# US 2014/0155304 A1 · Anticorrosive composition

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- Number: US 2014/0155304 A1
- Document ID: US20140155304A1
- Status: Published application
- Kind: A1
- Application number: 14/176,710
- Filed: 2014-02-10
- Published: 2014-06-05
- Earliest claimed: 2008-06-09
- Assignees: Sears Petroleum & Transport Corporation and Sears Ecological Applications Co., LLC
- Applicants: Sears Petroleum & Transport Corporation and Sears Ecological Applications Co., LLC
- Inventors: Robert A. Hartley; David H. Wood
- Web page: https://patentgrep.com/patent/US20140155304A1

## CPC

- C09D 5/086: {Organic or non-macromolecular compounds}
- C09K 3/185: {Thawing materials}
- C09K 8/54: Compositions for in situ inhibition of corrosion in boreholes or wells
- C09K 15/34: containing plant or animal materials of unknown composition
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

## Abstract

The present invention relates to the discovery that melanoidins, and higher molecular weight fractions of products containing melanoidins, provide significant corrosive inhibition, which render these melanoidins suitable for use as anticorrosive agents in corrosive environments. In addition to being highly anticorrosive, the melanoidins of the present invention are environmentally friendly and non-toxic, and can be found in animal food and in human foodstuffs.

## Claims

### Claim 1

A method of reducing the corrosion caused by a chloride salt, the method comprising the steps of:
obtaining a molecular weight fraction of a product containing melanoidins, wherein the molecular weight fraction comprises melanoidins having a molecular weight greater than or equal to 12,400;
forming an aqueous solution including the molecular weight fraction of a product containing melanoidins; and
applying the solution to a metal surface, wherein the molecular weight fraction of a product containing melanoidins reduces corrosion at the metal surface caused by the chloride salt.

### Claim 2 (depends on 1)

The method of claim 1, wherein the metal surface contains iron.

### Claim 3 (depends on 1)

The method of claim 1, wherein the product containing melanoidins is selected from the group consisting of sugar cane and sugar beets.

### Claim 4 (depends on 1)

The method of claim 1, wherein the product containing melanoidins is selected from the group consisting of molasses, corn steep liquor, brewers condensed solubles, and distillers condensed solubles.

### Claim 5 (depends on 1)

The method of claim 1, wherein the metal surface is a roadway.

### Claim 6 (depends on 1)

The method of claim 1, wherein the metal surface is an oil well surface.

### Claim 7 (depends on 1)

The method of claim 1, wherein the chloride salt is at least one selected from the group consisting of sodium chloride, magnesium chloride, calcium chloride, and potassium chloride.

### Claim 8 (depends on 1)

The method of claim 1, wherein the chloride salt is an industrial brine.

### Claim 9 (depends on 1)

The method of claim 1, further comprising the step of adding a carbohydrate having a molecular weight in the range of 180 to 1500 to the solution, wherein said carbohydrate is at least one selected from the group consisting of glucose, fructose and higher saccharides based on glucose and/or fructose and mixtures thereof.

### Claim 10 (depends on 1)

The method of claim 1, further comprising the step of adding a thickener selected from the group consisting of cellulose derivatives and carbohydrates in the range of 60,000 to 1,000,000 for cellulose derivatives and 10,000 to 50,000 for carbohydrates to the chloride salt.

### Claim 11

An anticorrosive composition comprising:
water;
a chloride salt; and
water soluble solids, the water soluble solids comprising a molecular weight fraction of a product containing melanoidins, wherein melanoidins have a molecular weight greater than or equal to 12,400 and comprise at least 1.99% by weight of the water soluble solids.

### Claim 12 (depends on 11)

The anticorrosive composition of claim 11, wherein the product containing melanoidins is selected from the group consisting of sugar cane and sugar beets.

### Claim 13 (depends on 11)

The anticorrosive composition of claim 11, wherein the product containing melanoidins is selected from the group consisting of molasses, corn steep liquor, brewers condensed solubles, and distillers condensed solubles.

### Claim 14 (depends on 11)

The anticorrosive composition of claim 11, wherein the chloride salt is at least one selected from the group consisting of sodium chloride, magnesium chloride, calcium chloride, and potassium chloride.

### Claim 15 (depends on 11)

The anticorrosive composition of claim 11, wherein the chloride salt is an industrial brine.

### Claim 16 (depends on 11)

The anticorrosive composition of claim 11, further comprising a carbohydrate having a molecular weight in the range of 180 to 1500, wherein said carbohydrate is at least one selected from the group consisting of glucose, fructose and higher saccharides based on glucose and/or fructose and mixtures thereof.

### Claim 17 (depends on 11)

The anticorrosive composition of claim 11, further comprising a thickener selected from the group consisting of cellulose derivatives and carbohydrates in the range of 60,000 to 1,000,000 for cellulose derivatives and 10,000 to 50,000 for carbohydrates to the chloride salt.

### Claim 18 (depends on 11)

The anticorrosive composition of claim 11, wherein the melanoidins have a molecular weight greater than or equal to 12,400 and comprise at least 6% by weight of the water soluble solids

### Claim 19

An anticorrosive composition comprising:
water;
a chloride salt; and
water soluble solids, the water soluble solids comprising a molecular weight fraction of a product containing melanoidins, wherein melanoidins have a molecular weight greater than or equal to 10,000 and comprise at least 10% by weight of the water soluble solids.
