# US 2014/0193933 A1 · Method for manufacturing semiconductor optical device > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2014/0193933 A1 - Document ID: US20140193933A1 - Status: Published application - Kind: A1 - Application number: 14/149,329 - Filed: 2014-01-07 - Published: 2014-07-10 - Earliest claimed: 2013-01-08 - Assignees: Sumitomo Electric Industries, Ltd. - Applicants: Sumitomo Electric Industries, Ltd. - Inventors: Kenji SAKURAI - Web page: https://patentgrep.com/patent/US20140193933A1 ## CPC - H01S 5/1231: {Grating growth or overgrowth details} - B82Y 20/00: Nanooptics, e.g. quantum optics or photonic crystals - H01S 5/2275: {mesa created by etching} - H01S 5/2081: {using special etching techniques} - H01S 5/2222: {having special electric properties} - H01S 5/34306: {emitting light at a wavelength longer than 1000nm, e.g. InP based 1300 and 1500nm lasers} - H01S 2301/176: Specific passivation layers on surfaces other than the emission facet - H01S: DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL - B82Y: SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES ## Abstract A method for manufacturing a semiconductor optical device includes the steps of preparing a mold having an imprint pattern; forming a substrate product including a semiconductor layer; forming a first resin layer on the semiconductor layer; forming a diffraction grating pattern having periodic projections and recesses in the first resin layer using the mold, the projection of the diffraction grating pattern having a top portion and a base portion; changing a duty ratio of the diffraction grating pattern by dry-etching the first resin layer; forming a second resin layer on the first resin layer so as to cover the projection and the recess; removing the top portion by etching back the first and second resin layers; and selectively etching the first resin layer so as to have a reverse pattern to the diffraction grating pattern; and etching the semiconductor layer through the first resin layer. ## Claims ### Claim 1 A method for manufacturing a semiconductor optical device, comprising the steps of: preparing a mold having an imprint pattern including periodic projections and recesses; forming a substrate product including a semiconductor layer that extends along a reference plane; forming a first resin layer on the semiconductor layer; forming a diffraction grating pattern having periodic projections and recesses in the first resin layer by transferring the imprint pattern using the mold by nanoimprint lithography, the projection of the diffraction grating pattern having a top portion and a base portion; changing a duty ratio of the diffraction grating pattern in the first resin layer by dry-etching the first resin layer; forming a second resin layer on the first resin layer so as to cover the projection and the recess of the diffraction grating pattern in the first resin layer; removing the top portion of the projection of the diffraction grating pattern by etching back the first resin layer and the second resin layer while leaving the base portion of the projection, the second resin layer being left in the recess of the first resin layer; selectively etching the first resin layer through the second resin layer left in the recess of the first resin layer, the first resin layer having a reverse pattern to the diffraction grating pattern; and etching the semiconductor layer through the first resin layer having the reverse pattern to the diffraction grating pattern to form a diffraction grating. ### Claim 2 (depends on 1) The method for manufacturing a semiconductor optical device according to claim 1, wherein, in the step of removing the top portion of the projection, the base portion of the projection includes an end surface disposed between the base portion and the top portion and a side surface, and the side surface has a region adjacent to the end surface that extends substantially perpendicular to the reference plane. ### Claim 3 (depends on 1) The method for manufacturing a semiconductor optical device according to claim 1, further comprising a step of forming an insulating layer on the semiconductor layer, wherein the first resin layer is formed on the insulating layer, and in the step of forming the diffraction grating pattern in the first resin layer, the diffraction grating pattern has a height measured from a bottom surface of the recess to a surface of the insulating layer, the height being larger than a thickness by which the first resin layer is etched in the step of changing the duty ratio of the diffraction grating pattern. ### Claim 4 (depends on 1) The method for manufacturing a semiconductor optical device according to claim 1, wherein the first resin layer is composed of a resin containing no silicon, the second resin layer is composed of a resin containing silicon, and in the step of selectively etching the first resin layer, the first resin layer is etched by reactive ion etching with a gas mixture of tetrafluoromethane (CF4) gas and oxygen (O2) gas. ### Claim 5 (depends on 4) The method for manufacturing a semiconductor optical device according to claim 4, wherein the step of removing the top portion of the projection and the step of selectively etching the first resin layer are continuously performed by changing a mixing ratio of the CF4 gas to the O2 gas in the gas mixture. ### Claim 6 (depends on 1) The method for manufacturing a semiconductor optical device according to claim 1, further comprising a step of forming an insulating layer on the semiconductor layer, wherein the first resin layer is formed on the insulating layer, in the step of selectively etching the first resin layer, the first resin layer is etched until the insulating layer is exposed, the insulating layer is etched using the first resin layer having the reverse pattern to the diffraction grating pattern as a mask, and after removing the first resin layer, the semiconductor layer is etched using the insulating layer as a mask in the step of etching the semiconductor layer. ### Claim 7 (depends on 1) The method for manufacturing a semiconductor optical device according to claim 1, wherein, in the step of changing the duty ratio of the diffraction grating pattern, the first resin layer is dry-etched by reactive ion etching using O2 gas as an etching gas. ### Claim 8 (depends on 1) The method for manufacturing a semiconductor optical device according to claim 1, wherein the imprint pattern of the mold includes a plurality of grating patterns having different pitches, the grating patterns having a single duty ratio. ### Claim 9 (depends on 1) The method for manufacturing a semiconductor optical device according to claim 1, further comprising a step of forming a lower cladding layer, an active layer, and an upper cladding layer on the diffraction grating formed in the semiconductor layer after the step of etching the semiconductor layer.