# US 2014/0194390 A1 · Pesticidal compositions > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2014/0194390 A1 - Document ID: US20140194390A1 - Status: Published application - Kind: A1 - Application number: 14/205,556 - Filed: 2014-03-12 - Published: 2014-07-10 - Earliest claimed: 2006-12-14 - Assignees: Ishihara Sangyo Kaisha, Ltd. - Applicants: Ishihara Sangyo Kaisha, Ltd. - Inventors: Toru KOYANAGI; Masayuki Morita; Tetsuo Yoneda; Tsuyoshi Ueda; Kazuhisa Kiriyama; Taku Hamamoto - Web page: https://patentgrep.com/patent/US20140194390A1 ## CPC - A01N 43/56: 1,2-Diazoles; Hydrogenated 1,2-diazoles - A01N 43/08: with oxygen as the ring hetero atom - A01N 43/40: six-membered rings - A01N 43/78: 1,3-Thiazoles; Hydrogenated 1,3-thiazoles - A01N 53/00: Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof - A01N 57/32: containing heterocyclic radicals - A61P 33/14: Ectoparasiticides, e.g. scabicides - A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS - A61P: SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS ## Abstract A method of controlling pest with a pesticidal composition comprising synergistically effective amounts of at least one anthranilamide compound represented by the formula (I) or its salt and other pesticide: wherein each of R1a and R1b which are independent of each other, is halogen; each of R2 and R3 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or cyano; A is alkyl substituted by Y; Y is C3-4 cycloalkyl which may be substituted by at least one substituent selected from the group consisting of halogen, alkyl and haloalkyl; n is 0 or 1; and q is an integer of from 0 to 4; provided that R1a and R1b are not simultaneously chlorine nor bromine. ## Claims ### Claim at position 1 1-4. (canceled) ### Claim 5 A method for controlling pests which creates problems in agricultural and horticultural fields, by applying synergistically effective amounts of N-[2-bromo-4-chloro-6-[[α-methyl-(cyclopropylmethyl)amino]carbonyl]-phenyl]-3-bromo-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide or a salt thereof; and one or more of an insecticide, a fungicide or combination thereof, to the pests or plants, wherein the insecticide is selected from the group consisting of organophosphorus compounds, carbamate compounds, pyrethroid compounds, neonicotinoide compounds, benzoylurea compounds, nereistoxin derivatives, hydrazine compounds, antibiotics, semisynthetic antibiotics, pyrrole compounds, thiadiazin compounds, pyrazole compounds, organotin compounds, natural products, amitraz, acequinocyl, cyromazine, pyridalyl, spirotetramat, propargite, metaflumizone, flubendiamide, chlorantraniliprole, pyrifluquinazon, piridaben, HGW-86, and a combination thereof; wherein the fungicide is selected from the group consisting of tricyclazole, probenazole, fthalide, flutolanil, mepronil, tiadinil, pencycuron, azoxystrobin, validamycin, kasugamycin, isoprothiolane, pyroquilon, diclomezine, diclocymet, carpropamid, and a combination thereof; and wherein the weight ratio of the N-[2-bromo-4-chloro-6-[[α-methyl-(cyclopropylmethyl)amino]carbonyl]-phenyl]-3-bromo-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide or a salt thereof to the insecticide, the fungicide or combination thereof is from 1:40000 to 100:1. ### Claim 6 (depends on 5) The method according to claim 5, wherein the insecticide is selected from the group consisting of chlorpyrifos, fosthiazate, terbufos, thiodicarb, ethiofencarb, fenobucarb, permethrin, deltamethrin, lambda-cyhalothrin, bifenthrin, zeta-cypermethrin, phenothrin, imidacloprid, nitenpyram, acetamiprid, thiacloprid, thiamethoxam, clothianidin, dinotefuran, chlorfluazuron, flufenoxuron, lufenuron, thiosultap-sodium, tebufenozide, methoxyfenozide, spinosad, emamectin-benzoate, lepimectin, DE-175 (spinetoram), abamectin, chlorfenapyr, buprofezin, fipronil, tolfenpyrad, fenbutatin oxide, azadirachtin, amitraz, acequinocyl, cyromazine, pyridalyl, spirotetramat, propargite, metaflumizone, flubendiamide, chlorantraniliprole, pyrifluquinazon, piridaben, HGW-86, and a combination thereof. ### Claim 7 (depends on 5) The method according to claim 5, wherein the insecticide is selected from the group consisting of organophosphorus compounds, pyrethroid compounds, neonicotinoide compounds, benzoylurea compounds, hydrazine compounds, antibiotics, semisynthetic antibiotics, pyrrole compounds, pyrazole compounds, organotin compounds, natural products, amitraz, acequinocyl, cyromazine, pyridalyl, propargite, pyrifluquinazone, piridaben, and a combination thereof. ### Claim 8 (depends on 5) The method according to claim 5, wherein the insecticide is selected from the group consisting of fosthiazate, permethrin, deltamethrin, bifenthrin, zeta-cypermethrin, phenothrin, imidacloprid, acetamiprid, thiacloprid, clothianidin, dinotefuran, chlorfluazuron, flufenoxuron, lufenuron, tebufenozide, spinosad, emamectin-benzoate, chlorfenapyr, fipronil, fenbutatin oxide, azadirachtin, amitraz, acequinocyl, cyromazine, pyridalyl, propargite, pyrifluquinazon, pyridaben, and a combination thereof. ### Claim 9 (depends on 5) The method according to claim 5, wherein the insecticide is selected from the group consisting of fosthiazate, deltamethrin, bifenthrin, zeta-cypermethrin, phenothrin, imidacloprid, acetamiprid, thiacloprid, clothianidin, dinotefuran, chlorfluazuron, flufenoxuron, tebufenozide, spinosad, emamectin-benzoate, chlorfenapyr, fipronil, fenbutatin oxide, azadirachtin, acequinocyl, cyromazine, pyridalyl, propargite, pyrifluquinazon, pyridaben, and a combination thereof. ### Claim 10 (depends on 5) The method according to claim 5, wherein the insecticide is selected from the group consisting of fosthiazate, bifenthrin, imidacloprid, acetamiprid, thiacloprid, clothianidin, dinotefuran, chlorfluazuron, spinosad, emamectin-benzoate, fenbutatin oxide, azadirachtin, pyridalyl, pyridaben, and a combination thereof. ### Claim 11 (depends on 5) The method according to claim 5, comprising applying synergistically effective amounts of N-[2-bromo-4-chloro-6-[[α-methyl-(cyclopropylmethyl)amino]carbonyl]-phenyl]-3-bromo-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide or a salt thereof, and an insecticide selected from the group consisting of a pyrethroid compound, a neonicotinoide compound, and a combination thereof, wherein the weight ratio of the N-[2-bromo-4-chloro-6-[[α-methyl-(cyclopropylmethyl)amino]carbonyl]-phenyl]-3-bromo-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide or a salt thereof to the insecticide is from 1:5000 to 60:1. ### Claim 12 (depends on 11) The method according to claim 11, comprising applying the pyrethroid compound and which is permethrin, deltamethrin, lambda-cyhalothrin, bifenthrin, zeta-cypermethrin phenothrin, permethrin, deltamethrin, bifenthrin, zeta-cypermethrin, phenothrin, or a combination thereof. ### Claim 13 (depends on 12) The method according to claim 12, wherein the pyrethroid compound is permethrin, deltamethrin, bifenthrin, zeta-cypermethrin, phenothrin, or a combination thereof. ### Claim 14 (depends on 11) The method according to claim 11, comprising applying the neonicotinoide compound and which is imidacloprid, nitenpyram, acetamiprid, thiacloprid, thiamethoxam, clothianidin, dinotefuran, or a combination thereof. ### Claim 15 (depends on 14) The method according to claim 14, wherein the neonicotinoide compound is imidacloprid, acetamiprid, thiacloprid, clothianidin, dinotefuran, or a combination thereof.