# US 2014/0155251 A1 · Substrate for carbon nanotube growth and method for manufacturing the same

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- Number: US 2014/0155251 A1
- Document ID: US20140155251A1
- Status: Published application
- Kind: A1
- Application number: 14/095,447
- Filed: 2013-12-03
- Published: 2014-06-05
- Earliest claimed: 2012-12-04
- Assignees: Honda Motor Co., Ltd.
- Applicants: Honda Motor Co., Ltd.
- Inventors: Toshiyuki Ohashi; Toshio Tokune; Masahiro Ohta; Ryogo Kato; Toshiyuki Shima
- Web page: https://patentgrep.com/patent/US20140155251A1

## CPC

- B01J 23/78: with alkali- or alkaline earth metals
- B01J 23/745: Iron
- B01J 37/0244: {Coatings comprising several layers}
- B01J 37/342: {of electric, magnetic or electromagnetic fields, e.g. for magnetic separation}
- B82Y 30/00: Nanotechnology for materials or surface science, e.g. nanocomposites
- B82Y 40/00: Manufacture or treatment of nanostructures
- C23C 14/5893: {Mixing of deposited material}
- C23C 14/081: {of aluminium, magnesium or beryllium}
- C23C 14/18: on other inorganic substrates
- C23C 14/5853: {Oxidation}
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B82Y: SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04)

## Abstract

Provided is a substrate for carbon nanotube growth in which no metal particles as a catalyst aggregates and a method for manufacturing the substrate. A substrate for carbon nanotube growth 1 includes a base plate 2, a catalyst 3, a form-defining material layer 4 which allows the catalyst 3 to be dispersed and arranged, and a covering layer 5 which has a metal oxide to cover the catalyst. A method for manufacturing a substrate for carbon nanotube growth 1 includes a step of sputtering on a base plate 2 a metal which forms a catalyst 3 and oxidizing the surface of the metal, a step of sputtering a form-defining material on the base plate 2, and a step of further sputtering on the form-defining material a metal which forms a catalyst 3 and oxidizing the surface of the metal.

## Claims

### Claim 1

A substrate for carbon nanotube growth comprising a base plate and a catalyst disposed on the base plate, the substrate comprising:
a catalyst consisting of a transition metal;
a form-defining material layer which is formed on the base plate to define a form which allows the catalyst to be dispersed and arranged; and
a covering layer which consists of a metal oxide to cover the surface of the catalyst.

### Claim 2 (depends on 1)

The substrate for carbon nanotube growth according to claim 1, wherein the form-defining material layer controls a plane direction of the crystal structure of the catalyst to thereby define the form of the catalyst.

### Claim 3 (depends on 1)

The substrate for carbon nanotube growth according to claim 1, wherein the catalyst consists of an iron group element.

### Claim 4 (depends on 3)

The substrate for carbon nanotube growth according to claim 3, wherein the iron group element is Fe.

### Claim 5 (depends on 1)

The substrate for carbon nanotube growth according to claim 1, wherein the base plate consists of MgO (100) single crystal.

### Claim 6 (depends on 1)

The substrate for carbon nanotube growth according to claim 1, wherein the form-defining material layer has the same material as the base plate.

### Claim 7 (depends on 1)

The substrate for carbon nanotube growth according to claim 1, wherein the base plate consists of MgO (100) single crystal, and the form-defining material layer consists of MgO which is the same material as the base plate in terms of substance.

### Claim 8 (depends on 1)

The substrate for carbon nanotube growth according to claim 1, wherein the covering layer consists of MgFe2O4.

### Claim 9 (depends on 1)

The substrate for carbon nanotube growth according to claim 1, wherein the covering layer has a thickness ranging from 0.2 to 5.0 nm.

### Claim 10

A method for manufacturing a substrate for carbon nanotube growth comprising a base plate and a catalyst disposed on the base plate, the method comprising:
a step of sputtering on the base plate a metal which forms the catalyst and oxidizing the surface of the metal;
a step of sputtering on the base plate a form-defining material which defines a form which allows the catalyst to be dispersed and arranged; and
a step of further sputtering on the form-defining material a metal which forms the catalyst and oxidizing the surface of the metal.

### Claim 11 (depends on 10)

The method for manufacturing a substrate for carbon nanotube growth according to claim 10, wherein the step of sputtering a form-defining material which defines a form which allows the catalyst to be dispersed and arranged, and the step of further sputtering on the form-defining material a metal which forms the catalyst and oxidizing the surface of the metal are repeated in a plurality of times.

### Claim 12 (depends on 10)

The method for manufacturing a substrate for carbon nanotube growth according to claim 10, wherein the metal which forms the catalyst consists of a transition metal.

### Claim 13 (depends on 10)

The method for manufacturing a substrate for carbon nanotube growth according to claim 10, wherein the metal which forms the catalyst consists of an iron group element.

### Claim 14 (depends on 10)

The method for manufacturing a substrate for carbon nanotube growth according to claim 10, wherein the iron group element is Fe.

### Claim 15 (depends on 10)

The method for manufacturing a substrate for carbon nanotube growth according to claim 10, wherein the base plate consists of MgO (100) single crystal.

### Claim 16 (depends on 10)

The method for manufacturing a substrate for carbon nanotube growth according to claim 10, wherein the form-defining material is the same material as the base plate.

### Claim 17 (depends on 10)

The method for manufacturing a substrate for carbon nanotube growth according to claim 10, wherein the form-defining material is MgO.
