# US 2014/0155302 A1 · Oil well drilling fluids, oil well cement composition and slurry of weighting material

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- Number: US 2014/0155302 A1
- Document ID: US20140155302A1
- Status: Published application
- Kind: A1
- Application number: 13/695,664
- Filed: 2011-11-21
- Published: 2014-06-05
- Earliest claimed: 2011-07-11
- Assignees: Elkem AS
- Inventors: Mohamed Al-Bagoury; Christopher Drysdale Steele
- Web page: https://patentgrep.com/patent/US20140155302A1

## CPC

- C09K 8/032: {Inorganic additives}
- C04B 28/04: Portland cements
- C09K 8/145: {characterised by the composition of the clay}
- C09K 8/32: Non-aqueous well-drilling compositions, e.g. oil-based
- C09K 8/48: Density increasing or weighting additives
- Y02W 30/91: Use of waste materials as fillers for mortars or concrete
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE
- Y02W: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT

## Abstract

The present invention relates to oil well drilling comprising a weighting agent consisting of microfine, particulate ilmenite having a FeTiO3 content of at least 85% by weight, a specific surface area (BET) between 1 and 5 m2/g, where 90% by volume of the particles have a size of less than 12.5 μm and a D50 between 3 μm and 6 μm by volume measured by laser diffraction using Malvern laser diffraction particle size analyzer, where the particles have an average circularity of at least 0.85 determined by image analysis. The invention further relates to high density oil well cement slurry comprising water, Portland cement, a weighting material and optionally silica flour, microsilica, fiber, rubbery particles a fluid loss addition and a retarder, where the weighting material is particulate microfine ilmenite having a FeTiO3 content of at least 85% by weight, a specific surface area (BET) between 1 and 5 m2/g, and where 90% by volume of the particles have a size of less than 12.5 μm and a D50 between 3 and 6 μm measured by laser diffraction using Malvern laser diffraction particle size analyzer, and where the particles have an average circularity of at least 0.85 determined by image analysis. Finally, the invention relates to a slurry of microfine ilmenite.

## Claims

### Claim 1

Oil well drilling fluids characterized in that the oil well drilling fluid comprises a weighting agent consisting of microfine, particulate ilmenite having a FeTiO3 content of at least 85% by weight, a specific surface area (BET) between 1 and 5 m2/g, where 90% by volume of the particles have a size of less than 12.5 μm and a D50 between 3 μm and 6 μm by volume measured by laser diffraction using Malvern laser diffraction particle size analyzer, where the particles have an average circularity of at least 0.85 determined by image analysis.

### Claim 2 (depends on 1)

Oil well drilling fluids according to claim 1, characterized in that the microfine ilmenite has a specific surface area between 1.5 and 4 m2/g.

### Claim 3 (depends on 1)

Oil well drilling fluids according to claim 1, characterized in that the ilmenite particles have an average circularity of at least 0.90.

### Claim 4

A high density oil well cement slurry comprising water, Portland cement, a weighting material and optionally silica flour, microsilica, fiber, rubbery particles a fluid loss addition and a retarder, characterized in that the weighting material is particulate microfine ilmenite having a FeTiO3 content of at least 85% by weight, a specific surface area (BET) between 1 and 5 m2/g, and where 90% by volume of the particles have a size of less than 12.5 μm and a D50 between 3 and 6 μm measured by laser diffraction using Malvern laser diffraction particle size analyzer, and where the particles have an average circularity of at least 0.85 determined by image analysis.

### Claim 5 (depends on 4)

Cement slurry according to claim 4, characterized in that the microfine ilmenite has a specific surface area between 1.5 and 4 m2/g.

### Claim 6 (depends on 4)

Cement slurry according to claim 4, characterized in that the ilmenite particles have a circularity of at least 0.90.

### Claim 7

A stable non settling aqueous slurry, characterized in that the slurry comprises water, up to 85% by weight microfine ilmenite having a FeTiO3 content of a least at 85% by weight, a specific area (BET) between 1 and 5 m2/g, where 90% by volume of the particles have a size of less than 12.5 μm and a D50 between 3 and 6 μm by volume measured by laser diffraction using Malvern laser diffraction particle analyzer, where the particles have an average circularity of at least 0.85 determined by image analysis and 0.05 to 1% dispersant based on the weight of dry microfine ilmenite selected from an ethoxylated polycarboxylate, polyacrylic aid salt, alkali metal salt of lignosulphonate and biopolymer sulphonated acrylite copolymer the dispersant having an molecular weight below 50 000 g/mol.

### Claim 8 (depends on 7)

Slurry according to claim 7, characterized in that the dispersant has a molecular weight between 3000 and 20 000 g/mol.

### Claim 9 (depends on 7)

Slurry according to claim 7, characterized in that the microfine ilmenite particles have an average circularity of at least 0.90.