Claims2
A sulfonium salt having the general formula (1):
- wherein R1 is hydrogen, fluorine, methyl or trifluoromethyl, R2, R3, and R4 are each independently a substituted or unsubstituted, straight or branched C1-C10 alkyl, alkenyl or oxoalkyl group, a substituted or unsubstituted C6-C18 aryl, aralkyl or aryloxoalkyl group, or 4-fluorophenyl group, any two of R2, R3, and R4 may bond together to form a ring with the sulfur atom, with the proviso that at least one of R2, R3, and R4 is a 4-fluorophenyl group.
Dependencies are inferred from the claim text.