# US 2014/0155668 A1 · Manufacturing Process

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- Number: US 2014/0155668 A1
- Document ID: US20140155668A1
- Status: Published application
- Kind: A1
- Application number: 14/078,673
- Filed: 2013-11-13
- Published: 2014-06-05
- Earliest claimed: 2012-12-05
- Assignees: ExxonMobil Chemical Patents Inc.
- Applicants: ExxonMobil Chemical Patents Inc.
- Inventors: Chunshe Cao; Jeffrey L. Andrews; Michel Molinier
- Web page: https://patentgrep.com/patent/US20140155668A1

## CPC

- C07C 5/2737: {with crystalline alumino-silicates, e.g. molecular sieves}
- C07C 2529/78: containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS

## Abstract

The invention relates to minimizing ammonia poisoning of a catalyst and to a xylene isomerization process using said catalyst.

## Claims

### Claim 1

A process in a reactor system comprising a reactor having a rhenium-based zeolite catalyst therein, said process comprising:
(i) a step comprising introducing nitrogen gas into said reactor system to at least partially displace any oxygen and/or moisture in said reactor system under conditions including a temperature T1 and a pressure P1, and then contacting said rhenium-based zeolite catalyst with said nitrogen gas for a predetermined period of time and/or until oxygen and/or moisture in said reactor system fall to a predetermined level;
(ii) a step comprising introducing hydrogen gas into said reactor system to at least partially displace said nitrogen in said reactor system under conditions including a temperature T2 and a pressure P2, and then contacting said rhenium-based zeolite is catalyst with said hydrogen gas for a period of time which may be predetermined and/or measured by one or more of reactor system characteristics selected from ammonia levels, oxygen levels, moisture levels, and nitrogen gas levels measured in said reactor system;
wherein T2≦T1 and P2≦P1 and at least one of T2<T1 and P2<P1 is true; and
(iii) a step comprising contacting said rhenium-based zeolite catalyst with a paraxylene-depleted feedstream comprising orthoxylene and metaxylene, whereby at least a portion of said orthoxylene and metaxylene are isomerized to paraxylene.

### Claim 2 (depends on 1)

The process of claim 1, further comprising, after step (ii) and before step (iii), at least one step (a), comprising increasing said reactor system pressure by increasing the pressure of hydrogen gas in said reactor system, followed by venting of said reactor system to decrease said reactor system pressure.

### Claim 3 (depends on 1)

The process of claim 1, wherein said zeolite is selected from at least one of MFI, MTW, and MOR zeolites.

### Claim 4 (depends on 1)

The process of claim 1, wherein hydrogen is introduced into said reactor to displace nitrogen at a temperature less than T1 and a pressure less than P1 for a period of time until at least one of the following conditions is measured in said reactor system: (i) ammonia levels are at or below a predetermined level; and (ii) nitrogen levels are at or below 1.0 vol %, based on the volume of total gases.

### Claim 5 (depends on 1)

The process of claim 1, wherein said conditions include T2<180°C<T1 and P2<0.5 MPa<P1.

### Claim 6 (depends on 5)

The process of claim 5, wherein T2≦160° C.

### Claim 7 (depends on 1)

The process of claim 1, wherein at least one of the following conditions is measured during the contacting of step (ii) before beginning step (iii): (aa) the moisture level as measured in the recycle gas line is less than 500 vppm; (bb) nitrogen level as measured in the recycle gas line has decreased to below 1.0 vol %; (cc) ammonia level as measured in the recycle gas line is at or below 5 vppm.

### Claim 8 (depends on 7)

The process of claim 7, wherein at least two of said conditions are measured during said contacting of step (ii) before beginning step (iii).

### Claim 9 (depends on 7)

The process of claim 7, wherein all of said conditions are measured during said contacting of step (ii) before beginning step (iii).