# US 2014/0193673 A1 · Polarity switching flow battery system and method > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2014/0193673 A1 - Document ID: US20140193673A1 - Status: Published application - Kind: A1 - Application number: 14/147,516 - Filed: 2014-01-04 - Published: 2014-07-10 - Earliest claimed: 2013-01-04 - Assignees: Ashlawn Energy, LLC - Applicants: Ashlawn Energy, LLC - Inventors: Michael Woolery; Joseph F. Startari; Maurice Daniel; Bryan P. Tipton - Web page: https://patentgrep.com/patent/US20140193673A1 ## CPC - H01M 8/04186: of liquid-charged or electrolyte-charged reactants - H01M 8/04276: Arrangements for managing the electrolyte stream, e.g. heat exchange - H01M 8/0438: Pressure; Ambient pressure; Flow - H01M 8/04477: {of the electrolyte} - H01M 8/188: {by recharging of redox couples containing fluids; Redox flow type batteries} - Y02E 60/50: Fuel cells - H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY - Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION ## Abstract A flow battery system and method are provided. The flow battery system may include a feed system feeding positive electrolyte from a first storage tank to a positive inlet of a battery stack and negative electrolyte from a second storage tank to a negative inlet of the battery stack, a return system returning charged electrolyte from the battery stack to the first and second storage tanks, and a controller to selectively control at least one of the feed system and the return system so positive electrolyte, from the first storage tank, is applied a negative charge by the battery stack and then returned by the return system to the second storage tank, and so negative electrolyte, from the second storage tank, is applied a positive charge by the battery stack and then returned by the return system to the first storage tank. ## Claims ### Claim 1 A flow battery system, comprising: a feed system configured to at least feed positive electrolyte transported from a first storage tank, storing the positive electrolyte, to a positive inlet of a battery stack configured for transport to a first half cell of a battery cell of the battery stack, and configured to feed negative electrolyte transported from a second storage tank, storing the negative electrolyte, to a negative inlet of the battery stack configured for transport to a second half cell of the battery cell; a return system configured to at least return charged electrolyte transported from the first half cell to the first storage tank and to return charged electrolyte transported from the second half cell to the second storage tank; and a controller to control a polarity switching of the flow battery system to selectively control at least one of the feed system and the return system, so positive electrolyte, from the first storage tank, transported in the feed system to the battery stack is applied a negative charge by the battery stack and then returned by the return system to the second storage tank, and so negative electrolyte, from the second storage tank, transported in the feed system to the battery stack is applied a positive charge by the battery stack and then returned by the return system to the first storage tank. ### Claim 2 (depends on 1) The flow battery system of claim 1, wherein the controller is at least one of a valve controller in feed system and a valve controller in the return system, and the selective control to perform the polarity switching is performed based on a determined ion reactant imbalance between electrolytes stored in the first storage tank and the second storage tank. ### Claim 3 (depends on 2) The flow battery system of claim 2, wherein the controller further comprises a controller unit, including one or more processing devices, in communication with one or more of the valve controller in feed system, the valve controller in the return system, wherein the controller unit determines when to perform the polarity switching of the flow battery system based upon the determined ion reactant imbalance. ### Claim 4 (depends on 3) The flow battery system of claim 3, further comprising one or more state of charge (SOC) sensors configured to determine an SOC of the positive and/or negative electrolytes in the flow battery system, and wherein the controller uses the determined SOC to determine when to reverse the controlled polarity switching of the flow battery system. ### Claim 5 (depends on 3) The flow battery system of claim 3, further comprising one or more flow sensors configured to determine an amount of flow of electrolytes in the flow battery system after the polarity switching occurs to determine when to reverse the controlled polarity switching of the flow battery system. ### Claim 6 (depends on 1) The flow battery system of claim 1, wherein the controller determines when to perform the polarity switching of the flow battery system based upon a determination of a sufficiently discharged state of an electrolyte in the flow battery system. ### Claim 7 (depends on 6) The flow battery system of claim 6, wherein the sufficiently discharged state of electrolyte is a 20/80 state of charge (SOC) of the positive or negative electrolyte stored in the first or second storage tanks. ### Claim 8 (depends on 1) The flow battery system of claim 1, wherein the controlling of the polarity switching of the flow battery system includes at least one of controlling the feed system to feed the positive electrolyte transported from the first storage tank to the negative inlet of the battery stack and to feed the negative electrolyte transported from the second storage tank to the positive inlet of the battery stack and controlling the return system to return the charged electrolyte transported from the first half cell to the second storage tank and to return the charged electrolyte from the second half cell to the first storage tank. ### Claim 9 (depends on 8) The flow battery system of claim 8, wherein the controlling of the return system further comprises controlling a battery lead system to switch a polarity of first and second poles of the battery stack so the first half cell applies a negative charge and the second half cell applies a positive charge. ### Claim 10 (depends on 1) The flow battery system of claim 1, further comprising: a battery lead system including a switch for switching polarities of first and second poles of the battery stack; and the battery stack including the battery cell, having the first half cell and the second half cell, configured so electrolyte transported through the first half cell is charged by the first pole and electrolyte transported through the second half cell is charged based on the second pole, the first pole and the second pole being opposite poles. ### Claim 11 (depends on 10) The flow battery system of claim 10, further comprising the first storage tank storing the positive electrolyte and the second storage tank storing the negative electrolyte. ### Claim 12 (depends on 1) The flow battery system of claim 1, wherein the controller controls the flow battery system to control the polarity switching of the flow battery system by controlling the polarity of first and second poles of the battery stack, to change from a first set polarity, where the first half cell applies the positive charge and the second half cell applies the negative charge, to a second set polarity, where the first half cell applies the negative charge and the second half cell applies the positive charge, upon a determined ion reactant imbalance between electrolytes stored in the first storage tank and the second storage tank. ### Claim 13 (depends on 12) The flow battery system of claim 12, wherein the ion reactant imbalance determination is based upon a determined excess in volume of electrolyte in the first storage tank and/or the second storage tank. ### Claim 14 (depends on 1) The flow battery system of claim 1, wherein the controlling of the polarity switching of the flow battery system includes controlling the return system, with the return system being configured so as to return the charged electrolyte transported from the first half cell to the second storage tank and return the charged electrolyte transported from the second half cell to the first storage tank when the polarity switch of the flow battery system is performed, and so as to return the charged electrolyte transported from the first half cell to the first storage tank and return the charged electrolyte transported from the second half cell to the second storage tank when the polarity switch of the flow battery system is not performed. ### Claim 15 (depends on 14) The flow battery system of claim 14, wherein the controller controls the polarity switching of the flow battery system to selectively control the return system and a battery lead system for the battery stack, wherein the controlling of the battery lead system includes controlling a polarity of first and second poles of the battery stack, to change from a first set polarity, where the first half cell applies the positive charge and the second half cell applies the negative charge, to a second set polarity, where the first half cell applies the negative charge and the second half cell applies the positive charge. ### Claim 16 (depends on 15) The flow battery system of claim 15, wherein the controller performs the polarity switching of the flow battery system when an ion reactant imbalance is determined between electrolytes stored in the first storage tank and the second storage tank. ### Claim 17 (depends on 15) The flow battery system of claim 15, wherein, upon a determined stopping point of the polarity switching, the controller controls the flow battery system to stop the polarity switching and be set to a normal mode, which includes controlling a switching of the polarity of the first and second poles so the first half cell applies the positive charge and the second half cell applies the negative charge and controlling the return system to return the charged electrolyte transported from the first half cell to the first storage tank and to return the charged electrolyte from the second half cell to the second storage tank. ### Claim 18 (depends on 17) The flow battery system of claim 17, wherein the determined stopping point is determined to be before a time when plural cycles of a volume of electrolyte of one of the first or second storage tanks has flowed through one or more battery stacks of the flow battery system. ### Claim 19 (depends on 15) The flow battery system of claim 15, wherein the first half cell and the second half cell are in fluid separation in the battery cell by a neutral or reversible exchange membrane, distinct from a cation exchange membrane and an anion exchange membrane. ### Claim 20 (depends on 1) The flow battery system of claim 1, wherein the controlling of the polarity switching of the flow battery system includes controlling the feed system, with the feed system being configured so as to feed the positive electrolyte transported from the first storage tank to the negative inlet of the battery stack and to feed the negative electrolyte transported from the second storage tank to the positive inlet of the battery stack when the polarity switch of the flow battery system is performed, and so as to feed the positive electrolyte transported from the first storage tank to the positive inlet of the battery stack and to feed the negative electrolyte transported from the second storage tank to the negative inlet of the battery stack when the polarity switch of the flow battery system is not performed. ### Claim 21 (depends on 20) The flow battery system of claim 20, wherein the controller performs the polarity switching of the flow battery system when an ion reactant imbalance is determined between electrolytes stored in the first storage tank and the second storage tank. ### Claim 22 (depends on 20) The flow battery system of claim 20, wherein, upon a determined stopping point of the polarity switching of the flow battery system, the controller controls the flow battery system to stop the polarity switching and be set to a normal mode, which includes controlling the feed system to feed the stored positive electrolyte transported from the first storage tank to the positive inlet of the battery stack and to feed the stored negative electrolyte transported from the second storage tank to the negative inlet of the battery stack. ### Claim 23 (depends on 22) The flow battery system of claim 22, wherein the determined stopping point is determined to occur after at time when at least plural cycles of a volume of electrolyte of one of the first or second storage tanks has flowed through battery stacks of the flow battery system. ### Claim 24 (depends on 20) The flow battery system of claim 20, wherein the first half cell and the second half cell are in fluid separation by a cation exchange membrane or an anion exchange membrane. ### Claim 25 (depends on 1) The flow battery system of claim 1, wherein the electrolytes include positive and negative electrolytes that respectively are single elemental reactants. ### Claim 26 (depends on 25) The flow battery system of claim 25, wherein the positive electrolyte is a VO2+/VO2+ couple and the negative electrolyte is a V3+/V2+ couple. ### Claim 27 A flow battery system, comprising: a battery stack including a battery cell, including a first half cell and a second half cell, configured so electrolyte transported through the first half cell is charged based on a first pole of the battery stack and electrolyte transported through the second half cell is charged based on a second pole of the battery stack, the first pole and the second pole being opposite poles; a first storage tank storing positive electrolyte; a second storage tank storing negative electrolyte; a feed system configured to at least feed the positive electrolyte transported from the first storage tank to the battery stack and to feed the negative electrolyte transported from the second storage tank to the battery stack; a return system configured to at least return charged electrolyte transported from the first half cell to the first storage tank and to return charged electrolyte transported from the second half cell to the second storage tank; and a controller to control a polarity switching of the flow battery system to rebalance electrolyte ion reactant concentrations of the positive electrolyte stored in the first storage tank and/or negative electrolyte stored in the second storage tank, by positive electrolyte, from the first storage tank, transported in the feed system to the battery stack being applied a negative charge by the battery stack and then being returned by the return system to the second storage tank, and by negative electrolyte, from the second storage tank, transported in the feed system to the battery stack being applied a positive charge by the battery stack and then being returned by the return system to the first storage tank. ### Claim 28 (depends on 27) The flow battery system of claim 27, wherein the electrolytes include positive and negative electrolytes that respectively are single elemental reactants. ### Claim 29 (depends on 28) The flow battery system of claim 28, wherein the positive electrolyte is a VO2+/VO2+ couple and the negative electrolyte is a V3+/V2+ couple. ### Claim 30 (depends on 27) The flow battery system of claim 27, wherein, in the controlling of the polarity switching of the flow battery system, the controller further controls a setting of a polarity of the battery stack, between a first set polarity where the first pole is controlled to be a positive pole and the second pole is controlled to be a negative pole and a second set polarity where the first pole is controlled to be the negative pole and the second pole is controlled to be the positive pole, such that the polarity switching of the flow battery system is performed by changing the polarity of the battery stack from the first set polarity to the second set polarity, so that the positive electrolyte fed by the feed system from the first storage tank to the first half cell is negatively charged and the negative electrolyte fed by the feed system from the second storage tank to the second half cell is positively charged. ### Claim 31 (depends on 30) The flow battery system of claim 30, wherein, in the controlling of the polarity switching of the flow battery system, the return system is configured so as to return the charged electrolyte transported from the first half cell to the second storage tank and return the charged electrolyte transported from the second half cell to the first storage tank when the polarity switch of the flow battery system is performed, and so as to return the charged electrolyte transported from the first half cell to the first storage tank and return the charged electrolyte transported from the second half cell to the second storage tank when the polarity switch of the flow battery system is not performed. ### Claim 32 (depends on 27) The flow battery system of claim 27, wherein, in the controlling of the polarity switching of the flow battery system, the feed system is configured so as to feed the positive electrolyte transported from the first storage tank to a negative inlet of the battery stack and to feed the negative electrolyte transported from the second storage tank to a positive inlet of the battery stack when the polarity switch of the flow battery system is performed, and so as to feed the positive electrolyte transported from the first storage tank to the positive inlet of the battery stack and to feed the negative electrolyte transported from the second storage tank to the negative inlet of the battery stack when the polarity switch of the flow battery system is not performed. ### Claim 33 A flow battery system, comprising: a controller to control a polarity switching of the flow battery system to selectively control at least one of a feed system and a return system for a battery stack of the flow battery system, to rebalance electrolyte ion reactant concentrations of positive electrolyte stored in a first storage tank and/or negative electrolyte stored in a second storage tank, so the positive electrolyte, from the first storage tank, transported in the feed system to the battery stack is applied a negative charge by the battery stack and then returned by the return system to the second storage tank, and so the negative electrolyte, from the second storage tank, transported in the feed system to the battery stack is applied a positive charge by the battery stack and then returned by the return system to the first storage tank, to rebalance the electrolyte ion reactant concentrations, such that the feed system is configured to at least feed the positive electrolyte transported from the first storage tank to a positive inlet of the battery stack configured for transport to a first half cell of a battery cell of the battery stack, and configured to feed the negative electrolyte transported from the second storage tank to a negative inlet of the battery stack configured for transport to a second half cell of the battery cell, and such that the return system is configured to at least return charged electrolyte transported from the first half cell to the first storage tank and to return charged electrolyte transported from the second half cell to the second storage tank. ### Claim 34 A method for controlling a flow battery system, the method comprising: feeding positive electrolyte transported from a first storage tank, storing the positive electrolyte, to a positive inlet of a battery stack configured for transport to a first half cell of a battery cell of the battery stack, and feeding negative electrolyte transported from a second storage tank, storing the negative electrolyte, to a negative inlet of the battery stack configured for transport to a second half cell of the battery cell; returning charged electrolyte transported from the first half cell to the first storage tank and returning charged electrolyte transported from the second half cell to the second storage tank; and selectively controlling a polarity switching of the flow battery system by controlling at least one of a changing of the feeding of electrolyte to the battery stack and changing of the returning of charged electrolyte from the battery stack to the first and second storage tanks, so positive electrolyte, from the first storage tank, transported in the feed system to the battery stack is applied a negative charge by the battery stack and then returned by the return system to the second storage tank, and so negative electrolyte, from the second storage tank, transported in the feed system to the battery stack is applied a positive charge by the battery stack and then returned by the return system to the first storage tank. ### Claim 35 (depends on 34) The method of claim 34, wherein the polarity switching of the flow battery system is performed based on a determined ion reactant imbalance between electrolytes stored in the first storage tank and the second storage tank. ### Claim 36 (depends on 34) The method of claim 34, wherein the selective controlling of the polarity switching includes selectively controlling one of a valve controller in a feed system of the flow battery system to perform the changing of the feeding of electrolyte to the battery stack and a valve controller in a return system of the flow battery system to perform the changing of the returning of charged electrolyte from the battery stack to the first and second storage tanks, based on a determined ion reactant imbalance between electrolytes stored in the first storage tank and the second storage tank. ### Claim 37 (depends on 36) The method of claim 36, further comprising determining when to perform the polarity switching of the flow battery system based upon the determined ion reactant imbalance between electrolytes in the first storage tank and second storage tank. ### Claim 38 (depends on 37) The method of claim 37, further comprising monitoring a state of charge (SOC) of the positive and/or negative electrolytes in the flow battery system, and determining when to reverse the controlled polarity switching of the flow battery system based on the monitored SOC. ### Claim 39 (depends on 37) The method of claim 37, further comprising monitoring an amount of flow of electrolytes in the flow battery system after the polarity switching to determine when to reverse the controlled polarity switching of the flow battery system. ### Claim 40 (depends on 34) The method of claim 34, further comprising determining when to perform the polarity switching of the flow battery system based upon a determination of a sufficiently discharged state of an electrolyte in the flow battery system. ### Claim 41 (depends on 40) The method of claim 40, wherein the sufficiently discharged state of electrolyte is a 20/80 state of charge (SOC) of the positive or negative electrolyte stored in the first or second storage tanks. ### Claim 42 (depends on 34) The method of claim 34, wherein the battery stack includes the battery cell, having the first half cell and the second half cell, configured so electrolyte transported through the first half cell is charged by a first pole of the battery stack and electrolyte transported through the second half cell is charged based on a second pole of the battery stack, the first pole and the second pole being opposite poles. ### Claim 43 (depends on 42) The method of claim 42, wherein the controlling of the polarity switching includes controlling a changing of the polarity of the battery stack, by controlling a polarity of the first and second poles of the battery stack, to change from a first set polarity, where the first half cell applies the positive charge and the second half cell applies the negative charge, to a second set polarity, where the first half cell applies the negative charge and the second half cell applies the positive charge, upon a determined ion reactant imbalance between electrolytes stored in the first storage tank and the second storage tank. ### Claim 44 (depends on 43) The method of claim 43, further comprising monitoring volumes of electrolyte stored in the first and/or second storage tanks and determining the ion reactant imbalance based upon a determined excess in the monitored volume of electrolyte in the first or second storage tanks. ### Claim 45 (depends on 34) The method of claim 34, wherein the controlling of the polarity switching includes controlling the changing of the returning of charged electrolyte from the battery stack to the first and second storage tanks, so as to return the charged electrolyte transported from the first half cell to the second storage tank and return the charged electrolyte transported from the second half cell to the first storage tank when the polarity switch of the flow battery system is performed, and so as to return the charged electrolyte transported from the first half cell to the first storage tank and return the charged electrolyte transported from the second half cell to the second storage tank when the polarity switch of the flow battery system is not performed. ### Claim 46 (depends on 45) The method of claim 45, wherein the controlling of the polarity switching further includes a changing of a polarity of the battery stack, comprising controlling a polarity of first and second poles of the battery stack to change from a first set polarity, where the first half cell applies the positive charge and the second half cell applies the negative charge, to a second set polarity, where the first half cell applies the negative charge and the second half cell applies the positive charge, when the polarity switch of the flow battery system is performed and to subsequently switch back to the first set polarity when the polarity switching is stopped. ### Claim 47 (depends on 46) The method of claim 46, further comprising determining to stop the polarity switching before a time when plural cycles of a volume of electrolyte of one of the first or second storage tanks has flowed through one or more battery stacks of the flow battery system. ### Claim 48 (depends on 46) The method of claim 46, wherein the first half cell and the second half cell are in fluid separation in the battery cell by a neutral or reversible exchange membrane, distinct from a cation exchange membrane and an anion exchange membrane. ### Claim 49 (depends on 34) The method of claim 34, wherein the controlling of the polarity switching includes controlling the changing of the feeding of electrolyte to the battery stack, so as to feed the positive electrolyte transported from the first storage tank to the negative inlet of the battery stack and to feed the negative electrolyte transported from the second storage tank to the positive inlet of the battery stack when the polarity switch of the flow battery system is performed, and so as to feed the positive electrolyte transported from the first storage tank to the positive inlet of the battery stack and to feed the negative electrolyte transported from the second storage tank to the negative inlet of the battery stack when the polarity switch of the flow battery system is not performed. ### Claim 50 (depends on 49) The method of claim 49, wherein, upon a determined stopping point of the polarity switching of the flow battery system, the controlling of the polarity switching controls the flow battery system to stop the polarity switching and the flow battery system to be set to a normal mode, which includes controlling the feed system to feed the stored positive electrolyte transported from the first storage tank to the positive inlet of the battery stack and to feed the stored negative electrolyte transported from the second storage tank to the negative inlet of the battery stack. ### Claim 51 (depends on 50) The method of claim 50, further comprising determining the stopping point to occur after a time when at least plural cycles of a volume of electrolyte of one of the first or second storage tanks has flowed through battery stacks of the flow battery system. ### Claim 52 (depends on 49) The method of claim 49, wherein the first half cell and the second half cell are in fluid separation by a cation exchange membrane or an anion exchange membrane. ### Claim 53 (depends on 34) The method of claim 34, wherein the electrolytes include positive and negative electrolytes that respectively are single elemental reactants. ### Claim 54 (depends on 53) The method of claim 53, wherein the positive electrolyte is a VO2+/VO2+ couple and the negative electrolyte is a V3+/V2+ couple.