Water soluble high syndiotactic polyvinyl alcohol
AssigneeSekisui Specialty Chemicals America, LLC
InventorsYohei Nishimura, Regan Pollock, Richard Vicari
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Abstract
A water soluble polyvinyl alcohol copolymer having a diad syndiotacticity of greater than about 60% and less than about 70%. In some embodiments, the water soluble polyvinyl alcohol copolymer is soluble in water at a concentration of at least 1 wt % at a temperature of less than 100° C. In other embodiments, the composition is soluble in water at a concentration of at least 5 wt % at a temperature in the range from about 90° C. to less than 100° C. The high solubility of the high syndiotactic poly vinyl alcohols disclosed herein may provide various advantages as described herein, including ease of processing and decreased use of harmful solvents.
Claims20
A composition comprising:
- a water soluble polyvinyl alcohol copolymer having a diad syndiotacticity of greater than about 60% and less than about 70%.
A method of preparing a polarizing film, comprising:
- dissolving a water soluble polyvinyl alcohol copolymer, having a diad syndiotacticity in the range from greater than about 60% to less than about 70%, in water at a temperature of less than 100° C. to form an aqueous solution;
- casting a film from the aqueous solution;
- infusing the film with iodine to form a polyvinyl alcohol—iodine complex;
- and
- stretching the film.
A process for forming a water-soluble high syndiotactic polyvinyl alcohol composition, comprising:
- copolymerizing at least one of vinyl pivalate, vinyl trifluoroacetate, vinyl trichloroacetate, and vinyl formate and at least one solubilizing comonomer to form a copolymer;
- saponifying the copolymer to produce a polyvinyl alcohol copolymer having a degree of hydrolysis of at least 95%;
- wherein the polyvinyl alcohol copolymer has a diad syndiotacticity of greater than about 60% to less than about 70% and is soluble in water at a temperature of less than 100° C. at concentrations of greater than 1 wt %.
Dependencies are inferred from the claim text.