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US 2014/0271537 A1Published application
Deuterium-enriched aldehydes
AssigneeDeuterra Agrochemicals, LLC
InventorAnthony W. Czarnik
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Abstract
The present invention generally relates to deuterium-enriched aldehydes, compositions comprising deuterium-enriched aldehydes, and methods for slowing the rate of aldehyde autoxidation. In one aspect, the present invention provides a composition comprising a compound of structure 1: wherein: there are at least 6×1018 molecules of the aldehyde and Rx is hydrogen, wherein the deuterium isotope in Rx is in an amount greater than 0.10 percent of the hydrogen atoms present in Rx.
Claims20
A composition, comprising:
- a deuterium-enriched aldehyde of structure 1:
- wherein:
- there are at least 6×1018 molecules of the aldehyde in the composition;
- Rx is hydrogen, wherein the deuterium isotope is present in an amount greater than 0.10% of the Rx hydrogen atoms;
- R1, R2 and R3 are independently selected from hydrogen, alkyl, substituted alkyl, alkenyl, substituted alkenyl, alkynyl, substituted alkynyl, heteroalkyl, substituted heteroalkyl, aryl, substituted aryl, heteroaryl, and substituted heteroaryl;
- alternatively, the CR1R2R3 moiety forms a group selected from:
- an aryl, substituted aryl, heteroaryl, and substituted heteroaryl;
- alternatively, the CR1R2 moiety forms a group a group selected from:
- an alkenyl and substituted alkenyl;
- alternatively, the CR1R2R3 moiety forms a group a group selected from:
- an alkynyl and substituted alkynyl;
- and,
- optionally, the aldehyde is substituted with C(O)Ry, wherein Ry is hydrogen, wherein the deuterium isotope is optionally present in an amount greater than 0.10% of the Ry hydrogen atoms, provided that Rx is optionally H when the deuterium isotope is present in an amount greater than 0.10% of the Ry hydrogen atoms.
10 more elements
Dependencies are inferred from the claim text.