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US 2014/0227449 A1Published application
Uses of carbenes in solution as organopolysiloxane polycondensation catalysts
AssigneeBluestar Silicones France SAS
InventorsChristian Maliverney, Laurent Saint-Jalmes
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Abstract
The invention relates to the use of novel stable carbenes in solution as organopolysiloxane polycondensation catalysts.
Claims15
A silicone-based elastomer precursor composition X comprising:
- a silicone base B comprising at least one polyorganosiloxane oil or gum C, said oil or gum C being (i) polymerizable or crosslinkable via a polycondensation reaction and having (ii) a dynamic viscosity of from 10 mPa·s to 1.5×106 mPa·s at 25° C.;
- and
- a catalytic composition Y′ comprising:
- a) a catalytically effective amount of at least one polycondensation catalyst A which is a carbene of formula (I) below:
- with:
- the symbol X being selected from the group consisting of the following atoms or groups:
- —O—, —S—, —N(R)— and —P(R)— with R being a C1-C30 group,
- R1, R2 and R3 being identical or different, optionally substituted, C1-C30 groups optionally comprising one or more atoms selected from the group consisting of:
- S, P, Si, N and O, and
- the symbols X, R1, R2 and R3 taken in pairs can form a 5-, 6- or 7-membered ring, and
- b) at least one solvent comprising at least one alcohol G.
8 more elements
Dependencies are inferred from the claim text.